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Heat sealable monoaxially oriented propylene-based film with directional tear

a propylene-based film, monoaxial orientation technology, applied in the direction of textiles and paper, synthetic resin layered products, filament/thread forming, etc., can solve the problems of loss or spillage of contents during opening, difficulty for consumers to open pouches by hand, and save transportation costs. , to achieve the effect of minimizing thermal shrinkage and enhancing heat sealing properties

Inactive Publication Date: 2010-03-04
TORAY PLASTICS AMERICA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent text describes a method for making a sealable film with excellent directional tear properties for retort packaging applications. The film has good heat seal strength and hermetic seal properties. The method involves using a specific resin formulation and a combination of ethylene-propylene impact copolymer and ethylene-butene impact copolymer. The film can be monoaxially oriented and has a high seal initiation and seal strength. The film can also be laminated with additional layers for further strength and flexibility. Overall, the method provides a sealable film that can withstand retort packaging conditions and has excellent directional tear properties.

Problems solved by technology

Flexible retort pouches are lighter in weight and this saves in transportation costs.
However, the high seal strengths required for retort packaging also make it difficult for the consumer to open the pouch by hand, especially if the retort package is made of all polymeric films.
However, such a tear can easily result in “zippering” of the pouch whereby the tear is not uniformly parallel to the top edge of the pouch but can become vertical or diagonal to the top of the pouch and cause a potential loss or spillage of the contents during opening.
Some concerns using perforation techniques is not only additional cost, but also the potential compromising of barrier properties since these techniques are essentially perforating the pouch laminate.
However, the process of orienting such a film—either uniaxially or biaxially—typically diminishes the seal properties in that the seal initiation temperature (SIT) of the film is raised and the overall seal strengths are weaker.
Without being bound by any theory, this is believed to be due to the fact that the orientation process aligns the amorphous regions into a more ordered configuration, raising the Tg of the film, and thus, seal properties are poorer.
There is typically a minimum and maximum range for uniaxial orientation stretching in the machine direction (MDX): less than 3.0 MDX, the film usually suffers from uneven stretching mark defects and over 7.0 MDX, processing stability can be difficult to maintain, as the film may be prone to breakage at this high orientation rate.
The monoaxially oriented film which imparts the “tearing zone” is on the outside of the pouch and does not contact the pouch contents and is not designed or considered to be appropriate for heat-sealability.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0052]A single-layer extrusion article including a mixed resin layer of an ethylene-propylene impact copolymer Total 5571 at 92 wt % of the layer and 4 wt % of metallocene-catalyzed propylene-butene elastomer Mitsui XM7070 and 4 wt % of metallocene-catalyzed ethylene-butene elastomer Mitsui A4085S was extruded and cast and monoaxially oriented in the machine direction at a 4.8:1.0 stretch ratio. The resin components were dry-blended together and extruded in a single-screw extruder and cast using a matte finish chill roll. The total thickness of this film substrate after monoaxial orientation was ca. 70 μm. The film was passed through a corona treater for discharge treatment on one side of the film and wound into roll form. The film was tested for directional tear performance, haze, and heat sealability properties.

example 2

[0053]Example 1 was repeated except that the mixed resin layer was oriented in the machine direction at a 5.8:1.0 stretch ratio.

example 3

[0054]Example 1 was repeated except that the mixed resin layer was oriented in the machine direction at a 7.0:1.0 stretch ratio.

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Abstract

A monoaxially oriented film including heat sealable layer including an ethylene-propylene impact copolymer and a metallocene-catalyzed propylene-butene elastomer. The heat sealable layer may include a metallocene-catalyzed ethylene-butene elastomer. The film is oriented at least 4 times in the machine direction and exhibits excellent linear directional tear properties in the machine direction and excellent heat seal performance. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims the benefit of U.S. Provisional Application, U.S. Ser. No. 61 / 089,121, filed on Aug. 15, 2008, the entirety of which is incorporated herein by reference.FIELD OF THE INVENTION[0002]This invention relates to a monoaxially oriented heat sealable propylene-based film which exhibits excellent sealability and directional tearability.BACKGROUND OF THE INVENTION[0003]Cans and retortable pouches have been used routinely for the preservation and packaging of pre-cooked foods without additional preservation techniques such as freezing, pickling, salting, drying, or smoking. Such canning and retorting applications subject the food contents to high temperatures for short time periods which effectively cook the contents within the container and / or sterilize the contents such that the contents remain safely preserved until used by the consumer.[0004]With the increasing cost of metals and metal processing, flexible retort pouches...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B32B27/08C08L23/04B32B7/02B29C47/08B29C47/06B29C48/08B29C48/21
CPCC08J5/18Y10T428/2826C08L23/0815C08L23/10C08L23/16C08L2205/02C08L2205/035C08L2314/06C08J2323/16Y10T428/2495B29L2009/00B29L2007/008B32B27/08B32B2307/582B32B2307/31B32B2250/242B32B2250/03B32B2250/02B32B27/327B32B2439/46B29C47/0021B29C47/065B29D7/01B29K2023/00C08L2666/02C08L2666/06Y10T428/31913B29C48/08B29C48/21
Inventor LEE, MARK S.KOEHN, HAROLD E.COLETTA, EMILIOBROWN, MATTHEW H.
Owner TORAY PLASTICS AMERICA
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