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High performance bipolar lead-acid storage battery

A lead-acid battery, bipolar technology, used in lead-acid batteries, lead-acid battery construction, batteries with bipolar electrodes, etc., can solve different expansion coefficients, safety cannot be guaranteed, and welding points are prone to overheating question

Inactive Publication Date: 2014-01-22
林子进 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The development and utilization of new energy is quite hot, especially in the automotive industry. High-performance secondary batteries are the current technical bottleneck. After several years of practice, it has been proved that lithium-ion batteries cannot be used due to their structural and material problems. The charging and discharging of high current makes safety impossible to be guaranteed. Judging from the current situation, bipolar lead-acid battery is the best battery of choice in the automotive industry. bipolar lead-acid battery, such as Chinese patent ZL200920112517.4 discloses a bipolar lead-acid battery, including a positive terminal piece and a negative terminal piece drawn from the casing and a sealed battery cover with a one-way valve, The bipolar plate adopts carbon fiber substrate, and the bipolar plate divides the inner cavity of the shell into multiple compartments. There is only one sealed battery cover for the one-way valve, and the internal air chambers are connected. This bipolar lead-acid battery The design does not discuss whether it can be industrially mass-produced for the time being. Its obvious defects are: 1. The electrodes are drawn out through the positive terminal piece and the negative terminal piece. When the current is flowing, the welding point is most likely to overheat, causing the welding wire of the welding point to melt; 2. Although the material of the electrode is not disclosed, because the electrode needs to be coated with lead paste, according to the existing design ideas, the application material of the electrode must use lead alloy , because the lead alloy has a certain rigidity, is not easy to deform, and is easy to apply lead paste; 3. This design uses a one-way valve for the air chambers, and the air pressure in each compartment is averaged, but the expansion coefficients of different compartments are different. , so it is easy for one of the compartments to exceed the limit, but the one-way valve has not been opened; in addition, according to the actual production process, according to the design structure, it is easy to produce a short circuit when adding acid during the production process, and its product rate is high
Patent Publication No. CN103151566 discloses a bipolar high-power lead-acid battery. In order to solve the problem of adding acid, the design is provided with an inverted tapered groove on any frame of the bipolar type facing the other, located between two inverted The plastic partition between the tapered grooves is hollowed out and two inverted tapered grooves cooperate to form an inverted tapered hole for installing a safety valve. The two adjacent safety valves are misplaced. Although this design is to some extent It solves the problem of adding acid, but because the purpose of its design is only to solve the problem of adding acid, the bipolar lead-acid battery designed by this patent does not have an air chamber, and the setting of the safety valve is to prevent the internal liquid from leaking out, so The setting of the safety valve is relatively firm and can only be opened artificially. From the patent figure 1 and 2 It can be seen that, especially from figure 2 It can be seen from the cross-sectional diagram of the second, fourth and sixth porous partitions that plastic partitions are installed on the top of the porous partition, it can be inferred that the purpose of setting the inverted tapered groove is to solve the problem of acid addition, because it is for The effect of adding acid, which determines the size of the tapered groove will not be too large

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0024] like figure 1 As shown, this embodiment is a high-efficiency bipolar lead-acid storage battery. The storage battery uses a bipolar plate, including a positive terminal electrode, a negative terminal electrode, and a The bipolar plate between the electrodes; the positive terminal electrode and the negative terminal electrode include the electrode copper sheet and the electrode lead sheet, and the electrode copper sheet is soldered on the electrode lead sheet, and the melting point of ordinary solder is close to that of lead, so Conventional soldering materials cannot be used. In this embodiment, the soldering material is lead-tin eutectic material, and the soldering temperature is precisely controlled at about 280 degrees. In order to ensure that the current will not be too large due to the accumulation of electrons at the top, resulting in overheating and melting of the solder joints, which will cause the electrode copper sheet and the electrode lead sheet to be disconn...

Embodiment 2

[0030] Such as image 3 As shown, it is a storage battery composed of 10 compartments, which includes a positive electrode, a negative electrode, and 9 bipolar plates arranged between the positive electrode and the negative electrode, wherein the positive line The structure of the electrode and the negative electrode is similar to the first embodiment, and the nine bipolar plates are arranged according to the principle of opposite polarity: the positive electrode is equipped with the negative electrode and the negative electrode is arranged correspondingly, that is, the positive terminal electrode is paired with the first The negative electrode side of 1 bipolar plate, the positive electrode side of the 1st bipolar plate is facing the negative electrode side of the 2nd bipolar plate...and so on until the last bipolar plate One side of the positive electrode of the polar plate is opposite to the negative electrode side of the negative terminal electrode. Each bipolar plate div...

Embodiment 3

[0032] The manufacturing steps of the pole plate grid in the lead-acid battery: firstly adopt common mesh cloth, preferably, the material of this mesh cloth adopts the material of acid resistance, corrosion resistance, is used for the soft mesh cloth, and its mesh cloth often It is woven with very thin wires, and the thin ribs that cannot be injection molded by the existing plastic are injected around the grid cloth to form a plastic frame, which is used to shape the mesh cloth to form The plastic grid, and further processes such as pasting, curing and drying on the plastic grid, and the subsequent processes such as pasting, curing and drying are the same as the existing conventional processes. Finally, the plastic plate is bonded to the lead plate. In a bipolar lead-acid battery, the electrodes at both ends are a plastic plate and a lead plate, and the middle plate is a positive plastic plate and a lead plate. Plate and a negative plastic pole plate again, so-called positive ...

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Abstract

The invention discloses a high performance bipolar lead-acid storage battery, which includes a positive terminal electrode, a negative terminal electrode and a bipolar pole plate disposed between the positive terminal electrode and the negative terminal electrode. The positive terminal electrode is provided with a positive pole plate, and the negative terminal electrode is provided with a negative pole plate. The bipolar pole plate side opposite to the positive terminal electrode is equipped with a negative electrode, and the bipolar pole plate side opposite to the negative terminal electrode is equipped with a positive electrode. The space between the positive terminal electrode and the negative electrode of the bipolar pole plate, and the space between the positive electrode of the bipolar pole plate and the negative terminal electrode are respectively provided with a fiber partition board for adsorbing an electrolyte solution. The top of each fiber partition board is respectively provided with a gas chamber, and the gas chambers are isolated mutually. Each gas chamber top is equipped with a safety valve, the upper end of which is provided with a cover plate. The gas chambers are set independently, and each gas chamber is respectively provided with the safety valve, so that the stress generated by expansion and contraction of any compartment cannot affect the other compartment.

Description

technical field [0001] The invention relates to the field of bipolar lead-acid batteries, in particular to a high-efficiency bipolar lead-acid storage battery. Background technique [0002] In recent years, carbon dioxide emissions have been reduced in order to protect the environment. The development and utilization of new energy is quite hot, especially in the automotive industry. High-performance secondary batteries are the current technical bottleneck. After several years of practice, it has been proved that lithium-ion batteries cannot be used due to their structural and material problems. The charging and discharging of high current makes safety impossible to be guaranteed. Judging from the current situation, bipolar lead-acid battery is the best battery of choice in the automotive industry. bipolar lead-acid battery, such as Chinese patent ZL200920112517.4 discloses a bipolar lead-acid battery, including a positive terminal piece and a negative terminal piece dra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/18H01M2/12H01M10/12H01M50/30
CPCH01M4/661H01M4/68H01M10/14H01M10/18H01M50/35H01M50/463Y02E60/10Y02P70/50
Inventor 林子进伊晓波
Owner 林子进
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