Optical-use pressure-sensitive adhesive sheet
An adhesive sheet, optical technology, applied in the direction of optics, adhesive type, ester copolymer adhesive, etc., can solve the problem of peeling off the display and touch panel or lens, and achieve excellent twist adhesion and reliable adhesion sex enhancing effect
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[0102] When preparing the above-mentioned acrylic polymer, a polymerization initiator such as a thermal polymerization initiator or a photopolymerization initiator (photoinitiator) can be used depending on the type of polymerization reaction. The polymerization initiators may be used alone or in combination of two or more.
[0103] As the photopolymerization initiator, there is no particular limitation, and for example, benzoin ether photopolymerization initiators, acetophenone photopolymerization initiators, α-keto alcohol photopolymerization initiators, aromatic sulfonyl chloride photopolymerization initiators, and aromatic sulfonyl chloride photopolymerization initiators can be used. Polymerization initiators, photoactive oxime photopolymerization initiators, benzoin photopolymerization initiators, benzil photopolymerization initiators, benzophenone photopolymerization initiators, ketal photopolymerization initiators, thiazolin photopolymerization initiators xanthone-based ...
Embodiment 1
[0133] In a mixture of 70 parts by weight of 2-ethylhexyl acrylate (2EHA), 26 parts by weight of N-vinyl-2-pyrrolidone (NVP) and 4 parts by weight of N-hydroxyethylacrylamide (HEAA), Cooperate with 0.05 parts by weight of the trade name "Irgacure 184" manufactured by Ciba Specialty Chemical Co., Ltd. and 0.05 part by weight of the trade name "Irgacure 651" manufactured by Ciba Specialty Chemical Company as a photopolymerization initiator, and then irradiate ultraviolet light until the viscosity (BH type viscometer , No. 5 rotor, 10 rpm, measuring temperature 30° C.) was about 20 Pa·s, thereby producing a prepolymer composition in which the above-mentioned monomer components were partially polymerized.
[0134]0.05 parts by weight of an isocyanate-based crosslinking agent (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name "Coronet L") was added to 100 parts by weight of the above-mentioned prepolymer composition to prepare an acrylic adhesive. Composition for l...
Embodiment 2
[0139] As shown in Table 1, except that the addition amount of Coronet L and the thickness of the pressure-sensitive adhesive layer were changed, a prepolymer composition, a composition for forming an acrylic pressure-sensitive adhesive layer, and Double-sided adhesive sheet (double-sided adhesive sheet without substrate).
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