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Novel silicon carbide ceramic and preparation method thereof

A silicon carbide ceramic and silicon carbide technology are applied in the field of new silicon carbide ceramics and their preparation, which can solve the problems of free silicon and high production costs in ceramics, and achieve the effects of reducing the pressure of processing waste, saving resources and reducing costs.

Inactive Publication Date: 2011-02-02
HENAN XINDAXIN SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Although the existing production process of silicon carbide ceramics can satisfy the performance of silicon carbide ceramics, there are still the following problems: (1) The Achilles heel of reaction sintered silicon carbide ceramics is that the ceramics contain free silicon
The existence of free silicon restricts the application of reaction sintered silicon carbide ceramics in high temperature (greater than 1500°C) and strong corrosion environment, so the lower the content of free silicon in reaction sintered silicon carbide ceramics, the better; (2) Pressureless sintered silicon carbide Although the performance of ceramics is good, its production cost is high

Method used

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  • Novel silicon carbide ceramic and preparation method thereof

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Embodiment 1

[0026] Embodiment 1: A kind of novel silicon carbide ceramics, the mass percent of its main material is composed of: 80% silicon carbide powder, 10% silicon powder and 10% carbon powder, and its auxiliary material is polyvinyl alcohol and polyethylene glycol, polyethylene The consumption of alcohol is 1% of the main material gross mass, and the total mass of polyethylene glycol is 0.5% of the main material gross mass;

[0027] Carry out the following steps in sequence during preparation:

[0028] (1) Prepare silicon carbide powder, a. Soak the silicon carbide waste material with an acid solution with a pH of 1 for 8 hours to remove metal and oxide impurities, and then soak with an alkaline solution with a pH of 11 for 2 hours to remove silicon dioxide; B, disperse the product of step a in water of 0.8 times its mass to form a suspension, adjust the pH of the suspension to 2, stir for 6 hours, filter, wash the filter cake with water until the washing liquid is neutral, and dry ...

Embodiment 2

[0034] Embodiment 2: A kind of novel silicon carbide ceramics, the mass percent of its main material is composed of: 90% silicon carbide powder, 6% silicon powder and 4% carbon powder, and its auxiliary material is carboxymethyl cellulose and tetramethyl hydrogen Ammonium oxide, the amount of carboxymethyl cellulose is 5% of the total mass of the main ingredients, and the total mass of tetramethylammonium hydroxide is 1% of the total mass of the main ingredients;

[0035] Carry out the following steps in sequence during preparation:

[0036] (1) Prepare silicon carbide powder, a. Soak the silicon carbide waste material in an acid solution with a pH of 3 for 9 hours to remove metal and oxide impurities, and then soak in an alkaline solution with a pH of 12 for 3 hours to remove silicon dioxide; B, disperse the product of step a in water of 0.9 times its mass to form a suspension, adjust the pH of the suspension to 1, stir for 12 hours, filter, wash the filter cake with water un...

Embodiment 3

[0042] Embodiment 3: A kind of novel silicon carbide ceramics, the mass percent of its main material is composed of: 85% silicon carbide powder, 8% silicon powder and 7% carbon powder, and its auxiliary material is polyvinyl alcohol and carboxymethyl cellulose Mixture and aluminophosphate, the amount of the mixture of polyvinyl alcohol and carboxymethyl cellulose is 3% of the total mass of the main material, and the total mass of aluminophosphate is 1% of the total mass of the main material;

[0043] Carry out the following steps in sequence during preparation:

[0044] (1) Prepare silicon carbide powder, a. Soak the silicon carbide waste material in an acid solution with a pH of 5 for 10 hours to remove metal and oxide impurities, and then soak in an alkaline solution with a pH of 13 for 4 hours to remove silicon dioxide; b. Disperse the product of step a in water of 1 times its mass to form a suspension, adjust the pH of the suspension to 1.5, stir for 14 hours, filter, wash...

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Abstract

The invention belongs to the field of silicon carbide materials, and in particular relates to a novel silicon carbide ceramic and a preparation method thereof. The novel silicon carbide ceramic is prepared from main materials and auxiliary materials, wherein the main materials comprise the following components in percent by mass: 80 to 90 percent of silicon carbide powder, 6 to 10 percent of silicon powder and 4 to 10 percent of carbon powder; and the auxiliary materials comprise a binder and a dispersant, wherein the dosage of the binder is 1 to 5 percent based on the total mass of the main materials; and the dosage of the dispersant is 0.5 to 1 percent based on the total mass of the main materials. The silicon carbide ceramic prepared by the method has the characteristics of high performance, volume density of between 3.05 and 3.10 g / cm<3>, free silicon content of less than 5 percent, hardness of 90 to 93 HRA, and bending strength of between 400 and 450 MPa.

Description

technical field [0001] The invention belongs to the field of silicon carbide materials, and in particular relates to a novel silicon carbide ceramic and a preparation method thereof. Background technique [0002] Silicon carbide ceramics have high strength, high toughness, low creep, friction and wear resistance, corrosion resistance and good oxidation resistance, and its excellent mechanical properties, low thermal expansion coefficient and high thermal conductivity determine the carbonization Silicon ceramics have very good thermal shock resistance. In recent years, silicon carbide ceramics have been widely used in high-tech industries such as machinery, chemical industry, military industry, and energy. At present, industrial silicon carbide ceramics mainly adopt two methods: reaction sintering and pressureless sintering. [0003] The basic principle of reaction sintered silicon carbide is: under the action of capillary force, the reactive liquid silicon penetrates into ...

Claims

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Application Information

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IPC IPC(8): C04B35/622C04B35/565
Inventor 姜维海宋贺臣
Owner HENAN XINDAXIN SCI & TECH
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