Formaldehyde catalytic purification fibre and preparation method thereof

A catalytic purification and formaldehyde technology, which is applied in fiber treatment, fiber chemical characteristics, rayon manufacturing, etc., can solve the problems of low soaping degree of catalytic fibers, reduced mechanical properties of pores, and low reusability, etc., and achieves the removal rate of formaldehyde. Fast, easy weaving and molding, the effect of improving the utilization rate

Inactive Publication Date: 2013-01-02
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Secondly, there are two traditional methods for preparing catalytic fibers: one is the impregnation method, the catalyst required by the impregnation method must be a soluble chemical, the preparation process will cause air pollution, and the catalytic fiber prepared by the impregnation method has a low degree of soaping , low reusability
Another method is the solution electrospinning technology. Polymers that are insoluble in organic matter cannot be spun, and insoluble inorganic particles must be soluble polymers loaded with inorganic particles before they can be directly spun with polymers. Complicated, and the mechanical properties of the fibers obtained by solution electrospinning are significantly reduced due to the appearance of holes on the surface of the solvent volatilization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] MnO 2 Add catalytic particles to absolute ethanol and stir at high speed for 1-2 hours, then heat and stir to 80°C to obtain MnO 2 suspension, will account for MnO 2 The silane coupling agent with a mass fraction of 1% of the particles was added dropwise to MnO 2 In the suspension, continue to stir for 1-2 hours, filter and dry.

[0020] 100 parts of polypropylene, surface-treated MnO 2 20 parts of catalytic particles, 0.3 parts of antioxidant 1010, and 15 parts of polyester plasticizer are fully mixed, and spun by melt electrospinning equipment (spinning temperature: 220°C, spinning distance 12cm, spinning voltage 55kV).

Embodiment 2

[0022] MnO 2 Add catalytic particles to absolute ethanol and stir at high speed for 1-2 hours, then heat and stir to 80°C to obtain MnO 2 suspension, will account for MnO 2 The titanate coupling agent with a particle mass fraction of 1.2% was added dropwise to MnO 2 In the suspension, continue to stir for 1-2 hours, filter and dry.

[0023] 100 parts of polypropylene, surface-treated MnO 2 30 parts of catalytic particles, 0.4 parts of antioxidant 1010 and antioxidant 168 were added at a ratio of 3:1 and mixed thoroughly, and spun by melt electrospinning equipment (spinning temperature: 220°C, spinning distance 12cm, spinning voltage 65kV).

Embodiment 3

[0025] MnO 2 Add catalytic particles to absolute ethanol and stir at high speed for 1-2 hours, then heat and stir to 80°C to obtain MnO 2 suspension, will account for MnO 2 Silane coupling agent and titanate coupling agent (ratio: 1:1) with 1% particle mass fraction were added dropwise with MnO 2 In the suspension, continue to stir for 1-2 hours, filter and dry.

[0026] 100 parts of polypropylene, surface-treated MnO 2 30 parts of catalytic particles, 0.5 parts of antioxidant 1010, and 10 parts of polyester plasticizer are fully mixed, and spun by melt electrospinning equipment (spinning temperature: 210°C, spinning distance 10cm, spinning voltage 60kV).

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PUM

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Abstract

The invention relates to a formaldehyde catalytic purification fibre and a preparation method thereof. The catalytic fibre prepared according to the invention comprises the following required specific substance components in parts by mass: 100 parts of polymers, 20-50 parts of MnO2 catalytic particles, 0.2-1.5 parts of coupling agent, 0.1-0.5 part of antioxygen and 0-50 parts of plasticizer. The indoor formaldehyde catalytic fibre provided by the invention is not needed to be subjected to treatment on toxic organics, has no secondary pollution, is easy to industrially produce, is low in cost,is simple in preparation process, enables the utilization ratio of the catalyst to be increased, ensures high formaldehyde removal speed and removal ratio, is easy to weave and form, has high soapingdegree, and can be used for a long term; and abundant mineral products are used as the selected catalyst.

Description

technical field [0001] The invention relates to the use of melt electrostatic spinning technology and inorganic particle and polymer coupling technology to load inorganic catalytic particles on polymer nanofibers to prepare formaldehyde catalytic purification fibers, so as to have efficient performance of catalytic purification of indoor formaldehyde. Background technique [0002] First of all, most indoor formaldehyde catalysts are in powder state, which is easy to agglomerate, has a small contact area with formaldehyde, and has a low effective utilization rate. Moreover, powder catalysts are not easy to shape and are difficult to apply. Fiber curing technology can effectively solve these two problems. The higher specific surface area effectively increases the contact area between the catalyst and formaldehyde, the purification rate is improved, and the fiber is easy to weave, and can be prepared into products of various shapes. [0003] Secondly, there are two traditional ...

Claims

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Application Information

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IPC IPC(8): D01F1/10D01F6/46D01F6/92D01D5/00
Inventor 刘勇赵凤雯丁玉梅杨卫民
Owner BEIJING UNIV OF CHEM TECH
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