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Preparation method for copper-steel composite

A composite material and copper plate technology, which is applied in metal material coating process, metal rolling, coating, etc., can solve the problems of large plate-shaped parts that are difficult to be uniformly combined, coarse structure, interface corrosion, etc., and achieve small reduction , Low composite temperature, little effect

Inactive Publication Date: 2012-09-19
JIANGSU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The basic process of the reverse solidification method is: make a thin master tape of a certain thickness pass through a molten metal pool with a certain height and superheating degree vertically at a certain speed. When the cold master tape is introduced into the molten metal pool, the temperature of its surface The temperature of the dry metal liquid is much lower, so the metal melt solidifies and grows on the parent strip; since the solidified layer metal liquid can be different from the parent strip, this process is also suitable for the production of composite materials; the liquid-solid phase rolling method is the Northeastern University A composite new technology started to be developed in the late 1980s. At present, the construction of the stainless steel / aluminum composite strip pilot production line and the laboratory research work on the steel / copper composite strip have been completed; the liquid metal (copper or copper Alloys) are continuously cast on the steel strip and enter the rolling mill at the same time as the solid steel strip to undergo deformation, and realize the metallurgical bonding of the interface under pressure; the liquid-solid phase rolling composite technology is based on the rapid non-equilibrium solidification of liquid metal Solidification is characterized by direct plastic forming, which can effectively control the direction and limit of complex interfacial reactions of dissimilar metals, such as diffusion, dissolution, formation and growth of new phases, and thus ensure a good combination of composite interfaces; however, the above two new Due to the problem of high temperature oxidation of steel, the composite method is still in the research and development stage; the casting method is easy to cause interface corrosion, it is difficult to uniformly combine when manufacturing large plate-shaped parts, and the structure is coarse and uneven

Method used

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  • Preparation method for copper-steel composite
  • Preparation method for copper-steel composite
  • Preparation method for copper-steel composite

Examples

Experimental program
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Effect test

Embodiment 1

[0019] Through the conventional hot-dip galvanizing method, degrease, derust, dip in the plating solution, and dry the surfaces of the steel plate and copper plate to be laminated, and dip a layer of zinc with a thickness of 10 μm in the zinc solution at 450 ° C. Spray water-based graphite paint on the non-dipping surface and dry it for protection; heat the galvanized steel plate and copper plate galvanized surface to 450°C under the protection of static hydrogenation nitrogen containing 0.2 vol.% hydrogen, keep it warm for 10 minutes, and then In the case of a reduction of 5%, the copper-steel composite material was obtained by rolling through two rolls successively, and holding time at 550°C for 2.0h.

[0020] figure 1 For photos of copper-steel composites, figure 2 It is an SEM photo of the copper-steel composite interface; it can be seen from the figure that the copper-steel interface is well bonded, and the test of the interface bonding strength shows that the tensile s...

Embodiment 2

[0022] Through the conventional hot-dip galvanizing method, degrease the surface of the steel plate and copper plate to be laminated, derust, dip in the plating solution, dry, and dip-coat in a zinc-aluminum alloy (Zn-5wt%) melt at 440 ° C for a period of time. For zinc-aluminum alloys with a layer thickness of 8 μm, spray water-based graphite coating on the non-dip-coated surface before immersion plating and dry it for protection; Heated to 500°C under the protection of hydrogenation and nitrogen, and held for 8 minutes, and then rolled through two rolls successively at a reduction of 5%, and held at 550°C for 1.5 hours to obtain a copper-steel composite material. Analysis shows that, The copper-steel interface is well bonded, and the tensile strength of the copper-steel composite interface reaches 90MPa.

Embodiment 3

[0024] Through the conventional hot-dip galvanizing method, degrease, derust, dip in the plating solution, and dry the surfaces of the steel plate and copper plate to be laminated, and dip-coat a layer of zinc with a thickness of 3 μm in a zinc melt at 460 ° C. Before dip-plating Spray alcohol-based graphite paint on the non-dipping surface for protection; heat the galvanized steel plate and copper plate galvanized surface to 550°C under the protection of static hydrogenation nitrogen containing 0.5vol.% hydrogen, keep it warm for 5min, and then press the amount In the case of 10%, the copper-steel composite material is obtained by rolling with two rolls successively at 600 ° C for 1.0 h. The analysis shows that the copper-steel interface is well bonded, and the tensile strength of the copper-steel composite interface reaches 95MPa .

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Abstract

The invention relates to a bimetal composite, in particular to a composition method for copper or copper alloys on the surface of steel. Steel and copper can be both compounded with zinc or zinc alloys with a low melting point effectively, a layer of zinc is plated on the surface of each of a copper plate and a steel plate by a hot-dip method, the zinc is heated to a temperature higher than the melting point of zinc under protection of gases, the copper plate and the steel plate are pressed together under pressure, liquid thin zinc layers on the surfaces of the plates are compounded and diffused mutually by thermal insulation, and accordingly composition of steel and copper is achieved.

Description

technical field [0001] The invention relates to bimetal composite materials, in particular to a method for compounding copper or copper alloy on the surface of steel. technical background [0002] Copper and copper alloys have excellent electrical conductivity, thermal conductivity and wear resistance, and are widely used in industries such as electric power, electrical appliances, electronics, heat transfer, information, automobiles, and home appliances; in the world's resource reserves, copper resources are relatively scarce, so , Replacing copper with other metals is a great strategy to save copper resources; in order to maximize the performance of metal materials, one of the methods is to combine materials with different properties to make composite materials; copper-steel Composite materials are copper or copper alloys on the surface of steel to form bimetallic composite materials. Because this composite material has the advantages of anti-corrosion, anti-wear, excellen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B21B1/38C23C2/06
Inventor 陈刚赵玉涛杨涛
Owner JIANGSU UNIV
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