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Composite plate and preparation method thereof

a technology of composite plates and preparation methods, applied in the field of construction materials, can solve the problems of poor chemical resistance, high cost of stone plates obtained this way, and limited application, and achieve the effects of low raw material cost, good physical and chemical properties, and reduced raw material cos

Active Publication Date: 2021-01-14
FOSHAN YIXIN STONE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention is a composite plate made from recycled materials such as cullet, calcium carbonate, and resin. This reduces the cost of the raw materials and the preparation process. The combination of different particle sizes of all the materials results in good physical and chemical properties similar to those of artificial quartz stones. The invention also improves production efficiency by reducing the vibration frequency of the pressure plate during the vibration pressing process. Overall, this invention is a high-quality, cost-effective, energy-efficient, and environmentally friendly composite plate.

Problems solved by technology

The preparation of the sintered type is similar to the preparation of ceramic bricks, that is, it is obtained by firing at a high temperature; the cost of the stone plates obtained this way is high.
Although artificial granite is inexpensive, it has poor chemical resistance, thus its application is limited.
However, due to the gradual depletion of natural high-quality quartz, some researchers have introduced glass into the formula to replace part of the quartz.
However, due to the amorphous nature of glass, the pulverization of the glass results in a material that has a lot of corners and edges and has a large specific surface area, resulting in poor fluidity, thus more resin is required compared with using quartz.
In the aforementioned patent, the amount of resin is 8%-16%, which increases the cost of the artificial stone.
The excessively high resin content also reduces the mechanical properties of the artificial stone.
Established thinking of the person skilled in the art is that the addition of cullet greatly reduces the fluidity of the slurry, hence the plate is not uniform, its physical and chemical properties are also reduced.
However, heavy calcium carbonate is not hard, thus it reduces the mechanical properties of quartz stone plates.
However, it uses a combination of a variety of resins and the cost is thus high.
Summarizing the aforementioned prior art documents, there are several problems in artificial quartz stones of the prior art: 1. A significant amount resin is used, resulting in poor mechanical properties and high cost.
Quartz is used in abundance, resulting in high raw material cost.
Too many different types of raw materials give rise to a lot of early-stage processing steps and high manufacturing cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

embodiment 1

[0056]This embodiment provides a composite plate prepared from the following formula:

[0057]45% cullet, 38% calcium carbonate, 15% unsaturated polyester resin, 1% curing agent, 1% auxiliary agent;

[0058]wherein the curing agent is t-butyl peroxybenzoate and the auxiliary agent is a titanate coupling agent.

[0059]The cullet has a particle size ranging from 130 to 150 mesh, the calcium carbonate has a particle size ranging from 280 to 300 mesh.

[0060]Preparation:

[0061](1) Each raw material was prepared according to the formula.

[0062](2) Various raw materials were mixed uniformly to obtain a base material.

[0063](3) The base material was subjected to vibration pressing to obtain a plate clay body, wherein the vibration pressing frequency was 30 Hz, the time was 5 min.

[0064](4) The plate clay body was heat-cured at 80° C. to obtain the composite plate product.

embodiment 2

[0065]This embodiment provides a composite plate prepared from the following formula:

[0066]49.8% cullet, 45% calcium carbonate, 5% unsaturated polyester resin, 0.1% curing agent, 0.1% auxiliary agent;

[0067]wherein the curing agent is benzoyl peroxide and the auxiliary agent is an aluminate coupling agent.

[0068]The cullet has a particle size ranging from 40 to 50 mesh, the calcium carbonate has a particle size ranging from 380 to 400 mesh.

[0069]Preparation:

[0070](1) Each raw material was prepared according to the formula.

[0071](2) Various raw materials were mixed uniformly to obtain a base material.

[0072](3) The base material was subjected to vibration pressing to obtain a plate clay body, wherein the vibration pressing frequency was 40 Hz, the time was 2 min.

[0073](4) The plate clay body was heat-cured at 90° C. to obtain the composite plate product.

embodiment 3

[0074]This embodiment provides a composite plate prepared from the following formula:

[0075]51% cullet, 41.8% calcium carbonate, 6% unsaturated polyester resin, 0.7% curing agent, 0.5% auxiliary agent;

[0076]wherein the curing agent is t-butyl peroxy-2-ethylhexanoate and the auxiliary agent is γ-methacryloxypropyltrimethoxysilane.

[0077]The cullet has a particle size ranging from 100 to 120 mesh, the calcium carbonate has a particle size ranging from 300 to 320 mesh.

[0078]Preparation:

[0079](1) Each raw material was prepared according to the formula.

[0080](2) Various raw materials were mixed uniformly to obtain a base material.

[0081](3) The base material was subjected to vibration pressing to obtain a plate clay body, wherein the vibration pressing frequency was 45 Hz, the time was 2 min.

[0082](4) The plate clay body was heat-cured at 90° C. to obtain the composite plate product.

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Abstract

A composite plate is mainly made from the following raw materials in percentage by weight: 35% to 45% of calcium carbonate, 45% to 55% of cullet, 5% to 15% of unsaturated polyester resin, 0.1% to 1% of a curing agent, 0.1% to 1% of an auxiliary agent, wherein a ratio of an amount of the calcium carbonate to an amount of the cullet is 0.75%. The invention employs cullet, calcium carbonate, and resin as the main raw materials to prepare an artificial stone plate; no natural quartz is used, and hence the raw material cost is low. A reasonable ratio of cullet to calcium carbonate reduces the use of resin, which further reduces the raw material cost. Through a reasonable combination of different raw materials, the composite plate of the invention has physical and chemical properties and decorative abilities that are similar to those of traditional artificial quartz stone.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]The present application claims the benefit of Chinese Patent Application No. 201910607431.7 filed on Jul. 8, 2019, the contents of which are incorporated herein by reference in their entirety.FIELD OF THE INVENTION[0002]The present invention relates to the technical field of construction materials, in particular to a composition plate and a preparation method thereof.BACKGROUND OF THE INVENTION[0003]With the continuous improvement of living standards, people pursue a higher quality of life, and various artificial stones are being widely used. In terms of preparation methods, existing artificial stones can be divided into three types: a sintered type, a heat-curing type, and a low-temperature curing type. The preparation of the sintered type is similar to the preparation of ceramic bricks, that is, it is obtained by firing at a high temperature; the cost of the stone plates obtained this way is high. The plate obtained by low-temperature c...

Claims

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Application Information

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IPC IPC(8): C03C14/00C03C1/00
CPCC03C14/004C03C1/002C03C2214/30C03C2214/12C03C2214/04C04B26/18C04B2111/542C04B14/28C04B14/22C04B24/045C04B24/40C04B24/00C04B24/02C04B24/42C04B20/0076C04B20/008C04B40/0071C04B40/0263
Inventor ZHANG, GUOMINGXIAN, JIANSONGLIANG, ZHIJIANLIU, JUNXIANLIU, TING
Owner FOSHAN YIXIN STONE CO LTD
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