Fruit and vegetable fresh-keeping packaging film and preparation method thereof
A technology of fresh-keeping and packaging films for fruits and vegetables, applied in polyether coatings, coatings, etc., which can solve the problems of high air permeability, poor fresh-keeping effect, and inconspicuous adjustment of gas components, etc., and achieve high transmission rate and good fresh-keeping effect , Prolong the effect of fresh-keeping effect
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Embodiment 1
[0035] A fresh-keeping packaging film for fruits and vegetables, comprising a base film and a coating solution coated on the base film, wherein the coating solution includes 5 to 10 parts of polyvinyl alcohol aqueous solution, 1 part of polyethylene glycol aqueous solution ~2 parts, 0.5~2 parts of modified sodium lignosulfonate and 0.1~0.3 parts of glutaraldehyde aqueous solution; .
[0036] Preferably, the amine-based reagent is one or more of ethylenediamine, diethanolamine, tetramethylpiperidinamine and diethylenetriamine.
[0037] Preferably, the mass ratio of the amine-based reagent to sodium lignosulfonate is 1-6:5.
[0038] The preparation method of described fruit and vegetable fresh-keeping wrapping film, comprises the steps:
[0039] (1) Preparation of coating solution: the polyvinyl alcohol aqueous solution of 5-10% mass concentration and the polyethylene glycol aqueous solution of 5-10% mass concentration are mixed, and then the modified sodium lignosulfonate is ...
Embodiment 2
[0049] A preparation method of a fruit and vegetable fresh-keeping packaging film, comprising the steps of:
[0050] (1) Preparation of modified sodium lignosulfonate: Weigh 5 g of sodium lignosulfonate dried in a 60° C. Stir for 1 hour at ℃ to a uniform solution; use ammonia solution to adjust the pH to 11; add 1 g of ethylenediamine to the flask, and after the water bath heats up to 70 ℃, slowly add 0.2 g of 0.5 mol / L glutaraldehyde, and continue at 70 Stir at ℃ for 4 hours; after the reaction solution is cooled to room temperature, transfer it to a beaker to cool to room temperature, then pour 350g of a mixture solution of ethanol and isopropanol into the beaker to obtain a modified solution; seal the modified solution with a plastic wrap , let stand at room temperature for 24 hours; centrifuge the upper layer of the solution after standing at 5000rpm, and centrifuge for 20min. Dry to obtain modified sodium lignosulfonate.
[0051] (2) Preparation of coating liquid: put 5...
Embodiment 3
[0056] A preparation method of a fruit and vegetable fresh-keeping packaging film, comprising the steps of:
[0057] (1) Preparation of modified sodium lignosulfonate: Weigh 5 g of sodium lignosulfonate dried in a 60° C. Stir for 1 hour at ℃ to a uniform solution; use ammonia solution to adjust the pH to 11; add 3g of ethylenediamine and 3g of diethanolamine to the flask, and slowly add 2g of 0.5mol / L glutaraldehyde after the water bath is heated to 80℃ , continue to stir at 80°C for 4h; after the reaction solution is cooled to room temperature, transfer it to a beaker to cool to room temperature, then pour 350g of ethanol and isopropanol mixture solution into the beaker to obtain a modified solution, and use Seal the plastic wrap and let it stand at room temperature for 24 hours; centrifuge the upper layer of the solution after standing at 5000 rpm for 20 minutes. The product is vacuum dried to obtain modified sodium lignosulfonate.
[0058](2) Preparation of coating soluti...
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