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Expanded-graphite sheet

a graphite sheet and expansion technology, applied in the direction of magnetic/electric field screening, modification by conduction heat transfer, chemical instruments and processes, etc., can solve the problems of low graphite sheet production efficiency, high cost of polymer films, and long time-consuming films, etc., to achieve high thermal conductivity, and high thermal conductivity in parallel direction

Inactive Publication Date: 2007-05-17
TOYO TANSO KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0006] Accordingly, the object of the present invention is to provide an expanded-graphite sheet whose thermal conductivity in parallel direction is uniform and higher than its thermal conductivity in perpendicular direction and which can be produced efficiently at relatively low cost.
[0013] The advantage offered by the first feature of the present invention is as follows. Because the thermal conductivity in parallel direction of the expanded-graphite sheet is 350 W / (m·K) or more, surfacewise thermal conduction through the sheet is quick; therefore, the expanded-graphite sheet is suitable for the conduction and diffusion of heat. Especially if the expanded-graphite sheet is made of expanded graphite alone, its thermal conductivity in parallel direction can be made much higher than its thermal conductivity in perpendicular direction; therefore, it is more suitable for the conduction and diffusion of heat. If the expanded-graphite sheet is made by compressing with a rolling mill or the like expanded graphite which is made by heating and forming graphite soaking up liquid such as sulfuric acid, no heat treatment in particular is required and, hence, the expanded-graphite sheet can be produced easily in a short time. If the expanded-graphite sheet is produced with a rolling mill, the expanded-graphite sheet can be produced continuously; therefore, the expanded-graphite sheet can be produced efficiently. If the expanded-graphite sheet is made of expanded graphite alone, the raw-material cost of the expanded-graphite sheet is relatively low and, hence, the expanded-graphite sheet can be produced at relatively low cost.
[0017] The advantage offered by the fifth feature of the present invention is as follows. Because the total impurity content of the expanded-graphite sheet is as low as 10 ppm or less, components and devices fitted with the expanded-graphite sheet are prevented from deteriorating due to impurities.
[0018] The advantage offered by the sixth feature of the present invention is as follows. Because the entanglement of graphite fibers of the expanded-graphite sheet is firm and, hence, the graphite fibers are firmly bonded together, the expanded-graphite sheet is strong and does not easily tear.

Problems solved by technology

However, such polymer films are costly.
Besides, heat-treating of such polymer films takes a long time; therefore, the production efficiency of the graphite sheet is low.
Accordingly, the graphite sheet is very costly and, hence, the application of the graphite sheet to apparatuses and equipment is limited.
Although the thermal conductivity in parallel direction of the graphite sheet of the above Japanese Unexamined Patent Publication No. 2001-79977 is very high, its thermal conductivity in parallel direction is not uniform if its thickness or density is not uniform.
When it is used to conduct heat from a heat source to other places, spots of low thermal conductivity becomes heat spots which affect nearby components or devices.
However, no method of preventing such heat spots from being made is disclosed in the Japanese Unexamined Patent Publication No. 2001-79977.

Method used

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Experimental program
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Effect test

first embodiment

[0047] The thermal conductivities in parallel direction, electromagnetic-wave-shielding effect, and surface roughness of expanded-graphite sheets of the present invention were compared with those of expanded-graphite sheets currently in use. The expanded-graphite sheets of the present invention were made by compressing refined sheets at a rolling speed of 1-2 m / min and had the bulk density of 1.9 Mg / m3. The expanded-graphite sheets currently in use were made by compressing refined sheets at rolling speeds of 3-10 m / min and had the bulk density of 1.0 Mg / m3.

[0048] The thermal diffusivity of the expanded-graphite sheet was found by using the laser flash method and its thermal conductivity was calculated from the thermal diffusivity so found. Nine test pieces 25 mm by 25 mm were cut off from the 200-by-200 mm expanded-graphite sheet, and the mean thermal conductivity of the nine test pieces was calculated.

[0049] The electromagnetic-wave-shielding effect of the expanded-graphite sheet...

second embodiment

[0055] Refined sheets of the thickness of 1.0 mm and the bulk density of 1.0 Mg / m3 were compressed into expanded-graphite sheets of the thickness of 0.5 mm and the bulk density of 1.9 Mg / m3 in the rolling-speed range of 1-10 m / min to ascertain the effects of the rolling speed on the surface roughness, creases, and thermal conductivity of the expanded-graphite sheets.

[0056] As to the dispersion of thermal conductivity, nine test pieces were cut off from the expanded-graphite sheet of each of the rolling speeds of 1, 2, 4, 6, 8, and 10 m / min and the difference between the highest and lowest conductivities of the nine test pieces was divided by the mean conductivity of the nine test pieces.

[0057] As shown in FIG. 3, as the rolling speed increased, the center line average height and the dispersion of thermal conductivity increased. When the rolling speed increased from 2 m / min to 4 m / min, the center line average height and the dispersion of thermal conductivity almost doubled. This in...

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Abstract

This invention provides an expanded-graphite sheet whose thermal conductivity in their surfacewise directions is relatively uniform and higher than its thermal conductivity in perpendicular direction and which can be produced efficiently at relatively low cost. Because the expanded-graphite sheet is made of expanded graphite alone and has the thermal conductivities in parallel direction of 350 W / (m·K) or more, its thermal conductivities in parallel direction is much higher than its thermal conductivity in perpendicular direction; therefore, it is suitable for the conduction and diffusion of heat. Besides, the expanded-graphite sheet can be produced easily, in a short time, efficiently, at relatively low cost.

Description

[0001] This application is a continuation of International Application No. PCT / JP2005 / 012733, filed Jul. 11, 2005 which claims priority on Japanese Patent Application 2004-249137 filed Aug. 27, 2004.TECHNICAL FIELD [0002] This invention relates to a thermally anisotropic expanded-graphite sheet whose thermal conductivity in its surfacewise directions is higher than that in its thicknesswise directions. BACKGROUND OF THE INVENTION [0003] Thermally anisotropic sheets whose thermal conductivity in their surfacewise directions (hereinafter referred to as “thermal conductivity in parallel direction”) is higher than that in their thicknesswise directions (hereinafter referred to as “thermal conductivity in perpendicular direction”) have been used to conduct heat from heat sources to other places. The higher the thermal conductivity in parallel direction of a sheet is, the quicker the thermal conduction through it is; accordingly, sheets of high thermal conductivity in parallel direction h...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C01B31/04
CPCC01B31/0423C01B32/225C09K5/14C01B32/20C01P2006/10C01P2006/32C01P2006/80H05K7/2039H05K9/0081
Inventor HIROSE, YOSHIAKI
Owner TOYO TANSO KK
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