Adhesive composition, adhesive sheet, and back grinding method for semiconductor wafer
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example 1
[0061]A monomer mixture (100 parts by weight) comprising isobonyl acrylate, methyl acrylate, ethyl acrylate, n-butyl acrylate and 2-hydroxyethyl acrylate was prepared such that 5 parts by weight of isobonyl acrylate (IBOA) were contained in the mixture, and the glass transition temperature of the polymer prepared from the mixture was −25° C. Then, the monomer mixture was polymerized to prepare an acrylic pressure-sensitive adhesive polymer having a solid content of 45 weight %. Next, an isocyanate cross-linking agent was added to the prepared pressure-sensitive adhesive polymer in an amount of 2 parts by weight, relative to 100 parts by weight of the pressure-sensitive adhesive polymer. The resultant was applied to an ethylene-acetic acid vinyl copolymer film having a thickness of 80 μm, and then dried, thus preparing a pressure-sensitive adhesive layer (thickness: 20 μm). The prepared pressure-sensitive adhesive sheet was aged for 2 hours at 50° C., and then subjected to tests to b...
example 2
[0062]Except for the fact that a monomer mixture (100 parts by weight) comprising isobonyl acrylate, methyl acrylate, ethyl acrylate, n-butyl acrylate and 2-hydroxyethyl acrylate was used such that 10 parts by weight of isobonyl acrylate (IBOA) were contained therein and the glass transition temperature of the polymer prepared from the mixture was −9° C., the pressure-sensitive adhesive sheet was prepared in the same manner as Example 1.
example 3
[0063]Except for the fact that a monomer mixture (100 parts by weight) comprising isobonyl acrylate, methyl acrylate, ethyl acrylate, n-butyl acrylate and 2-hydroxyethyl acrylate was used such that 20 parts by weight of isobonyl acrylate (IBOA) were contained therein and the glass transition temperature of the polymer prepared from the mixture was −1° C., the pressure-sensitive adhesive sheet was prepared in the same manner as Example 1.
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