Modified legume starch-based compound for paper finishing
A technology of bean starch and composition, applied in the field of processing paper or flat board, paper or flat board, application of bean starch in processed paper or flat board, coloring surface treatment and/or coating, can solve the problem of paste Problems such as instability and difficulty in dissolving
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Embodiment 1
[0097] A pea starch sample was taken, with an amylose content of 36.7%, and liquefied according to the method described in European patent application EP 0 902 037 submitted by the applicant.
[0098] A product called APF with a water fluidity (WF) equal to 75 was obtained.
[0099] Another sample of the same natural pea starch was subjected to two-step treatment, liquefaction and esterification, wherein the esterification treatment was acetylation treatment (acetyl value AV=1.8), and the product obtained in this way was called APFA, and its WF was equal to 88.
[0100] Similarly, a sample of corn starch was subjected to two-step treatment, liquefaction and acetylation (AMFA, acetyl value AV=1.9), and the product WF was equal to 78.
[0101] Another sample of the same native pea starch was subjected to two-step treatment, liquefaction and esterification, wherein the esterification treatment was cationic (nitrogen level = 0.16%, WF = 80), and the product thus obtained was calle...
Embodiment 2
[0109] Samples of different pastes containing 20% MS prepared by the above method were evaluated for stability by observing the presence and / or increased amount of insoluble matter and placing each sample at high temperature (70 or 90°C) After 24 hours, the amount of insoluble matter therein was measured.
[0110] liquefaction and acetylation
[0111] From the above experimental results, it can be found that for pea starch, whether it is only liquefied or liquefied plus acetylation, it can show and prevent the biggest inconvenience in use, especially the enrichment of insoluble substances in the circuit. This property allows the paste to be stored at high temperatures.
Embodiment 3
[0113] This step is used to dilute the samples of different pastes obtained by the above method to have rheological properties suitable for coating processing.
[0114] In the second step, the diluted sample is divided into two equal parts.
[0115] One of the pastes is equally divided into six parts, which are called APF1, APFA1, AMFA1, APFC1, AMFC1 and APFR1 for direct use.
[0116] The other was added a commercial optical brightener equivalent to 20% of the amount of starch, and the six new samples obtained were called APF2, APFA2, AMFA2, APFC2, AMFC2 and APRA2.
[0117] modified starch
Powder - Control
sample
Dry solidity when coating
Mass (%MS)
pH
60°C, 100 rev / min Brinell
Viscosity (mPa.s)
APFA1
15
5.2
31
APFR1
14
7.1
44
APF1
15
7.0
70
AMFA1
15
5.3
95
APFC1
15
7.1
28
AMFC1
14
7...
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