Cashew phenol modified linetype phenolic resin and method for manufacturing composite laminated board
A technology of phenolic novolac resin and cashew phenol is applied in the field of manufacturing composite base laminates, which can solve the problem that the performance is difficult to meet the high-performance copper clad laminate, the heat resistance, flatness, and punching properties are not satisfied, and lead-free reflow soldering is not suitable. and other problems, to achieve the effect of excellent heat resistance, high heat resistance and high flatness
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specific Embodiment 1
[0023] In a 1000 ml four-necked flask, 210 grams of phenol, 90 grams of cardanol, 198 grams of formaldehyde, and 2.1 grams of hydrochloric acid were successively added. Then heat up to 98-100°C for boiling reaction for 2-3 hours, vacuum dehydration until the water is removed, remove the vacuum, add 230 grams of methanol to dissolve evenly, and obtain a novolac resin with a solid content of 52-55%. Use this resin and epoxy resin, flame retardant, whitening agent in proportion to make resin glue. Then use the glue to impregnate 130g / m 2 The bleached wood pulp paper is dried to obtain a paper-based prepreg with certain solubility and glue content. Combine 6 sheets of paper-based prepreg, 2 sheets of cloth-based prepreg, and 1 sheet of glue-coated copper foil, and press for 90 minutes at a temperature of 175°C and a unit pressure of 8mpa to obtain a 1.6mm composite-based copper-clad laminate as sample 1. Then test according to the national standard GB / T4723-1995.
specific Embodiment 2
[0024] In a 1000 ml four-necked flask, 240 grams of phenol, 70 grams of cashew phenol, 186 grams of formaldehyde, and 2.2 grams of hydrochloric acid were put into a 1000 milliliter four-necked flask, and the process of Example 1 was followed to obtain Sample 2. Test according to the same standard.
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