Preparation method of large-power high-magnification lithium iron phosphate battery
A lithium iron phosphate battery, lithium iron phosphate technology, applied in the manufacture of electrolyte batteries, battery electrodes, non-aqueous electrolyte batteries, etc., to achieve improved conductivity or lithium ion migration speed, conductive ion or lithium ion migration speed, safety and reliability. The effect of high rate performance improvement
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Embodiment 1
[0026] 1) Prepare the positive electrode sheet.
[0027] 1.1) Preparation of modified lithium iron phosphate cathode material: 6.5kg of isopropanol, 0.8kg of glucose, Nb 2 o 5 0.01kg, 1.290kg of ammonium dihydrogen phosphate, 1.905kg of ferrous oxalate, and 0.22kg of lithium carbonate were successively put into a ball mill (the theoretical molar content of Nb in the proportioning ratio was 1%), ball milled for 3 hours, and then put into a sand mill to sand Grind for 3 hours, then pass through a double-cone vacuum dryer in Dry at high temperature for 5 hours to obtain the precursor, and the precursor is passed through under the protection of nitrogen. keep warm for 4 hours, Heat preservation for 10 hours, and then natural cooling to obtain a lithium iron phosphate material, and finally crushed by a pulverizer to obtain a modified lithium iron phosphate positive electrode material. The tested Nb molar content is 0.99%, and the specific surface area is 13.2m2 / g.
[0028] 1...
Embodiment 2
[0038] 2) Prepare the positive electrode sheet.
[0039] 1.1) Preparation of modified lithium iron phosphate cathode material: Put 6.5kg of isopropanol, 0.8kg of glucose, 0.006kg of cobalt oxide, 1.290kg of ammonium dihydrogen phosphate, 1.905kg of ferrous oxalate, and 0.22kg of lithium carbonate into a ball mill in sequence (theoretical molar content of Co is 1% in the proportioning), ball milled for 3 hours, then put into the sand mill for sand milling for 3 hours, then passed through the double cone vacuum drier Dry at high temperature for 5 hours to obtain the precursor, and the precursor is passed through under the protection of nitrogen. keep warm for 4 hours, Heat preservation for 10 hours, and then natural cooling to obtain a lithium iron phosphate material, and finally crushed by a pulverizer to obtain a modified lithium iron phosphate positive electrode material. The tested Co molar content is 0.98%, and the specific surface area is 12.5m2 / g.
[0040] 1.2) The a...
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