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Aqueous transfer glue and preparation method thereof

A transfer glue, water-based technology, applied in adhesive types, non-polymer adhesive additives, adhesive additives, etc., can solve problems such as poor leveling, high latex film-forming temperature, and increased surface tension, and achieve The effect of simple process and low cost

Inactive Publication Date: 2011-09-21
上海奇想青晨新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to address the above problems, carry out the molecular design of the acrylate emulsion, optimize various additives, thereby providing a water-based transfer adhesive, which can completely meet the requirements of the cigarette pack processing factory for the adhesive itself At the same time, the present invention also starts from molecular design and solves the problem of poor leveling of water-based transfer adhesives in winter due to increased surface tension and high minimum film-forming temperature of latex

Method used

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  • Aqueous transfer glue and preparation method thereof
  • Aqueous transfer glue and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] (a) Add 260.0kg of deionized water, 4kg of emulsifier (ie 3.00kg of CO-458 and 1kg of DB-45) and 0.5kg of buffer (baking soda) into the reactor, stir and heat up to 65~ After 75°C, mixed raw materials are obtained;

[0037] (b) Add 213.30kg of deionized water and 6.2kg of emulsifier (ie 4.70kg of CO-458 and 1.50kg of DB-45) into the pre-emulsification tank, stir for 0 to 20 minutes, then add 18kg of acrylic acid in turn under stirring , 10kg hydroxyethyl acrylate, 239kg methyl methacrylate, 173kg butyl acrylate and 60kg 2-ethylhexyl acrylate, stirred at 20°C for 60 minutes to obtain a pre-emulsion, and 35kg of it was taken out as a seed solution;

[0038] (c) Warm up the mixed raw materials in the polymerization kettle of step a to 60° C., after adding the seed liquid in step b, after stabilizing for 2 to 15 minutes, add the aqueous solution of the persulfate initiator (for the formula, see “Components in Table 1 Three: bottom initiator solution A"), after 5 to 10 minu...

Embodiment 2

[0043] The preparation steps are the same as in Example 1, and the formula and process conditions are shown in Table 1 and Table 2.

Embodiment 3

[0045] The preparation steps are the same as in Example 1, and the formula and process conditions are shown in Table 1 and Table 2.

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Abstract

The invention relates to an aqueous transfer glue which is prepared through an emulsion polymerization with methyl methacrylate, butyl acrylate monomer, acrylic acid 2- Octyl Nitrite, a functional monomer, an initiator, an emulsifier buffering agent, a functional auxiliary agent, a PH adjusting agent and deionized water. The invention also provides the preparation method of the aqueous transfer glue. The invention is characterized by simple technology, low cost, environment friendliness and the ultimate product meets the 16 limitation requirements on harmful substances in the tobacco industry. Meanwhile, the golden paperboard and silver paperboard prepared from the aqueous transfer glue provided in the invention have better flexibility resistance and brightness than those of the products currently for sale. In particular, regarding to help with the limitation of harmful substances, the aqueous transfer glue is far better than the carboxylated styrene-butadiene rubber latex used in the current tobacco package industry.

Description

technical field [0001] The invention relates to an adhesive and a preparation method thereof, in particular to a water-based transfer adhesive used for preparing various gold cardboards and silver cardboards by a transfer method and for compounding laser films and various papers and a preparation method thereof. Background technique [0002] Transfer glue is an important adhesive for preparing gold cardboard, silver cardboard, laser film and various paper composites. Although the transfer adhesive has long been water-based, but at present, carboxylated styrene-butadiene emulsion is mostly used. The most representative product is the product of the German BASF company. The carboxylated styrene-butadiene transfer adhesive produced by BASF has always dominated the Chinese cigarette pack industry. The performance is very excellent, but with the increase in the limit requirements of harmful substances in the tobacco industry, and the extremely stringent requirements for the adhes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/12C09J133/08C09J11/06
Inventor 夏宇正刘国富赵永旗戚向东
Owner 上海奇想青晨新材料科技股份有限公司
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