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Polymer foam and method for preparing the same

a polymer foam and polymer technology, applied in the field of polymer foam preparation, can solve the problems of low thermal stability and mechanical strength, cell rupture, low melt strength, etc., and achieve the effects of high melt strength, lower melt strength, and improved foamability

Active Publication Date: 2017-02-02
LEE CHANG YUNG CHEM IND CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present patent provides a method for preparing a polymer sheet or foam with a co-continuous structure, which has superior mechanical and physical properties compared to conventional composites and foams made by the same composition. The method involves coating materials onto polymer pellets and then performing a PIF process at a high temperature and pressure for a specific holding time to obtain a polymer sheet with a co-continuous structure. The resulting polymer sheet or foam can then be treated with a foaming process using a foaming agent at a lower temperature and pressure for a saturation time to obtain a low-density foam with high performance. This method is more suitable for industrial applications due to the reduced pressure and time required. Additionally, the resulting polymer foam has low foam density and high strength, making it useful in various industrial applications.

Problems solved by technology

However, like other commodity polymers, the low thermal stability and mechanical strength prevent PP from many engineering and structural applications.
Furthermore, its low melt strength leads to cell rupture and low expansion ratio in the melt foaming process unless long-chain branching, polymer compounding, or chemical crosslinking are used to modify PP.
However, PP is very difficult to be foamed because of its low melt strength and high crystallinity.
However, these methods face limited applications owning to the significant cost increase in materials and poor mechanical strength of foamed products in comparison with PP and other widely used foam materials such as polystyrene (PS).
It is known that the unmodified polymer, especially neat polypropylene (PP), is very difficult to be foamed due to its low melt strength and high crystallinity.

Method used

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  • Polymer foam and method for preparing the same

Examples

Experimental program
Comparison scheme
Effect test

example 1

Preparation of Polymer Foam with Only PP

Characterization

[0066]Foam density: The mass densities of obtained PP samples ρf were measured according to ASTM D792 involving weighing polymer foam in water using a sinker. ρf was calculated as follows:

ρf=aa-bρwater

where a is the apparent mass of specimen in air, b the apparent mass of specimen completely immersed in water.

[0067]Scanning electron microscopy (SEM): The morphologies of the obtained PP foams were studied by SEM (Philips XL30). The samples were immersed in liquid nitrogen for 30 min and then fractured. The fractured surfaces were sprayed with a layer of gold for further observation by SEM.

[0068]Thermal mechanical analysis (TMA): The thermal stability of PIF and foamed samples were investigated by using a TMA (TA Instruments TMA 2940). The dimension change of samples was measured at a scanning rate of 5° C. / min from 30° C. to 180° C. under penetration mode.

[0069]Differential Scanning Calorimetry (DSC): The TA Q200 DSC was used to...

example 2

Preparation of Polymer Foam with a Composite Comprising PP and MWCNT

Characterization

[0089]All the characterization methods used in the present example are similar to those illustrate in Example 1, and the differences are listed below.

[0090]SEM: The difference between Example 1 and present example is that the samples were immersed in liquid nitrogen for 10 min and then fractured in the present example.

[0091]DSC: The difference between Example 1 and present example is that samples were cut into 10-15 mg thin slices for DSC characterization in the present example.

[0092]XRD: The difference between Example 1 and present example is that the samples were scanned from 5° to 70° with an increment of 0.4°.

[0093]Polarizing microscopy: A Leitz 1720 Cryostat Microtome was utilized to prepare thin slices of PP sample. The PP samples were cooled down to −15° C., and then cut into 25 and 50 μm thin slices. The 25 μm slices were utilized to observe the crystal structure of PP sample before and after...

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Abstract

Polymer foam and a method for preparing the same are disclosed. In the present disclosure, the method sequentially comprises the following steps: providing a polymer body; performing a pressure-induced flow (PIF) process on the polymer body at a first predetermined temperature and a first predetermined pressure for a pressure holding time, to obtain a polymer sheet; and performing a foaming process on the polymer sheet by using a foaming agent at a second predetermined temperature and a second predetermined pressure for a saturation time, to obtain polymer foam.

Description

CROSS REFERENCE TO RELATED APPLICATION[0001]This application claims the benefit of filing date of U.S. Provisional Application Ser. No. 62 / 197,630, entitled “Semi-crystalline Polymer Nanocomposite and Foam Structure and Method for Making the Same” filed Jul. 28, 2015 under 35 USC §119(e)(1).BACKGROUND[0002]1. Field of the Invention[0003]The present disclosure relates to a method for preparing polymer foam and, more particularly to a method for preparing polymer foam via a pressure-induced flow (PIF) process.[0004]2. Description of Related Art[0005]Polymer foam, especially polypropylene foam, has many industrial applications, and the global polymer foam market has witnessed a rapid growth in the past few years.[0006]Polypropylene (PP), as one of the most widely used commercial polymers, has many desirable properties, such as high melting point, good plasticity, low density, excellent chemical resistance and food safety, and easy recycling. These outstanding properties as well as a lo...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C08J9/12C08J9/00B29D7/01B29C44/02B29C44/34C08J5/18B29B11/06
CPCC08J9/122B29K2023/12C08J9/0071B29B11/06B29C44/02B29C44/3415B29C44/3442B29D7/01C08J2203/06C08J2203/08C08J2205/044C08J2323/12C08J2201/02B29K2105/04C08J5/18B29C44/3446B29C44/60C08K7/24C08L23/12C08J9/224C08J2300/22B29K2995/004B29K2027/06B29C67/207B29C44/3453B29K2077/00B29K2069/00B29K2105/041B29K2105/048B29K2023/06B29K2067/006B29K2995/0063B29K2105/06B29K2995/0077
Inventor LEE, LY JAMESLI, DACHAOYEN, YING-CHIEHFU, DAJIONGCHIU, YUEN-YUEN D.LIN, CHIANG-HSIANG
Owner LEE CHANG YUNG CHEM IND CORP
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