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Silicon nano line/non crystal heterogeneous agglomeration solar battery

A technology of solar cells and silicon nanowires, applied in the field of solar energy, can solve the problems of instability, attenuation of photoelectric conversion efficiency, problems in the stability of amorphous silicon solar cells, etc.

Inactive Publication Date: 2008-09-10
BEIJING NORMAL UNIVERSITY
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Problems solved by technology

However, due to the instability of its internal structure and the existence of a large number of hydrogen atoms, amorphous silicon has light fatigue effect (Staebler-Wronski effect), so there are problems in the stability of amorphous silicon solar cells after long-term work, and its photoelectric conversion efficiency will decrease with Attenuation with the continuation of light time

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  • Silicon nano line/non crystal heterogeneous agglomeration solar battery

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Embodiment Construction

[0022] The present invention at first adopts the preparation method of the nano-silicon wire array that we propose, at first after the large-area nano-silicon wire array is prepared on the surface of the P-type silicon substrate, a metal aluminum film is deposited on the P-type silicon substrate surface by vacuum evaporation, After sintering, it is used as the back ohmic contact electrode. Then, plasma-enhanced chemical vapor deposition technology is used to deposit n-type hydrogenated amorphous silicon film (α-Si:H) on the surface of p-type silicon nanowires and their arrays to form a silicon nanowire / amorphous silicon three-dimensional radial p-n heterojunction , using magnetron sputtering technology to deposit a layer of indium tin oxide (ITO) transparent conductive film on the surface of silicon nanowire / amorphous silicon three-dimensional heterojunction. Then use the mask method to deposit Ti / Pd / Ag on the surface of the ITO conductive film as the front ohmic contact elect...

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Abstract

The invention discloses a solar battery device of a silicon nanowire array, which pertains to the technical field of solar batteries and is characterized in that a p-type silicon nanowire / an n-type three-dimensional amorphous silicon heterogenous junction layer is contained between a transparent indium tin oxide conductive film and a P-type silicon base layer. A solar conversion device comprises layers that are overlapped in sequence, namely, a Ti / Pd / Ag gridiron electrode serving as a frontal extraction electrode, a transparent ITO conductive film layer playing a role in transparence and serving as a frontal extraction electrode, an n-type amorphous silicon which is positioned above the p-type silicon nanowire forms a p-n heterogenous junction together with the P-type silicon nanowire; the P-type silicon nanowire is positioned above the P-type silicon base layer and forms the three-dimensional heterogenous junction together with the n-type amorphous silicon as well as serves as an antireflection layer of the solar battery, the P-type silicon base layer serves as a base area of the solar battery, the back electrode of an aluminum metal film serves as a back extraction electrode. The solar conversion device with the novel structure provided by the invention has strong capacity of light absorption and high photoelectric conversion efficiency.

Description

technical field [0001] The invention relates to a silicon nanowire solar battery device, which belongs to the technical field of solar energy. Background technique [0002] Facing the global energy shortage crisis and the continuous deterioration of the ecological environment, countries around the world are actively researching, developing and utilizing renewable energy, so as to realize the sustainable development of the energy industry and society. Among them, solar energy has become the focus of renewable energy due to its unique advantages. If 0.1% of the solar energy on the earth's surface is converted into electrical energy, the conversion rate is 5%, and the annual power generation can reach 5.6×10 12 A kilowatt-hour is equivalent to 40 times the current energy consumption in the world. Therefore, solar energy is considered to be the best solution to the energy crisis and the deterioration of the ecological environment. Experts at home and abroad predict that by 21...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/072H01L31/0747
CPCY02E10/50
Inventor 彭奎庆
Owner BEIJING NORMAL UNIVERSITY
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