Method for preparing bromophenol
A technology for bromophenol and phenol, applied in the field of preparing bromophenol, can solve the problems of cumbersome catalyst preparation process, low para-selectivity of bromide, environmental pollution of hydrogen bromide, etc., and achieves short preparation cycle, low cost, improved The effect of catalytic activity
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Embodiment 1
[0021] Embodiment 1: prepare brominated phenol:
[0022] (1) Catalyst preparation: add a certain amount of activated carbon of 200 to 400 microns to 10% HNO 3 In the solution, heat and reflux for 1.5 hours until the activated carbon is just submerged, then cool, wash the activated carbon particles with water until the pH is neutral, filter with suction, dry at 120°C for 3 hours, and cool in a desiccator. Add 4g of activated carbon to 4g of phosphomolybdenum tungsten heteropoly acid aqueous solution with a mass concentration of 15%, soak overnight, dry in a drying oven at 90°C for 3h, and then cool in a desiccator to obtain phosphorus with a loading capacity of 15% activated carbon. Molybdenum tungsten heteropolyacid catalyst.
[0023] (2) Get above-mentioned catalyst 10g, mix with 2mol phenol, 2.2mol potassium bromide respectively, then add 4L mass concentration and be 99.5% acetic acid and 2.2mol mass concentration be 30% hydrogen peroxide (the molar number of hydrogen perox...
Embodiment 2
[0024] Embodiment 2: prepare bromophenol:
[0025] (1) Catalyst preparation: add a certain amount of activated carbon of 200 to 400 microns to 10% HNO 3 In the solution, heat and reflux for 1.5 hours until the activated carbon is just submerged, then cool, wash the activated carbon particles with water until the pH is neutral, filter with suction, dry at 120°C for 3 hours, and cool in a desiccator. Add 4g of activated carbon to 4g of 15% silicon-molybdenum-tungsten heteropoly acid aqueous solution, soak overnight, dry in a drying oven at 90°C for 3 hours, and then cool in a desiccator to obtain silicon with a loading capacity of 15% activated carbon. Molybdenum tungsten heteropolyacid catalyst.
[0026] (2) Get above-mentioned catalyst 10g, mix with 2mol phenol, 2.2mol potassium bromide respectively, then add 6L mass concentration and be 99.5% acetic acid and 3mol mass concentration be 30% hydrogen peroxide, stir vigorously at room temperature, react 5 After 1 hour, filter, ...
Embodiment 3
[0027] Embodiment 3: prepare bromophenol:
[0028] (1) Catalyst preparation: add a certain amount of activated carbon of 200 to 400 microns to 10% HNO 3 In the solution, heat and reflux for 1.5 hours until the activated carbon is just submerged, then cool, wash the activated carbon particles with water until the pH is neutral, filter with suction, dry at 120°C for 3 hours, and cool in a desiccator. 4g of activated carbon is added to 4g of phosphomolybdenum heteropoly acid aqueous solution with a mass concentration of 15%, soaked overnight, dried at 90°C for 3h in a drying oven, and then cooled in a desiccator to obtain a 15% activated carbon-loaded phosphomolybdenum heteropolyacid catalyst.
[0029] (2) Get above-mentioned catalyst 8g, mix with 2mol phenol, 2.2mol potassium bromide respectively, then add 2L mass concentration and be 99.5% acetic acid and 4mol mass concentration be 30% hydrogen peroxide, stir vigorously at room temperature, react 5 After 1 hour, filter, wash,...
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