Multiphase fiber materials and compositions, methods of manufacture and uses thereof
A composition and fiber technology, applied in the direction of final product manufacturing, sustainable manufacturing/processing, textile/flexible product manufacturing, etc.
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Embodiment 1
[0068] The preparation of embodiment 1-lactam
[0069] In a covered vessel, melt four liters of caprolactam overnight in a convection oven. The lactam was poured into a 5 liter 3-neck distillation flask with a magnetic stir bar and electric heating mantle (top and bottom mantle). The distillation column has a vacuum jacket and consists of a 29 / 42 column and 10 tray section, 5 tray section, split distillation head and condenser. The condenser was maintained at 50°C using a heated water circulator. The system reduces the pressure from 7 mmHg to 4 mmHg. Heat was applied to bring the column to reflux conditions and held for 30 minutes. After allowing the column to stabilize for 30 minutes, the distillation head sampler was started, 4 seconds off, and 10 seconds to reflux. Slightly less than 1 liter of lactam was distilled off. The heat was turned off, and the heating mantle was removed, the lactam in the 5-liter flask was allowed to drop to 90°C, and then the vacuum on the sy...
Embodiment 2
[0070] Example 2 - Preparation of contemplated pre-fiber gel compositions
[0071] the gel
[0072] The resulting gel was gel-spun on a twin-screw extruder. The gels are surprisingly well spun into fiber products, and fiber bales can be prepared under most conventional spinning conditions. Furthermore, it can be seen that the extruder temperature can be lowered below conventional neat polymer conditions, provided the gel composition allows lower extruder pressures. Tables 1-5 shown below give a summary of several spinning conditions used in these examples.
Embodiment 3
[0073] Example 3 - Preparation of contemplated pre-fiber compositions
[0074] background
[0075] A conventional binder alloy sample (1-end of 22 denier / 12 filaments) was inserted into 1202mp 2-ply yarn during cabling and Superba(R) heat set. After Superba(R) heat setting, the Plybond test of the yarns did not show any signs of bonding. Subsequently, the yarn is autoclave heat set before being processed into banded carpet. No significant aesthetic effect was observed in the carpet using any of the conventional binder alloy samples. However, at the lowest nylon / binder ratio, there was a slight impact on carpet hand (firmness), but no texture or surface changes were observed in the carpet.
[0076] This study tested compositionally altered low-melt alloy fibers (higher process "binder" and higher lactam concentration). The goal of the research was to find an alloy composition that would melt and bond the fibers together within the bundle during Superba(R) heat setting. The...
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