Rare earth ion doped oxyhalogen silicate glass and preparation method thereof
The technology of silicate glass and rare earth ions is applied in the field of rare earth ion-doped oxyhalosilicate glass and its preparation, which can solve the problem of low scintillation efficiency of heavy metal halide glass, affecting scintillation light output, and poor short-wavelength transmittance. and other problems, to achieve the effect of improving flickering light output, high flickering efficiency, and good physical performance
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[0024] The present invention will be described in further detail below in conjunction with the embodiments of the drawings.
[0025] First, refer to Table 1. Table 1 shows the composition of a rare earth ion-doped oxyhalosilicate glass of the present invention. Table 2 shows a specific embodiment of the present invention. 4 groups of rare earth ion-doped oxyhalosilicate glass Recipe.
[0026] Table 1: Formula composition of rare earth ion doped halooxysilicate glass (mol%)
[0027] Make up
mol%
SiO 2
10~70
PbF 2
0~55
PbCl 2
0~50
AlF 3
0~20
Al 2 O 3
0~30
ZnF 2
0~10
Gd 2 O 3
1~20
Rare earth compound
0.1~10
[0028] Table 2: The formula (mol%) of the rare earth ion-doped halosilicate glass of specific example 4
[0029] Glass component (mol%)
Group 1
Group 2
Group 3
Group 4
SiO 2
40
45
30
29
PbF 2
42
44
47
30
AlF 3
12
4
10
10
Al 2 O 3
0
3
10
10
ZnF 2
4
2
0
0
PbCl 2
0
0
0
18
Gd 2 O 3
1
...
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