Multi-layered preform and multi-layered bottle manufactured by using the same

Abstract

A multi-layered preform for substantially preventing the generation of strains and obtaining improved stress cracking resistance with excellent appearance characteristics includes a mouth portion, a body portion and a bottom portion and has at least the body portion and the bottom portion formed of an inner layer, an intermediate layer, and an outer layer by a compression molding. A multi-layered bottle is manufactured by performing a biaxial stretch blow molding of such multi-layered perform. The multi-layered bottle includes a mouth portion, a shoulder portion, a body portion and a bottom portion. At least the shoulder portion, the body portion and the bottom portion include an inner layer, an intermediate layer and an outer layer.

Description

[0001] 1. Field of the Invention[0002] The present invention relates to a multi-layered preform which is formed by performing a compression molding of a plural kinds of oriented thermoplastic resins and a multi-layered bottle which is formed by performing a biaxial stretch blow molding of the multi-layered preform, and more particularly to a multi-layered preform and a multi-layered bottle having layers each of which has no strain generated by the flow orientation at a bottom portion thereof and also exhibits the excellent environmental stress resistance (ESC property), the excellent impact resistance, the excellent strength and the excellent appearance characteristics of the bottom portion thereof.[0003] 2. Description of the Prior Art[0004] Stretch blow molded bottles made of polyester, polypropylene, polyamide or the like, particularly polyester bottles exhibit the excellent transparency and the gas barrier property and hence, the stretch blow molded bottles have been widely used...

AI Technical Summary

Benefits of technology

[0033] With respect to the multi-layered preform and the multi-layered bottle according to the present invention, as described above, the residual strains due to the flow orientation of the resin is remarkably attenuated at the bottom portion so that the bottom portion is efficiently cooled whereby advantageous effects that the multi-layered preform and the multi-layered bottle can exhibit the excellent impact resistance and the excellent environmental stress crack resistance, can eliminate the occurrence of the crazing and the whitening, and can exhibit the excellent appearance characteristics are obtained.

[0034] As the oriented thermoplastic resin which is used as the material of the inner layer and the outer layer of the present invention, any arbitrary resin can be used so long as the resin can be subjected to the stretch blow molding and can be crystallized under heat. Thermoplastic polyester such as polyethylene terephthalate, polybutylene terephtalate, polyethylene naphthalate, polycarbonate, polyarylate or a copolymer thereof or the like, a blend of these resins or a blend of these resins and other resins is preferably used. Ethylene-terephtalate-based thermoplastic polyester such as polyethylene terephtalate or the like can be more suitably used.

[0035] Further, acrylonitrile resin, polypropylene, propylene-ethylene copolymer, polyethylene or the like can be also used.

[0036] Into these resins, various kinds of additives, for example, a coloring agent, a ultraviolet lays absorption agent, a mold lubricant, a lubricant, a nucleus agent, an oxidation prevention agent, a charging prevention agent and the like can be blended within a range which does not damage the quality of a molded product.

[0037] In the ethylene-terephtalate-based thermoplastic polyester resin which is used for forming the inner layer and the outer layer in the present invention, the substantial portion, generally not less than 70 mol % of ester repeating units is occupied by the ethlene terephtalate units and it is preferable that the glass transition point (Tg) is set in a range from 50 to 90.degree. C. and the melting point is set in a range from 200 to 275.degree. C. In the ethylene-terephtalate-based thermoplastic polyester resin, polyethylene terephtalate (PET) exhibits the particularly excellent pressure resistance, heat resistance, heat-pressure resistance and the like. However, copolymer polyester which includes a small quantity of ester units formed of dibasic acid such as isophtalic acid, naphthalene dicarboxylic acid or the like and diol such as propylene glycol or the like besides the ethylene terephtalate units can be also used.

[0038] As the thermoplastic resin which can be used as the material of the intermediate layer of the present invention, any arbitrary resin can be used corresponding to purposes. For example, to give the gas barrier property to the intermediate layer, it is preferable to use resin such as polyamide resin including polyamide which contains xylylene group such as ethylene-vinyl alcohol copolymer or polymetaxylylene adipamido (product name: MXD6). To achieve the further enhancement of the oxygen barrier property, it may be possible to use a resin composition which blends a transition metal-based catalyst such as cobaltate, reduced iron, or the like into the gas barrier resin or the diene-based chemical compound.

Problems solved by technology

In a single-layered preform manufactured by a conventional injection molding, at a gate portion of a bottom portion or in the vicinity of the gate portion, the turbulence of a resin flow is generated and the whitening is liable to occur.

Accordingly, there has been a problem that a bottle obtained by performing the biaxial stretch blow molding of the preform exhibits the poor appearance characteristics such as whitening, the crazing or the like of the bottom portion and reduces the impact resistance.

With respect to the multi-layered preform manufactured by the injection molding and the bottle obtained by performing the biaxial stretch blow molding using such a multi-layered preform, since a plurality of resins are injected, the respective flows of the resins become more complicated and this tendency appears particularly noticeably.

Further, with respect to a multi-layered preform obtained by performing an injection molding of oriented thermoplastic resin such as polyethylene terephthalate or the like, even when a body portion is transparent, the cooling efficiency at a gate portion or at a periphery thereof is poor so that these portions are liable to easily suffer from the whitening.

However, there have been problems that when the diameter of the gate increased, the diameter of a gate residual portion at the bottom portion is increased and hence, the appearance characteristics are worsened and when the injection pressure is reduced, the profiling of the preform is worsened and, at the same time, the injection residence time is prolonged so that the productivity is lowered.

Further, the above-mentioned problems appear outstandingly with respect to the multi-layered bottle obtained by performing the biaxial stretch blow molding of the multi-layered preform.

Particularly, at the time of performing the biaxial stretch blow molding, there has been a problem that an interlayer peeling-off is liable to be generated at a center portion or in the vicinity of the center portion of the bottom portion of the bottle so that the impact resistance is drastically deteriorated.

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