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Plastic composition and surface selective metallization process thereof

A plastic composition, selective technology, applied in metal material coating process, physical/chemical process catalyst, liquid chemical plating, etc., can solve the problems of poor coating adhesion, silver pollution, difficult to completely remove, etc. High, high coating adhesion effect

Active Publication Date: 2010-02-24
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, using this method for selective electroless plating involves the problem of silver pollution.
Since the silver nitrate, silver formate, silver acetate, silver propionate, and silver butyrate used in this patent are easy to decompose under sunlight and heat, it is easy to cause silver pollution in the non-laser radiation area during actual operation. Cleaning is also difficult to completely remove. After electroless copper plating, there will be some coatings on the non-laser radiation area on the surface of the substrate; in addition, by coating polyvinylpyrrolidone / silver colloid, and then using laser radiation to embed silver particles in the substrate, Cohesion of the coating is poor at the end of electroless plating

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] This example is used to illustrate the plastic composition and its surface selective metallization process provided by the present invention.

[0038] (1) Preparation of plastic composition: Weigh 1kg of ABS plastic particles (Dongguan Tongxin Engineering Plastics Co., Ltd., C2950) and 1kg of titanium dioxide powder, mix them evenly, and use an extruder (Nanjing New Era Mechanical and Electrical Industry and Trade Co., Ltd., XSD-35 ) to extrude, and then use an injection molding machine (Haitian Plastic Machinery Co., Ltd., HTF60W1) to inject to obtain a 4.5cm * 14.5cm ABS plastic composition base material, denoted as ABS-I.

[0039] (2) Substrate pretreatment: put the ABS-I prepared in step (1) into NaOH 1mol.L -1 、Na 2 CO 3 1mol.L -1 , 0.1mol.L -1 In the solution of sodium dodecyl sulfate, soak for 10 minutes at 50°C, take it out, wash it with deionized water, and then put it into the solution containing 1mol.L phosphoric acid -1 Soak in the solution for 10 minut...

Embodiment 2

[0045] This example is used to illustrate the plastic composition and its surface selective metallization process provided by the present invention.

[0046] Adopt the method identical with embodiment 1 to carry out selective metal electroless plating on plastic composition base material ABS-I surface, difference is: in the step (1), take by weighing 2kgABS plastic particles (Dongguan Tongxin Engineering Plastics Co., Ltd., C2950 ) and 20g of titanium dioxide powder. The prepared ABS plastic composition substrate is denoted as ABS-II.

[0047] According to the above method to obtain a plated piece, denoted as A2.

Embodiment 3

[0049] This example is used to illustrate the plastic composition and its surface selective metallization process provided by the present invention.

[0050] Adopt the method identical with embodiment 1 to carry out selective metal electroless plating to plastic composition base material ABS-I surface, difference is: in step (5), use infrared lamp (Shenzhen Anhongda Science and Technology Co., Ltd., PHILIPS infrared lamp tube IN R95E, wavelength 850nm) to replace the ultraviolet lamp adopted in Example 1, and the irradiation time was 10 min.

[0051] According to the above method to obtain a plated piece, denoted as A3.

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PUM

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Abstract

The invention provides a plastic composition and a surface selective metallization process thereof. The plastic composition comprises a high molecular polymer and a photocatalyst, wherein the mass ratio of the polymer to the photocatalyst is 1 to 100. The surface selective metallization process of the plastic composition comprises the following steps: performing laser etching on the surface of theplastic composition; putting the plastic composition after the laser etching into an aqueous solution containing a metal ion salt and a cavity sacrificial agent to perform photocatalysis reduction reaction so as to obtain a plastic composition with nanometer metal particles on the surface; and finally performing metal chemical plating. By adopting the plastic composition and the surface selectivemetallization process of the plastic composition, the bonding force of a plating layer and the chemical plating precision are very high.

Description

【Technical field】 [0001] The invention relates to a plastic composition and its surface selective metallization process. 【Background technique】 [0002] The circuit preparation of the traditional electronics industry and information industry mainly relies on chemical and photochemical methods. These methods must go through multiple processes such as photographic film, exposure, development and etching in the initial wiring process. With the rapid development of the electronic industry, higher requirements are put forward for the time, price and small-scale production capacity of product design and development. However, the traditional technology shows the disadvantages of too many processes and too long cycle time. [0003] Therefore, the laser direct writing technology in the electronics industry came into being. LPKF has invented a Laser Direct Structuring-LDS technology, which uses plastics added with a non-conductive organic metal compound as a raw material, and direct...

Claims

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Application Information

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IPC IPC(8): C08L101/00C08K3/22C08K3/30C08K3/24C23C18/31C23C18/20
CPCC23C18/22B01J37/16B01J35/004B01J35/39
Inventor 林信平宫清刘倩倩陈炎
Owner BYD CO LTD
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