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Biodegradable cigarette fiber material and cigarette filter

A biodegradable, fiber material technology, applied in the direction of smoke oil filter, fiber treatment, fiber chemical characteristics, etc., can solve the problems of high brittleness, poor heat resistance, low thermal deformation temperature, etc., and achieve the effect of good biodegradation performance

Active Publication Date: 2011-06-01
海南海福新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this prior published patent application teaches that lactic acid polymers can be used in the processing of cigarette filters, and compared with commercialized cellulose acetate filter rods and polypropylene filter rods, the polylactic acid cigarette filter rods not only have The advantages of complete biodegradability and low production cost, and the filter rod made show good results in terms of filtration performance and physical and mechanical properties, but it can be seen from the contents of the description that the main resin used in this technical solution It is a mixture of one or more specifications of polylactic acid, or a copolymer of lactide and caprolactone, lactide, or lactide and caprolactone and glycolide, these resins are made of lactone Polymerization, the prepared polymer is a random polymer, this material is brittle and easy to hydrolyze, the water content of the material is required to be less than 0.5 / 10,000 during processing, and this material has poor heat resistance and thermal deformation The temperature is very low (less than 60°C)

Method used

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  • Biodegradable cigarette fiber material and cigarette filter
  • Biodegradable cigarette fiber material and cigarette filter
  • Biodegradable cigarette fiber material and cigarette filter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Take by weighing 100 kilograms of weight-average molecular weight of (15 ± 1) ten thousand, dispersion index is 1.5, and the non-lactone monomer copolymerization modified polystyrene containing 15% (number of chain segments) randomly distributed ethylene glycol chain segments on the molecular chain Lactic acid is the base resin, and the ratio by weight of modified polylactic acid: triphenyl phosphate: antioxidant 1222 (3,5-di-tert-butyl-4-hydroxyphenyl diethyl phosphate) is 97: 2.5: Weigh the raw material at a ratio of 0.5, dry it in an oven at 55°C for 5 hours, stir it evenly in a high-speed mixer, and then extrude and granulate it on a Φ57 twin-screw extruder with an aspect ratio of 32. The temperature of the screw barrel is set as: The first stage is 190°C, the second stage is 195°C, the third stage is 200°C, the fourth stage is 200°C, and the fifth stage is 190°C. The extruded strips are pelletized with a pelletizer, dried on-line with hot air, and packaged , to obt...

Embodiment 2

[0065] Select 99.6 kg weight average molecular weight of (10 ± 1) million, dispersion index of 1.2, and the molecular chain contains 1% (number of chain segments) randomly distributed ethylene glycol monomethyl ether chain unit copolymerization non-lactone monomer copolymerization Modified polylactic acid is used as the base resin, and 0.4 kg of triphenyl phosphite is dried in an oven at 45°C for 8 hours, and stirred evenly in a high-speed mixer. In an environment with a drying device, the length-to-diameter ratio is Extrude and granulate on the Φ75 twin-screw extruder at 32, the temperature of the screw barrel is set at 160°C for the first stage, 185°C for the second stage, 195°C for the third stage, 200°C for the fourth stage, and 200°C for the fifth stage 195°C. The extruded material strips are pelletized by a pelletizer, dried on-line with hot air, and packaged to obtain the special material for the cigarette holder rod of the present invention.

[0066] The special materia...

Embodiment 3

[0075] It is 300,000 to select the weight-average molecular weight, and the dispersion index is 3.0, and the copolymerization non-lactone monomer copolymerization modified polylactic acid containing 30% (chain number) of glycolic acid chain segments randomly distributed on the molecular chain is the base material resin. After drying in an oven at 50°C for 8 hours, spin on a Φ65 melt spinning machine with a screw length-to-diameter ratio of 28. The first stage of the screw temperature of the spinning machine is set to 190°C, and the second stage is set to 205°C. The third section is set at 220°C, the filter temperature is 200°C, the box temperature is 205°C, and the straight pipe temperature is 205°C. After being sprayed out from a spinneret with a specification of 1250×1, it is cooled by side blowing of dry air with a temperature range of 20 to 40°C.

[0076] The tow after above-mentioned cooling is coated with oil in the oiling tank, and the oiling in the oiling tank is the f...

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Abstract

The invention provides a biodegradable cigarette fiber material and a cigarette filter. The biodegradable cigarette fiber material comprises the following raw materials of 90-100 percent of polylactic acid modified by a non-lactone monomer through copolymerization and 0-10 percent of stabilizing agent as well as the balance of high polymer of the polylactic acid chain segments, wherein the polylactic acid modified by the non-lactone monomer through copolymerization is a non-lactone monomer chain segment in a molecular chain containing 1-30 percent of the total quantity of the chain segments, the weight-average molecular weight of the high polymer is 0.5-3.5 millions and the dispersion index of the high polymer is 1.2-3.0. The biodegradable cigarette fiber material is prepared from the raw materials through using a melting spinning process. The invention also provides a biodegradable cigarette filter rod prepared from the cigarette fibre material through sizing processing, and a cigarette product. The processing and using properties of the raw materials are remarkably improved. The provided cigarette filter has a property equivalent to the property of the traditional general cigarette filter, a cigarette end discarded by a smoker can be decomposed within shorter time in the natural environment, and the pollution of the cigarette waste to the environment is avoided at present while the requirement of cigarette production is met.

Description

technical field [0001] The invention relates to a fiber material for cigarettes and a cigarette filter made of the fiber material. The fiber material for cigarettes and the cigarette filter are based on polylactic acid (PLA) polymer modified by copolymerization of non-lactone monomers. Material resin with excellent biodegradability. Background technique [0002] Cigarette filters have the functions of filtering, blocking and absorbing harmful components such as nicotine and tar in smoke. In addition to the above functions, good filter materials should also be able to improve the taste of smoke, reduce the stimulation of smoke on the oral cavity and the human body. Health damage. As a relatively mature technology, the materials currently used to manufacture cigarette filters are generally made of cellulose acetate fiber and polypropylene fiber. Considering the processing performance and the comprehensive performance of the final filter tip, cellulose acetate fiber is the fir...

Claims

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Application Information

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IPC IPC(8): D01F6/92D01D5/00D02J1/22A24D3/08A24D3/02
CPCD01F6/84C08G63/08A24D3/068D01F1/02C08L67/04A24D3/08
Inventor 季君晖
Owner 海南海福新材料有限公司
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