Method for preparing morphology-controlled polyphenylethene/polyaniline conductive polymeric composite microspheres
A conductive polymer and polystyrene technology, applied in the direction of non-metallic conductors, organic material conductors, etc., can solve the problems of single shape, poor controllability of product shape and size, etc., and achieve the effect of controlling shape
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0023] Example 1. Using ammonium persulfate (APS) as an oxidizing agent, polystyrene / polyaniline conductive polymer composite microspheres with a core-shell structure were obtained.
[0024] 1) first prepare monodisperse polystyrene microspheres by the method of soap-free emulsion polymerization;
[0025] 2) Dissolve 0.3g of PS spheres synthesized in step 1) in 20ml of deionized water, and stir magnetically until a uniform emulsion is formed;
[0026] 3) Accurately measure 2ml of aniline monomer (0.02mol) into the above emulsion with a syringe, and stir magnetically at room temperature for 10 hours until a uniform solution is formed;
[0027] 4) 0.02mol of ammonium persulfate (E ox =2.0V) was dissolved in 15ml of distilled water, and placed in the refrigerator to refrigerate for 30 minutes, and the optimum molar ratio of ammonium persulfate and aniline monomer was tested to be 1:1;
[0028] 5) Add 5ml of the aqueous solution of the oxidizing agent in step 4) to the solution ...
Embodiment 2
[0031] Embodiment 2, with ferric nitrate (Fe(NO 3 ) 3 ) as an oxidant to obtain polystyrene / polyaniline conductive polymer composite microspheres with a sea urchin-like structure.
[0032] 1) first prepare monodisperse polystyrene microspheres of a certain diameter by the method of soap-free emulsion polymerization;
[0033] 2) Dissolve 0.3g of PS spheres synthesized in step 1) in 20ml of deionized water, and stir magnetically until a uniform emulsion is formed;
[0034] 3) Accurately measure 2ml of aniline monomer (0.02mol) into the above emulsion with a syringe, and stir magnetically at room temperature for 10 hours until a uniform solution is formed;
[0035] 4) Dissolve 0.08mol of ferric nitrate in 15ml of distilled water, and place it in the refrigerator for 30 minutes to refrigerate. The best molar ratio of ammonium persulfate and aniline monomer is determined to be 1:4;
[0036] 5) Add 5ml of the aqueous solution of the oxidizing agent in step 4) to the solution cont...
Embodiment 3
[0039] Embodiment 3, with ferric chloride (FeCl 3 ) as an oxidant to obtain polystyrene / polyaniline conductive polymer composite microspheres with a sea urchin-like structure.
[0040] 1) first prepare monodisperse polystyrene microspheres of a certain diameter by the method of soap-free emulsion polymerization;
[0041] 2) Dissolve 0.3g of PS spheres synthesized in step 1) in 20ml of deionized water, and stir magnetically until a uniform emulsion is formed;
[0042] 3) Accurately measure 2ml of aniline monomer (0.02mol) into the above emulsion with a syringe, and stir magnetically at room temperature for 10 hours until a uniform solution is formed;
[0043] 4) 0.1mol of ferric chloride was dissolved in 15ml of distilled water, and placed in the refrigerator for 30 minutes, and the optimum molar ratio of ammonium persulfate and aniline monomer was determined to be 1:5;
[0044] 5) Add 5ml of the aqueous solution of the oxidizing agent in step 4) to the solution containing an...
PUM
Property | Measurement | Unit |
---|---|---|
diameter | aaaaa | aaaaa |
diameter | aaaaa | aaaaa |
diameter | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com