2, 6-di(aryl)-anthraquinone and preparation method thereof

Abstract

The invention relates to 2, 6-di(aryl)-anthraquinone and a preparation method thereof, the preparation method comprises the following steps: connecting electron donor or electron acceptor groups to the two sides of an anthraquinone ring in the 2 and 6 positions, and enabling a 2, 6-dibromo anthraquinone type derivative and a substituent group containing a vinyl group to generate an Heck reaction in alkaline conditions under the catalytic action of palladium acetate and tri-O-methoxy phosphorus for generating the 2, 6-di(aryl)-anthraquinone, and the general formula of the molecular structure of the 2, 6-di(aryl)-anthraquinone is shown in the specification, wherein R is the substituent group containing the vinyl group, the electron donor group or the electron acceptor group. As the compound has the larger conjugate plane and simultaneously has better photochemical stability, thermal stability and solubility, the compound can better capture multiple photons and excite the generation of multi-photon absorption and nonlinear absorption phenomena, and further meet the application requirements in the aspects of photoelectric conversion materials, nonlinear absorption materials and the like.

Description

technical field [0001] The invention relates to a class of symmetrical anthraquinone derivatives, especially a 2,6-bis(aryl)-anthraquinone and a preparation method thereof, which can meet various application requirements of photoelectric conversion materials and nonlinear absorption materials, etc. . Background technique [0002] In recent years, due to the huge application of organic multiphoton absorbing materials in photonics and biomedicine, many scientists have designed new organic molecules with large molecular conjugated systems for them. As early as 1931, Mayer theoretically predicted the existence of this nonlinear phenomenon {see references: [1]P.N.Prasad, D.R.Ulrich, Nonlinear Optical and Electroactive Polymers[M].NewYork, Plenum, 1988.}, and with the development of science and technology The phenomenon of multi-photon absorption has also been discovered and confirmed one by one by scientists in the experimental process {see reference [2]: W.Kaiser, C.G.B.Garr...

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Problems solved by technology

[0004] In recent years, there have been many reports on the preparation and synthesis of organic materials with macromolecular conjugated systems {X.Wang, D.M.Nguyen, C.O.Yanez, L.Rodriguez, H.Y.Ahn, M.V.Bondar, and K.D.Belfield, J. Am.Chem.Soc.2010, 132, 12237}, but in some reported compounds, their photochemical stability is not strong, especially in the process of preparing thin films, it is easy to decompose, thus restricting the molecular compounds of this type Application of Thin Films in Device Field

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