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Lead plaster for low temperature resistant lead storage battery for electric scooter and preparation method of lead plaster

A technology for electric bicycles and lead-acid batteries, which is applied to battery electrodes, circuits, electrical components, etc., can solve the problems of poor low-temperature performance, insufficient battery charge acceptance performance, and inability to meet environmental use requirements, and improve low-temperature discharge performance. , The effect of improving discharge capacity and service life

Active Publication Date: 2014-05-07
河北超威电源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002]At present, the low-temperature performance of lead-acid batteries used in electric mopeds is not good, and generally can only meet or slightly exceed the national standard: the low-temperature capacity at -15°C reaches 0.7C 2, and at present, domestic batteries with better low-temperature performance can reach: -20°C low-temperature capacity of 0.75C2; but their charging and receiving performance is relatively poor, generally only Slightly exceeds the national standard value: Ica / I0≥2 (Ica is the charging current, I0 is the discharge current: 0.1C2) , generally can reach: 2.0~2.3
It cannot meet the requirements of low temperature environment below -20°C, especially in the northeast and northwestern regions of our country, some of which can reach -30°C in winter
Therefore, in the cold northern regions of our country, there are common phenomena that the batteries of electric mopeds are undercharged (poor charging acceptance) and short travel distances (low discharge capacity).
[0003] At present, the commonly used methods to improve the low-temperature discharge performance of lead-acid batteries in China are: 1. Thinning the electrodes and increasing the specific surface area of ​​the electrodes, but the cost of production control quality is high and the efficiency is low ;2. Adding sulfate with good conductivity to the electrolyte improves the conductivity of the battery electrodes, but only increases the low-temperature capacity in the early stage, which cannot be maintained continuously; 3. Reduces the concentration of the electrolyte, but the battery capacity is generally low; 4. Increase the negative electrode feeding and improve the negative electrode capacity, but the cost is too high

Method used

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  • Lead plaster for low temperature resistant lead storage battery for electric scooter and preparation method of lead plaster
  • Lead plaster for low temperature resistant lead storage battery for electric scooter and preparation method of lead plaster

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Example 1 Preparation of expansion agent

[0049] (1) Add 12.0L of sulfuric acid into the lead bucket (density at 15°C is 1.40±0.05g / cm 3 ), the lead skin barrel is heated by steam.

[0050] (2) Open the valve of the heating steam on the lead drum, and when the sulfuric acid is heated to 80°C, adjust the steam valve to keep the temperature of the sulfuric acid between 80°C and 100°C.

[0051] (3) Put 3.0Kg of cotton (pure seedless cotton) into the lead bucket within 10 minutes, and at the same time, keep stirring with a plastic rod until all the cotton is semi-carbonized into a yellow-brown slurry (it cannot be carbonized and blackened) , close the steam valve.

[0052] (4) The expansion agent can only be used when the temperature drops to no higher than room temperature by 5°C. The storage period of the prepared expansion agent shall not exceed 3 days.

Embodiment 2

[0053] Example 2 Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

[0054] Low-temperature-resistant lead-acid battery lead paste for electric mopeds, including positive lead paste and negative lead paste:

[0055] The ratio of parts by weight of each component in the positive lead paste is: lead powder 960Kg, concentration 1.3-1.4g / cm 3Sulfuric acid 80 Kg, pure water 110Kg, colloidal graphite 4.0Kg, red lead 50Kg, stannous sulfate 1.0 Kg, sodium sulfate 0.5 Kg; short fiber 0.9 Kg;

[0056] The weight-number ratio of each component in the negative lead paste is: lead powder 1000 Kg, concentration 1.3-1.4g / cm 3 75 Kg of sulfuric acid, 105 Kg of pure water, 0.6 Kg of short fibers, 7.0 Kg of barium sulfate, 1.0 Kg of Norway lignin, 5.0 Kg of humic acid, 3.0 Kg of acetylene black, 1.5 K of semi-carbonized wood chips, and 8 L of swelling agent in Example 1.

[0057] (1) Ingredients

[0058] 1.1 Weigh each raw material ac...

Embodiment 3

[0070] Example 3 Low-temperature-resistant lead-acid battery lead paste for electric moped and preparation method thereof

[0071] Low-temperature-resistant lead-acid battery lead paste for electric mopeds, including positive lead paste and negative lead paste:

[0072] The ratio of parts by weight of each component in the positive lead paste is: lead powder 950Kg, concentration 1.4g / cm 3 Sulfuric acid 80 Kg, pure water 110Kg, colloidal graphite 3.0Kg, red lead 50Kg, stannous sulfate 1.5 Kg, sodium sulfate 1.0 Kg; short fiber 0.7 Kg;

[0073] The weight / number ratio of each component in the negative electrode lead paste is: lead powder 1000 Kg, concentration is 1.4g / cm 3 75 Kg of sulfuric acid, 105 Kg of pure water, 0.6 Kg of short fiber, 7.0 Kg of barium sulfate, 1.5 Kg of Norway lignin, 5.0 Kg of humic acid, 2.5 Kg of acetylene black, 1 K of semi-carbonized wood chips, and 12 L of swelling agent in Example 1.

[0074] (1) Ingredients

[0075] 1.1 Weigh each raw materi...

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Abstract

The invention relates to a lead plaster for a low temperature resistant lead storage battery for an electric scooter and a preparation method of the lead plaster. The lead plaster comprises an anode lead plaster and a cathode lead plaster, wherein the anode lead plaster comprises the following components in parts by weight: 950-970 parts of lead powder, 80-86 parts of 1.3-1.4g / cm<3> sulfuric acid, 110-125 parts of pure water, 3.0-4.0 parts of colloidal graphite, 30-50 parts of red lead, 1.0-1.5 parts of tin sulfate, 0.5-1.0 part of sodium sulfate and 0.7-0.9 part of short fiber; the cathode lead plaster comprises the following components in parts by weight: 1000 parts of lead powder, 75-81 parts of 1.3-1.4g / cm<3> sulfuric acid, 105-120 parts of pure water, 0.6-0.8 part of short fiber, 6.0-7.0 parts of barium sulfate, 1.0-1.5 parts of Norway lignin, 4.0-5.0 parts of humic acid, 3.0-5.0 parts of acetylene black and 1.0-1.5 parts of semi-carbonized saw dust. According to the lead plaster and the preparation method thereof, the acceptance performance when the battery is charged at low temperature is improved and the discharge capacity is increased; the lead plaster disclosed by the invention is applicable to low-temperature environment and is especially suitable for northeast and northwest regions in China.

Description

technical field [0001] The invention relates to a storage battery material and a preparation method thereof, in particular to a low-temperature-resistant lead storage battery lead paste for electric bicycles and a preparation method thereof. Background technique [0002] At present, the low-temperature performance of lead-acid batteries for electric mopeds is not good, and generally can only meet or slightly exceed the national standard: the low-temperature capacity at -15°C reaches 0.7C 2 , and at present, domestic batteries with better low-temperature performance can reach: -20°C low-temperature capacity of 0.75C 2 ; but its charging and receiving performance is relatively poor, generally only slightly exceeding the national standard value: Ica / I 0 ≥2 (Ica is the receiving current for charging, I 0 For discharge current: 0.1C 2 ), generally can reach: 2.0 ~ 2.3. It cannot meet the requirements for the use of environments with low temperatures below -20°C, especially in...

Claims

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Application Information

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IPC IPC(8): H01M4/56
CPCH01M4/57H01M4/62H01M4/624H01M4/627Y02E60/10
Inventor 钟维禄
Owner 河北超威电源有限公司
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