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Method for preparing ternary ethylene propylene vulcanized rubber powder master batches, products and application

An ethylene propylene vulcanizate and EPDM technology, applied in the chemical industry, can solve the problems of difficulty in antistatic rubber, time-consuming and energy consumption, and rising energy consumption, so as to improve the degree of dust pollution, avoid excessive processing, and improve performance. Benby's effect

Active Publication Date: 2011-03-23
上海西郊橡胶制品厂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are currently two main methods of recycling waste EPDM rubber products. One is the high-temperature dynamic desulfurization method. Although this method has the advantage of greater elongation, it has the disadvantages of emitting waste gas and requiring a lot of power for mechanical refining. The second is the simple addition of rubber powder, but this method has the disadvantage of poor compatibility between the rubber powder and the new rubber material. In order to solve this problem, it is usually added to the rubber material mixed with rubber powder. At the same time, add a high dose of softener, but the softener will be captured first by the new rubber material with high affinity, and it is not easy to enter the vulcanized rubber powder phase with high hardness. If the softener is to be in the new rubber phase and the rubber powder phase Reasonable matching requires more mixing and processing, which increases energy consumption
[0003] In addition, to make conductive or antistatic EPDM products, it is necessary to add a large amount of conductive auxiliary materials (such as conductive carbon black, acetylene carbon black, graphite powder). 1. Antistatic rubber is difficult. It is necessary to mix components such as conductive carbon black with high oil absorption value into the elastomer rubber. The processing process is not only time-consuming and energy-consuming, but also requires labor and black dust pollution.
[0004] At present, there is no technical solution in the industry to link the recycling of waste EPDM rubber with conductive or antistatic EPDM materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Embodiment 1, special glue for flooring in the car

[0025] (1-1), EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch preparation:

[0026] Get 100 parts by weight of 60 mesh EPDM vulcanized rubber powder EPDM vulcanized rubber powder,

[0027] 50 parts by weight of softening agent (paraffin oil);

[0028] Mix the above-mentioned materials with a high-speed mixer for 5 minutes, cool down and bag them after leaving the machine, and store them for a day and night for later use.

[0029] (1-2) For the special material for flooring in the car, the specific formula of the rubber material is:

[0030] EPDM 100 (parts by weight, the same below)

[0031] Take (1-1) EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch 300

[0032] Zinc oxide 5

[0033] stearic acid 2

[0034] Calcium carbonate 40

[0035] Carbon black 80

[0036] paraffin oil 50

[0037] Processing Aid AP 3

[0038] sulfur 1.8

[0039] Accelerator D 1

[0040] ...

Embodiment 2

[0046] Embodiment 2, other ethylene-propylene rubber special glue for flooring

[0047] (2-1), EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch preparation:

[0048] Get 100 parts by weight of 60 mesh EPDM vulcanized rubber powder EPDM vulcanized rubber powder,

[0049] 100 parts by weight of softening agent (machine oil);

[0050] Vulcanization system materials (containing sulfur, BZ, CZ, TMTD) 5 parts by weight

[0051] Mix the above-mentioned materials with a high-speed mixer for 5 minutes, pack them into 20kg bags after leaving the machine, and store them for a day and night for later use.

[0052] (2-2) For other special materials for ethylene-propylene rubber flooring, the specific formula of the rubber material is:

[0053] EPDM 100 (parts by weight, the same below)

[0054] Take (2-1) EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch 205

[0055]Zinc oxide 5

[0056] stearic acid 1

[0057] Carbon black 100

[0058] ...

Embodiment 3

[0063] Embodiment 3, adding EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch in the shock absorber

[0064] (3-1), EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch preparation:

[0065] Get 100 parts by weight of 60 mesh EPDM vulcanized rubber powder EPDM vulcanized rubber powder,

[0066] 10 parts by weight of softening agent (naphthenic oil);

[0067] Mix the above-mentioned materials with a high-speed mixer for 5 minutes, cool down and bag them after leaving the machine, and store them for a day and night for later use.

[0068] (3-2) Special material for ethylene-propylene rubber shock-absorbing parts, the specific formula of the rubber material is:

[0069] EPDM 100 (parts by weight, the same below)

[0070] Take (3-1) EPDM vulcanized rubber powder EPDM vulcanized rubber powder masterbatch 22

[0071] Zinc oxide 5

[0072] Stearic acid 0.5

[0073] naphthenic oil 40

[0074] Carbon black 80

[0075] DCP 4.5

[0076] T...

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PUM

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Abstract

The invention discloses a method for preparing ternary ethylene propylene vulcanized rubber powder master batches, products and application. The preparation method comprises the following steps of: mixing 40 to 100-mesh rubber powder of waste ternary ethylene propylene rubber and a large amount of softening agent or a softening agent and a vulcanization system material at normal temperature, and standing the mixture for one day and one night under common room temperature condition to obtain the ternary ethylene propylene vulcanized rubber powder master batch 1; or adding the ternary ethylene propylene vulcanized rubber powder master batch 1 into common ternary ethylene propylene mixing glue to obtain the ternary ethylene propylene vulcanized rubber powder master batch 2; or adding the ternary ethylene propylene vulcanized rubber powder master batch 1 into common conductive or antistatic ternary ethylene propylene mixing glue to obtain the conductive or antistatic ternary ethylene propylene vulcanized rubber powder master batch 3. The ternary ethylene propylene vulcanized rubber powder master batches 1, 2 and 3 can be used as independent products. The products are applied to any rubber product of a rubber plate, a coiled material, a sealing element, a shock absorption piece and a rubber roller of any one or a combined system rubber material of ternary ethylene propylene rubber and butyl rubber, wherein the tensile strength of the rubber product is 1.8 to 18MPa.

Description

technical field [0001] The invention belongs to the field of chemical industry, and relates to EPDM vulcanized rubber powder, which relates to the utilization of waste rubber powder and the technology of formulating rubber products. technical background [0002] my country is a country with poor rubber resources. Today, when we pay attention to sustainable and harmonious development, people pay more and more attention to environmental protection and the regeneration of waste rubber. As a high-performance special rubber widely used in my country, EPDM rubber is currently It mainly relies on imports, and its recycling is more valuable in the field of special rubber products. However, there are currently two main methods of recycling waste EPDM rubber products. One is the high-temperature dynamic desulfurization method. Although this method has the advantage of greater elongation, it has the disadvantages of emitting waste gas and requiring a lot of power for mechanical refining...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08K13/02C08K3/04C08K5/01C08J3/24C08J11/04
CPCY02P20/143Y02W30/62
Inventor 卢少云鱼伟令陈余方
Owner 上海西郊橡胶制品厂
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