Catalyst for using coal tar to prepare clean fuel oil by catalytic hydrogenation, preparation method and applications
A catalytic hydrogenation and coal tar technology, which is applied in the direction of catalyst activation/preparation, metal/metal oxide/metal hydroxide catalyst, physical/chemical process catalyst, etc., can solve the problems of complex processing technology and achieve simple process, Strong operability and stable performance
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Embodiment 1
[0026] Weigh 2.66g of aluminum sulfate and 56.84g of sodium silicate, dissolve them in 50g of deionized water to form an aqueous solution, add ammonia water dropwise to adjust the pH of the mixed solution to 8, and react at 40°C for 1.5 hours, then the product is filtered, washed, After drying and calcining at 550°C for 5 hours, the silica / alumina carrier A is obtained. For the specific preparation method, see CN 1184703A. The specific surface area of the carrier A is 320m 2 / g, the pore diameter is 6nm, and the pore volume is 0.7ml / g. Weigh 1.01g of sodium molybdate, 1.75g of cobalt nitrate, 1.56g of nickel chloride and 5.34g of sodium tungstate to make a mixed aqueous solution, impregnate it on 10g of carrier A by equal volume impregnation method, dry at 100°C for 12 hours, 500 ℃ roasting for 6 hours. The calcined carrier loaded with metal oxides was kneaded with 2.5g of kaolin solution and 0.3g of scallop powder, extruded on an extruder, and dried at 120°C for 5 hours,...
Embodiment 2
[0029] Weigh 1.64g of sodium metaaluminate and 41.7g of tetraethyl orthosilicate, the experimental procedure is the same as that of Example 1, prepare carrier B (see CN 1184703A for specific preparation method), the specific surface area of carrier B is 240m 2 / g, pore diameter 15nm, pore volume 0.65ml / g. Weigh 1.66g ammonium molybdate, 1.75g nickel nitrate, 2.19g cobalt oxalate and 5.58g ammonium paratungstate to prepare a mixed aqueous solution, impregnate 10g carrier B by equal volume impregnation method, dry at 20°C for 70 hours, and roast at 400°C for 10 hours . After cooling, it is kneaded with 5g of aluminum sol, and made into a spherical shape on a spheroid forming machine. After drying the spherical catalyst at 80°C for 24 hours, it is roasted in a muffle furnace. The roasting temperature is 300°C, and the roasting time is 12 hours to obtain clean coal tar. fuel oil catalyst. The composition of the final catalyst is: molybdenum oxide 9%, nickel oxide 3%, cobalt ...
Embodiment 3
[0032] Take by weighing 2.5g aluminum nitrate and 20wt% silica sol 100g, prepare silica / alumina carrier C according to the test procedure of embodiment 1 (see CN 1184703A for specific preparation method), the specific surface area of carrier C is 450m 2 / g, pore diameter 2nm, pore volume 0.3ml / g. Weigh 6.93g of molybdenum nitrate, 0.03g of cobalt carbonate, 2.37g of nickel sulfate and 3.88g of ammonium metatungstate to prepare a mixed aqueous solution, impregnate it on 10g of carrier C by equal volume impregnation method, dry at 120°C for 8 hours, and roast at 500°C 3.5 hours. After cooling, knead with 8g sodium carboxymethyl cellulose solution, extrude into strips on a strip forming machine, dry the strip catalyst at 120°C for 5 hours and then roast at 800°C for 3 hours to obtain a clean fuel oil catalyst made from coal tar. The composition of the final catalyst is: molybdenum oxide 15%, nickel oxide 4.5%, cobalt oxide 0.1%, tungsten oxide 13.7%, silicon oxide 40%, aluminu...
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