Environment-friendly type on-press-coating ink-jet CTP offset master, pigment ink and preparation method thereof
A pigment ink and pigment technology, which is applied in the field of environment-friendly bare-plate inkjet CTP offset printing plates, can solve the problems of polluting the environment, unfavorable environmental protection, affecting plate-making quality, etc., and achieves the effect of reducing plate-making costs, reducing printing costs, and shortening plate-making time.
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Embodiment 1
[0050] 12 grams of 50% acrylic acid-butyl acrylate copolymer emulsion (M=15000±200) with a molar ratio of acrylic acid: butyl acrylate=1:1.2, to which 4g of pigment black, 2g of OP-101% aqueous solution, 16g of ethylene glycol were sequentially added Alcohol, 10g polyethylene glycol, 2g hexamethylol melamine resin, 30g deionized water, stir for 30 minutes with a mixer with a rotating speed of 500 rpm, then stir with an emulsifier at a speed of 2000 rpm for 30 minutes, sand mill Machine pulverization for 80 minutes, finally adjust the pH value to 9, and filter with a 0.5-1μm microporous membrane to obtain black pigment ink. The physical properties of this ink at 20°C are as follows:
[0051] Surface tension 35mN / m,
[0052] Viscosity 3.5cp,
[0053] Particle size d=100nm,
[0054] Conductivity 1000US,
[0055] pH=9.0.
Embodiment 2
[0057] Add 8g of 50% styrene-ethyl acrylate copolymer emulsion M=(10000±150), molar ratio: styrene: ethyl acrylate=1.5:1, then add 7g of pigment black, 1g of OP-71% aqueous solution, 20g of ethylene glycol Alcohol, 15g n-butanol, 2g hexamethylol melamine resin, 24g deionized water, stir for 30 minutes with a mixer with a speed of 500 rpm, then stir for 60 minutes with an emulsifier with a speed of 10,000 rpm, and a sand mill Crush for 120 minutes, finally adjust the pH value to 8, and filter through a 0.5-1μm microporous membrane to obtain black pigment ink. The physical properties of this ink at 20°C are as follows:
[0058] Surface tension 40mN / m,
[0059] Viscosity 4.0cp,
[0060] Particle size d=130nm,
[0061] Conductivity 1200US,
[0062] pH = 8.0.
Embodiment 3
[0064] Add 17g of 50% maleic anhydride-methyl methacrylate copolymer (M=10000±150), molar ratio: maleic anhydride: methyl methacrylate=1:1, then add 8g of pigment black, 2g OP-1010% aqueous solution, 10g ethylene glycol, 15g polyethylene glycol, 1g hexamethylol melamine resin, 32g deionized water, stir for 30 minutes with a mixer with a speed of 500 rpm, and then use a mixer with a speed of 10000 rpm Stir at high speed with an emulsifier for 60 minutes, grind with a sand mill for 90 minutes, adjust the pH value to 9, and filter with a 0.5-1μm microporous membrane to obtain black pigment ink. The physical properties of this ink at 20°C are as follows:
[0065] Surface tension 35mN / m,
[0066] Viscosity 3.5cp,
[0067] Particle size d=105nm,
[0068] Conductivity 900US,
[0069] pH=9.0.
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