Mixed lithium battery positive material and preparation method thereof
A battery cathode and cathode material technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of poor cyclability, low compaction density, poor thermal stability, etc., and achieve low cost, high compaction density, The effect of increasing electrical conductivity
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specific Embodiment 1
[0021] A mixed lithium battery positive electrode material, the positive electrode material is a mixed reactant of cobalt oxide, a ternary precursor and a lithium salt; the molar ratio of the cobalt element in the cobalt oxide and the metal element in the ternary precursor is 1:1, The molar ratio of the cobalt oxide and the metal element in the mixture of the ternary precursor to the lithium element in the lithium salt is 1:1.05; after the cobalt oxide and the ternary precursor are fully ground, the lithium salt is added and mixed, and the Carrying out two-step sintering and sieving to obtain the positive electrode material, which is lithium cobalt manganate coated with lithium cobalt oxide, wherein the lithium cobalt manganese oxide particles are large, and the lithium cobalt oxide particles are small; the cobalt oxide is Co 3 o 4 ; The ternary precursor is (Ni 0.5 mn 0.3 co 0.2 )(OH) 2 ; The lithium salt is Li 2 CO 3 . Electron microscopy scanning was carried out to o...
specific Embodiment 2
[0027] A mixed lithium battery positive electrode material, the positive electrode material is a mixed reactant of cobalt oxide, a ternary precursor and a lithium salt; the molar ratio of the cobalt element in the cobalt oxide and the metal element in the ternary precursor is 0.5:1, The molar ratio of the cobalt oxide and the metal element in the mixture of the ternary precursor to the lithium element in the lithium salt is 1:1.05; after the cobalt oxide and the ternary precursor are fully ground, the lithium salt is added and mixed, and the Carrying out two-step sintering and sieving to obtain the positive electrode material, which is lithium cobalt manganate coated with lithium cobalt oxide, wherein the lithium cobalt manganese oxide particles are large, and the lithium cobalt oxide particles are small; the cobalt oxide is Co 3 o 4 ; The ternary precursor is (Ni 0.6 mn 0.2 co 0.2 )(OH) 2 ; The lithium salt is Li 2 CO 3 .
[0028] Made by the following steps:
[0029]...
specific Embodiment 3
[0033] A mixed lithium battery positive electrode material, the positive electrode material is a mixed reactant of cobalt oxide, a ternary precursor and a lithium salt; the molar ratio of the cobalt element in the cobalt oxide and the metal element in the ternary precursor is 2:1, The molar ratio of the cobalt oxide and the metal element in the mixture of the ternary precursor to the lithium element in the lithium salt is 1:1.05; after the cobalt oxide and the ternary precursor are fully ground, the lithium salt is added and mixed, and the Carrying out two-step sintering and sieving to obtain the positive electrode material, which is lithium cobalt manganate coated with lithium cobalt oxide, wherein the lithium cobalt manganese oxide particles are large, and the lithium cobalt oxide particles are small; the cobalt oxide is Co 3 o 4 ; The ternary precursor is (Ni 0.6 mn 0.2 co 0.2 )(OH) 2 ; The lithium salt is Li 2 CO 3 .
[0034] Made by the following steps:
[0035] (...
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