Preparation method for 3,4'dichloro diaryl ether
A technology of dichlorodiphenyl ether and m-dichlorobenzene, applied in 3 fields, can solve problems such as affecting product quality and yield, and achieve the effects of improving product quality, reducing pollution and fast reaction speed
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0040] A kind of 3, the preparation of 4' dichlorodiphenyl ether, its step is as follows:
[0041] (1) Preparation of potassium methoxide
[0042] Add 50L of petroleum ether (pre-dried) and 10kg of potassium metal into a 200L stainless steel reactor, and start stirring. Add 50L of anhydrous methanol dropwise within 2h. Reflux for 1 hour after the dropwise addition, and cool. A white paste potassium methoxide solution was obtained.
[0043] (2) Preparation of potassium p-chlorophenate
[0044] Add 40L of self-made potassium methoxide solution and 26kg of p-chlorophenol into a 200L stainless steel reaction kettle, pass nitrogen gas under stirring, react for 0.5h, and then heat up to 100°C to distill off the solvent to obtain white anhydrous potassium phenolate.
[0045] (3) Preparation of cuprous chloride
[0046] Add copper oxide to saturated sodium chloride hydrochloric acid solution, react at 100°C, then add copper powder, and stir until the solution becomes colorless an...
Embodiment 2
[0050]A kind of 3, the preparation of 4' dichlorodiphenyl ether, its step is as follows:
[0051] (1) Preparation of potassium methoxide
[0052] Add 50L of petroleum ether (pre-dried) and 10kg of potassium metal into a 200L stainless steel reactor, and start stirring. Add 50L of anhydrous methanol dropwise within 2h. Reflux for 1 hour after the dropwise addition, and cool. A white paste potassium methoxide solution was obtained.
[0053] (2) Preparation of potassium p-chlorophenate
[0054] Add 40L of self-made potassium methoxide solution and 26kg of p-chlorophenol into a 200L stainless steel reaction kettle, pass nitrogen gas under stirring, react for 0.5h, and then heat up to 100°C to distill off the solvent to obtain white anhydrous potassium phenolate.
[0055] (3) Preparation of cuprous chloride
[0056] Add copper oxide to saturated sodium chloride hydrochloric acid solution, react at 100°C, then add copper powder, and stir until the solution becomes colorless and...
Embodiment 3
[0060] A kind of preparation method of 3,4' dichlorodiphenyl ether, its step is as follows:
[0061] (1) Preparation of sodium methoxide
[0062] Add 50L of petroleum ether (pre-dried) and 6kg of metallic sodium into a 200L stainless steel reactor, and start stirring. Add 50L of absolute ethanol dropwise within 2h. Reflux for 1 hour after the dropwise addition, and cool. A white paste potassium methoxide solution was obtained.
[0063] (2) Preparation of potassium p-chlorophenate
[0064] Add 40L of self-made potassium methoxide solution and 26kg of p-chlorophenol into a 200L stainless steel reaction kettle, pass nitrogen gas under stirring, react for 0.5h, and then heat up to 100°C to distill off the solvent to obtain white anhydrous potassium phenolate.
[0065] (3) Preparation of cuprous chloride
[0066] Add copper oxide to saturated sodium chloride hydrochloric acid solution, react at 100°C, then add copper powder, and stir until the solution becomes colorless and tr...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com