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Fast repairing material in use for flush type desulfurized for molten iron

A technology for desulfurization of molten iron and repair material, applied in the field of refractory materials, can solve the problems of erosion and peeling of the lining of refractory materials of appliances, insufficient hydration reaction of cement binder, and low bonding strength of repair layer, etc., to achieve suitable sintering performance, The effect of excellent thermal shock stability and good extrusion rheological properties

Inactive Publication Date: 2007-10-10
武钢集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these two desulfurization processes require the use of submerged molten iron desulfurization equipment. Due to the violent erosion of molten iron and frequent rapid cooling and rapid heating, the refractory lining of the equipment is eroded and peeled off, which seriously restricts the service life of the desulfurization equipment. The technical and economic indicators of desulfurization, in order to effectively extend the service life of desulfurization equipment, many domestic manufacturers have successively used refractory plastics to repair, such as the Chinese Invention Patent Publication No. CN1161301C discloses a refractory mixture that can be submerged into molten iron to repair the gun lining. The main components are mullite corundum clinker, containing Al 2 o 3 Not less than 70% of high alumina cement, refractory clay, at the same time, add chemical bonding agent as auxiliary bonding agent to improve the repair bonding strength of refractory mixture
However, due to the high temperature shrinkage of the plastic repair material, the repair layer shrinks and cracks and peels off; the hydration reaction of the cement binder under high temperature repair conditions is insufficient, resulting in low bond strength of the repair layer; poor thermal shock stability, resulting in thermal spalling of the repair layer; Expensive and so on

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Prepare 0.5 tons of fast repairing material, the components of the repairing material are by weight percentage: burnt gemstone 30 with a particle size of 1 to 3 mm, burnt gemstone 20 with a particle size of 0.15 to 1 mm, super high-alumina clinker 25 with a particle size of 180 mesh, and 25 with a particle size of 180 mesh refractory clay 25, aluminum dihydrogen phosphate 9, melamine 0.7, aluminum silicate fiber 1. The ordinary repair material for desulfurization spray gun and the repair material of the present invention were used to carry out comparative repair experiments and 1200°C water-cooled thermal shock experiments in the laboratory. The strength is high, the explosion-proof temperature is greater than 550°C, the number of water cooling at 1200°C is increased by 5 times, and the service life of the repair layer of the repairing material of the present invention is increased by 2 times compared with the original one.

Embodiment 2

[0030] Prepare 2 tons of quick castables, the components of the repairing material are by weight percentage: burnt gem 28 with a particle size of 1-3mm, burnt gem 20 with a particle size of 0.15-1mm, super high-alumina clinker 28 with a particle size of 180 mesh, and a particle size of 180-mesh refractory clay 24, water glass 8, calcium lignosulfonate 0.7, aluminum silicate fiber shavings 1, yellow dextrin 2. Through industrial tests, the service life of a single spray gun is stable at 110 times / piece and the soaking time is stable at more than 1000 minutes.

Embodiment 3

[0031] Example 3: Preparation of 0.1 ton of repairing material. The components of the repairing material are by weight percentage: burnt gem 25 with a particle size of 1 to 3 mm, burnt gem 29 with a particle size of 0.15 to 1 mm, and super high-alumina clinker 21 with a particle size of 180 mesh , refractory clay 19 with a particle size of 180 mesh, kyanite 6 with a particle size of 150 mesh, plus aluminum dihydrogen phosphate 8, yellow dextrin 2, calcium lignosulfonate 0.4, and aluminum lactate 0.5. Using ordinary repairing materials for desulfurization mixers and the repairing materials of the present invention, comparative repair experiments and 1200°C water-cooled thermal shock experiments were carried out in the laboratory. Experimental results show that, compared with ordinary repair materials, the repair materials of the present invention have excellent construction performance, high bonding strength, explosion-proof temperature greater than 550°C, and 3 times higher wat...

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Abstract

A material for fast repairing the submersible desulfurizing tool of molten iron is proportionally prepared from 6 raw materials including super-grade high-Al powder, refractory clay, adhesive, disperser, anti-exploding agent, etc. Its advantages are high heat shock stability, adhesion and resistance to stripping and flush.

Description

technical field [0001] The invention relates to a refractory material for molten iron desulfurization pretreatment submerged hot metal desulfurization equipment, in particular to a quick repair material for a spray gun or agitator used for molten iron injection or stirring desulfurization. Background technique [0002] In order to meet the market's requirements for the quality of iron and steel products, continuously reduce the production cost of iron and steel products, and improve the market competitiveness of iron and steel enterprises, many iron and steel enterprises at home and abroad have carried out desulfurization pretreatment on the molten iron in the steelmaking furnace to optimize the smelting process and reduce production costs. , Even for the production of ordinary carbon steel, the sulfur content of molten iron entering the furnace is required to be less than 0.020%, so as to improve the final quality of steel products. It can be seen that hot metal desulfuriza...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66C04B14/04C04B14/34C04B14/10C21C7/064
Inventor 欧阳德刚胡清明罗安智李具中胡铁山陈双全刘守堂张爱平周明石王海清
Owner 武钢集团有限公司
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