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Surface processing solution for manufacturing solid electrolytic capacitor

A solid electrolysis and surface treatment technology, which is applied in the direction of solid electrolytic capacitors, etc., can solve the problems that the coupling agent is limited to silane coupling agent, the lead-out rate of capacitor capacity is small, and cannot meet the requirements of high performance, so as to achieve wide application range and reduce Effects of Equivalent Series Resistance, Significant Economic and Social Benefits

Inactive Publication Date: 2010-09-01
FUJIAN GUOGUANG ELECTRONICS SCI & TECHCO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] When producing solid electrolytic capacitors in the prior art, chemical polymerization or chemical polymerization and electrochemical polymerization are directly used to prepare the conductive layer on the oxide film medium, so that the capacity of the capacitor produced in this way is often small, and the ESR is large, which cannot Meet high performance requirements
[0005] The Chinese invention applications No. CN1761007 and No. CN1761006 published on April 19, 2006 disclose a technical solution for manufacturing solid electrolytic capacitors by using coupling agent treatment. The capacity has been significantly improved, but its Coupling agent is limited to silane coupling agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Taking a solid aluminum electrolytic capacitor as an example, an oxide film dielectric aluminum oxide is formed on the surface of the aluminum core of the anode body, and a surface treatment solution is impregnated on the surface of the aluminum oxide to form a treatment layer. After that, a solid electrolyte layer polypyrrole is formed on the surface of the treatment layer, and a first cathode layer is formed on the outer surface of the solid electrolyte layer; a second cathode layer is formed on the outer surface of the first cathode layer to obtain a monolithic capacitor element, and then the capacitor element is assembled and assembled. Encapsulate to make a solid aluminum electrolytic capacitor, the same below.

[0014] The surface treatment solution is composed of ethyl titanate coupling agent, methanol organic solvent, and deionized water. The mass concentration of ethyl titanate coupling agent is 0.001%, the mass concentration of deionized water is 10.000%, and ...

Embodiment 2

[0017] The difference between Example 2 and Example 1 lies in the composition of the surface treatment solution. The composition of the surface treatment solution in Example 2 is an aluminate coupling agent, an acetone organic solvent, and deionized water. Wherein the mass concentration of aluminate coupling agent is 50%, the mass concentration of deionized water is 10.0%, and the rest is acetone.

Embodiment 3

[0019] The difference between Example 3 and Example 1 lies in the composition of the surface treatment solution. The composition of the surface treatment solution in Example 3 is a bimetallic coupling agent coupling agent, ether organic solvent, and deionized water. Wherein the mass concentration of the bimetallic coupling agent coupling agent is 20%, the mass concentration of deionized water is 20.0%, and the rest is ether.

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PUM

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Abstract

The invention provides surface processing solution for manufacturing a solid electrolytic capacitor. The surface processing solution at least comprises a coupling agent, wherein the coupling agent is used for connecting an anode surface oxidation film medium and a solid electrolyte in the solid electrolytic capacitor; the coupling agent is at least one of or combination of more of a titanate coupling agent, an aluminate coupling agent, a duplex metal coupling agent, a lignin coupling agent and a tin coupling agent; and the mass concentration of the coupling agent is 0.001 to 50 percent. Through the surface processing solution, the adhesion between the anode surface oxidation film medium and the solid electrolyte is more uniform and the adhering area and the adhering strength are larger, so that the capacity of the solid electrolytic capacitor is increased and the equivalent series resistance of the solid electrolytic capacitor is reduced; and at the same time, the protective effect on the anode surface oxidation film medium is better and the creepage qualification rate of the solid electrolytic capacitor is higher.

Description

【Technical field】 [0001] The invention relates to a solid electrolytic capacitor, in particular to a surface treatment solution for making a solid electrolytic capacitor. 【Background technique】 [0002] With the continuous development of science and technology, the market increasingly needs capacitors with small size, large capacity, low loss, low ESR, and high reliability. One of the ways to improve the performance of capacitors is to improve the conductivity, regularity, and stability of solid electrolytes. sex, flatness. In the production process, chemical oxidation or electrolytic oxidation polymerization is generally used to polymerize pyrrole, aniline, thiophene or its derivative monomers to form a solid electrolyte for electrolytic capacitors. Since the oxide film medium on the surface of the anode body and the solid electrolyte are two materials with different properties, it is difficult for the monomer of the solid electrolyte to attach to the surface of the oxide ...

Claims

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Application Information

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IPC IPC(8): H01G9/15
Inventor 张易宁何腾云
Owner FUJIAN GUOGUANG ELECTRONICS SCI & TECHCO
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