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Chemical mechanical polishing method

A chemical machinery, polishing liquid technology, applied in polishing compositions containing abrasives, grinding machine tools, grinding devices, etc., to achieve the effects of reducing content, reducing use costs, and controlling the polishing process

Inactive Publication Date: 2014-07-02
ANJI MICROELECTRONICS (SHANGHAI) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In summary, in the previously published patents and literature, there is no polishing solution specifically for polishing the TSV barrier layer.

Method used

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Comparison scheme
Effect test

Embodiment 1

[0031] Embodiment 1 step-by-step chemical mechanical polishing method

[0032] Copper polishing liquid: TSV-A21 copper polishing liquid sold in Anji Market;

[0033] Barrier layer polishing solution: 5wt% silicon dioxide, benzotriazole as corrosion inhibitor, oxalic acid as complexing agent, hydrogen peroxide as oxidizing agent, water as the balance, pH=2.0;

[0034] Dielectric layer polishing liquid: 15wt% silicon dioxide, corrosion inhibitor is benzotriazole, complexing agent is oxalic acid, silicon nitride inhibitor is 0.1wt% sodium methylene dinaphthalene sulfonate, oxidant is hydrogen peroxide, Water is the balance, pH=3.0

[0035] 1. Use TSV-A21 copper polishing liquid on the first polishing disc, the polishing conditions are: the polishing pad is IC pad, the down pressure is 3.0psi, the rotational speed is polishing disc / polishing head=93 / 87rpm, and the flow rate of polishing liquid is 150ml / min, the polishing time is controlled by the end point control system.

[0...

Embodiment 2

[0038] Embodiment 2 step-by-step chemical mechanical polishing method

[0039] Copper polishing liquid: TSV-A21 copper polishing liquid sold in Anji

[0040] Barrier layer polishing solution: 8wt% silicon dioxide, corrosion inhibitor is methyl benzotriazole, complexing agent is citric acid, oxidizing agent is hydrogen peroxide, water is the balance, pH=3.0

[0041]Dielectric layer polishing liquid: 25wt% silicon dioxide, the corrosion inhibitor is tolyl benzotriazole, the complexing agent is citric acid, the silicon nitride inhibitor is 0.3wt% sodium methylnaphthalenesulfonate formaldehyde condensation polymer, Oxidant is hydrogen peroxide, water is the balance, pH=3.0

[0042] 1. Use TSV-A21 copper polishing liquid on the first polishing disc, the polishing conditions are: the polishing pad is IC pad, the down pressure is 3.0psi, the rotation speed is polishing disc / polishing head = 55 / 50rpm, and the flow rate of polishing liquid is 150ml / min, the polishing time is control...

Embodiment 3

[0045] Embodiment 3 step-by-step chemical mechanical polishing method

[0046] Copper polishing liquid: TSV-A21 copper polishing liquid sold in Anji

[0047] Barrier layer polishing solution: 10%wt silicon dioxide, 1,2,4-triazole as corrosion inhibitor, malonic acid as complexing agent, hydrogen peroxide as oxidizing agent, water as balance, pH=4.0

[0048] Dielectric layer polishing solution: 30wt% silicon dioxide, 1,2,4-triazole as a corrosion inhibitor, malonic acid as a complexing agent, and 0.5wt% polycondensation of benzylnaphthalenesulfonic acid formaldehyde as a silicon nitride inhibitor The oxidizing agent is hydrogen peroxide, the balance is water, pH=4

[0049] 1. Use TSV-A21 copper polishing liquid on the first polishing disc, the polishing conditions are: the polishing pad is IC pad, the down pressure is 2.0psi, the rotational speed is polishing disc / polishing head=115 / 110rpm, and the flow rate of polishing liquid is 150ml / min, the polishing time is controlled ...

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PUM

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Abstract

The invention discloses a technique of chemical mechanical polishing of TSVs (through silicon vias). The technique includes the steps of A, removing a copper covering layer with copper polishing solution and flattening the surface; B, removing a tantalum barrier layer and part of a dielectric layer with barrier layer polishing solution and flattening the surface; C, removing the dielectric layer with dielectric layer chemical mechanical polishing solution and reserving a silicon nitride layer. The capacity is increased by changing the polishing process; after the dielectric layer is polished, the process can be stopped by a silicon nitride stop layer, and the polishing process can be controlled well.

Description

technical field [0001] The present invention relates to a chemical mechanical polishing method, more specifically, to a chemical mechanical polishing process for through-silicon holes. Background technique [0002] With the development of integrated circuits, on the one hand, in the traditional IC industry, in order to improve integration, reduce energy consumption, and shorten delay time, the line width is getting narrower and narrower. On the other hand, due to physical limitations, the line width cannot be reduced infinitely. The semiconductor industry no longer relies solely on integrating more devices on a single chip to improve performance, but turns to multi-chip packaging. Through-silicon via (TSV) technology is widely recognized by the industry as a latest technology that realizes the interconnection between chips by making vertical conduction between chips and between wafers. TSV enables chips to be stacked in the three-dimensional direction with the highest densi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B24B37/04C09G1/02
CPCB24B37/04C09G1/02
Inventor 荆建芬姚颖王雨春王文龙
Owner ANJI MICROELECTRONICS (SHANGHAI) CO LTD
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