Inorganic colorful electrolysis coloring technology for aluminium profile anodic oxide film
An anodic oxidation film, electrolytic coloring technology, applied in the direction of electrolytic coating, surface reaction electrolytic coating, coating, etc., can solve the problems of easy pulverization, etc., achieve the effect of low production cost, fast coloring, and easy popularization and application
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Embodiment 1
[0040] The 6063-T5 aluminum alloy test piece (rectangular thin plate with a specification of 200mm×15mm) was routinely degreased, alkali-etched, neutralized and light-emitting, washed in NaOH solution at 60°C, and then heated at a concentration of 190 g / L In the sulfuric acid solution, the temperature is controlled at 18±2°C, the DC voltage is 15 volts, and the current density is 1.3 A / dm 2 , for 25 minutes of anodic oxidation treatment to obtain an oxide film of about 12um, and finally washed with water and set aside.
[0041] Then carry out electrolytic coloring treatment in the electrolytic coloring solution, the composition of the electrolytic coloring bath and the color index after coloring are listed in Table 1. This part of the operation will go through the following four steps, as follows:
[0042] 1. DC segment: Set the power supply voltage to DC output mode, then increase the voltage from 0V to 11V within 0-10 seconds, and then keep the voltage value at 11V for 20 ...
Embodiment 2
[0051] The specific steps are basically the same as in Example 1, except that step 3 is properly adjusted: the holding time at 13V direct current is changed from 60 seconds to 355 seconds. After the above steps, the surface of the workpiece can be dark green, and then the conventional Seal the hole at medium temperature and soak in the sealing solution for 30 minutes. After various tests, it shows that the color reproducibility of the colored oxide film is good, the color difference deviation is small (ΔE≤3.5), and the prepared dark green aluminum alloy profile products have all properties The indicators are all in line with the requirements of the national standard GB5237.2-2008. The 313B fluorescent ultraviolet lamp is used to test the artificial accelerated aging test. After 300 hours of irradiation, the color difference reaches grade 1, and the aging resistance is better than that of spray-coated aluminum profiles.
Embodiment 3
[0053] The specific steps are basically the same as in Example 1, except that step 3 is appropriately modified: the holding time at 13V direct current is changed from 60 seconds to 425 seconds. After the above steps, the surface of the workpiece can be made purple-red, and then the conventional method is used. Seal the hole at medium temperature and soak in the sealing solution for 30 minutes. After various tests, it shows that the color reproducibility of the colored oxide film is good, the color difference deviation is small (ΔE≤3.5), and the prepared purple-red aluminum alloy profile products have all properties The indicators are all in line with the requirements of the national standard GB5237.2-2008. The 313B fluorescent ultraviolet lamp is used to test the artificial accelerated aging test. After 300 hours of irradiation, the color difference reaches grade 1, and the aging resistance is better than that of spray-coated aluminum profiles.
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