Filled polypropylene composite material applied to rapid forming component

A technology for forming parts and composite materials, which is applied in the field of polypropylene composite materials, can solve the problems of poor material flow stability, large material shrinkage, and easy deformation, and achieve good dimensional stability, low shrinkage, and low cost.

Inactive Publication Date: 2013-04-24
SUZHOU RUNJIA ENGINEER PLASTIC
View PDF2 Cites 16 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the addition of a nucleating agent increases the crystallization temperature and half-crystallization time, making the crystallization of the material more uniform, the parts are shaped better under the same cooling time, and the gap between the parts and the gauge is improved by more than 50%, but the addition of the nucleating agent The shrinkage rate of the material is increased, and the product is about 0.6mm smaller at one SPC point, and it is easy to deform
In addition, the viscoelasticity of polymer materials causes the faster the injection speed, the worse the flow stability of the material. When injection molding large parts such as automobile bumpers, instrument panels, and door panels, tiger skin patterns are prone to appear.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0035] A method for preparing a filled polypropylene composite material applied to rapid prototyping parts, comprising the following steps:

[0036] (1) Preparation of nano-filler masterbatch: In the solution, swell the nano-filler organized with stearyl ammonium salt with maleic anhydride and a small amount of auxiliary swelling agent; the swollen organic nano-filler is mixed with powdered High-fluidity polypropylene and an appropriate amount of initiator are melted and reacted in a mixer, so that the nano-filler and grafted polypropylene are fully dispersed and contacted, and a polypropylene / nano-filled grafted intercalation blend is obtained, which is the improved Non-toxic nano filler masterbatch;

[0037] (2) Weigh the raw materials according to the weight ratio;

[0038] (3) Dry blend polypropylene, modified nano filler, toughener, heat stabilizer DSTP, antioxidant 1010, and antioxidant 168 in a high-speed mixer for 3-5 minutes;

[0039] (4) Put the mixed raw materials...

Embodiment 1

[0043] Preparation of modified montmorillonite masterbatch: swell organic montmorillonite with octadecyl ammonium salt in solution with maleic anhydride and a small amount of auxiliary swelling agent; swell organic montmorillonite with powdery high The weight ratio of fluid polypropylene is 45:55, 0.5% initiator is melted and reacted in the mixer, so that the montmorillonite and grafted polypropylene are fully dispersed and contacted, and a polypropylene / montmorillonite grafted plug is obtained. Layer blends, that is, modified nano-montmorillonite masterbatches.

[0044] Prepare materials according to the group distribution ratio in the following table:

[0045] Types of name Content (parts) Polypropylene Blends of homo- and copolymer polypropylenes with different flow properties 77.7 Toughener B-octyl rubber 1 Mineral powder filler talcum powder 19 Modified montmorillonite masterbatch Polypropylene / montmorillonite graft intercalati...

Embodiment 2

[0048] Prepare materials according to the group distribution ratio in the following table:

[0049] Types of name Content (parts) Polypropylene Blends of homo- and copolymer polypropylenes with different flow properties 74.7 Toughener B-octyl rubber 4 Mineral powder filler talcum powder 18 Modified montmorillonite masterbatch Polypropylene / montmorillonite graft intercalation blend 2 Nucleating agent β crystal nucleating agent Y-619 0.3 Thermal Oxygen Stabilizer DSTP octadecyl thiodipropionate 0.2 Antioxidant 1010 Tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]pentaerythritol ester 0.3 Antioxidant 168 Tris(2,4-di-tert-butylphenyl)phosphite 0.5

[0050] Dry mix the above materials in a high-speed mixer for 3-5 minutes, then melt and extrude them in a twin-screw extruder, and granulate. Zone 200~210℃, Zone 4 210~215℃, Zone 5 210~215, Zone 6 210~215, Zone 7 215~225, Zone 8 215~225, Zone 9 21...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
melt flow indexaaaaaaaaaa
fluidityaaaaaaaaaa
Mohs hardnessaaaaaaaaaa
Login to view more

Abstract

The invention discloses a filled polypropylene composite material applied to a rapid forming component, comprising the following ingredients in parts by weight: 60-88 parts of polypropylene, 1-25 parts of a toughener, 10-30 parts of a mineral powder filler, 1-5 parts of nanofiller master batches, 0.3-0.5 part of a nucleator, 0.1-1.0 part of heat stabilizer DSTP, 0.1-1.0 part of antioxidant 1010, and 0.1-0.5 part of antioxidant 168. The filled polypropylene composite material applied to a rapid forming component provided by the invention has the advantages of being good in material flowability, low in shrinking rate, good in dimensional stability, and capable of reducing apparent defects such as tiger skin strips; and moreover, a process for preparing the filled polypropylene composite material applied to a rapid forming component is simple and low in cost.

Description

technical field [0001] The invention relates to a polymer material, more specifically, to a polypropylene composite material. Background technique [0002] Polypropylene (PP) is one of the fastest growing varieties in the plastics industry. It has the advantages of good mechanical properties, light specific gravity, non-toxicity, corrosion resistance, easy processing, etc., and the raw materials are easy to obtain and low in price, so it has been widely used in the fields of home appliances, automobiles, and packaging. At present, the market competition of modified polypropylene materials is fierce, and many researchers improve their competitiveness by improving production efficiency, that is, increasing the injection molding rate of materials. However, there are not many reports in this area at present. Some reports disclose high-gloss rapid prototyping polypropylene and its preparation method. It increases the molding rate by adding a nucleating agent; Qilu Branch of Chin...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/14C08L23/08C08L23/16C08K13/06C08K9/04C08K3/34C08K3/26C08J3/22B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/92B29C2948/92561B29C2948/92704B29C2948/92895
Inventor 翁永华汪理文丁贤麟
Owner SUZHOU RUNJIA ENGINEER PLASTIC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products