Carbon nanotube thermal interface material as well as preparation method and application thereof

A technology of thermal interface materials and carbon nanotubes, which is applied in chemical instruments and methods, carbon compounds, inorganic chemistry, etc., can solve the problems of unreachable applications, increased surface thermal resistance, and inability to consider packaging issues, etc., to achieve high Thermal conductivity, meet the heat dissipation needs, and realize the effect of lossless transfer

Pending Publication Date: 2022-03-01
SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above method only considers the transfer process of the carbon nanotube array, and cannot consider the packaging problem in the application process
Secondly, the dry bonding method requires a certain pressure to press, which will destroy the directional structure of the carbon nanotube array.
However, the deposition of metal layers and weak oxidation methods ignore the stability of the application process
[0005] In addition, the oriented structure of vertically oriented carbon nanotube arrays is easily damaged under the action of external force, and reliable packaging is required in the actual application process, while the existing packaging methods for carbon nanotube arrays are basically all Covered packaging, the surface is basically covered by the packaging material, and the coverage of the packaging material often leads to an increase in the surface thermal resistance, which cannot achieve the purpose of the application

Method used

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  • Carbon nanotube thermal interface material as well as preparation method and application thereof
  • Carbon nanotube thermal interface material as well as preparation method and application thereof
  • Carbon nanotube thermal interface material as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0065] Example 1 Preparation of Vertically Aligned Carbon Nanotube Thermal Interface Material

[0066] (1) spin-coating UV-curable glue on a polyethylene terephthalate substrate;

[0067] (2) For the carbon nanotube array grown on the silicon substrate, paste the UV-curable glue that has been spin-coated in the previous step on its free end; then irradiate with ultraviolet light to cure the UV-curable glue;

[0068] (3) transferring the carbon nanotube array so that the end face of the growth sheet where the carbon nanotube array is in contact with the growth sheet is exposed;

[0069] (4) Paste the same UV-curable glue on the end face of the carbon nanotube array growth sheet, so as to obtain the carbon nanotube array whose upper and lower surfaces are all protected by the UV-curable glue;

[0070] (5) epoxy resin with mechanical buffering properties is filled between the carbon nanotube arrays;

[0071] (6) Removing the UV-curable glue to obtain a heat dissipation interfac...

Embodiment 2

[0074] Example 2 Preparation of Vertically Aligned Carbon Nanotube Thermal Interface Material

[0075] (1) scrape photoresist on polyimide substrate;

[0076] (2) For the carbon nanotube array grown on the copper substrate, affix the UV-curable glue that has been scraped in the previous step on its free end; then irradiate with ultraviolet light to cure the UV-curable glue;

[0077] (3) transferring the carbon nanotube array so that the end face of the growth sheet where the carbon nanotube array is in contact with the growth sheet is exposed;

[0078] (4) Paste the same photoresist as above on the end face of the carbon nanotube array growth sheet, so as to obtain the carbon nanotube array whose upper and lower surfaces are all protected by the photoresist;

[0079] (5) Silica gel with mechanical buffering properties is filled between the carbon nanotube arrays;

[0080] (6) The photoresist is removed to obtain a heat dissipation interface material with a designable surface...

Embodiment 3

[0082] Example 3 Preparation of Vertically Aligned Carbon Nanotube Thermal Interface Material

[0083] (1) Spin-coat temporary bonding glue on the polytetrafluoroethylene substrate;

[0084] (2) Aiming at the carbon nanotube array grown on the silicon dioxide substrate, affix the temporary bonding glue that has been scraped in the previous step on its free end; heat and dry to obtain the cured temporary bonding glue;

[0085] (3) transferring the carbon nanotube array so that the end face of the growth sheet where the carbon nanotube array is in contact with the growth sheet is exposed;

[0086] (4) Paste the same temporary bonding glue as above on the end face of the carbon nanotube array growth sheet, so as to obtain the carbon nanotube array whose upper and lower surfaces are all protected by the temporary bonding glue;

[0087] (5) Filling polyimide resin with mechanical buffering properties between the carbon nanotube arrays;

[0088] (6) The temporary bonding glue is r...

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Abstract

The invention relates to a carbon nanotube thermal interface material as well as a preparation method and application thereof, and particularly discloses a vertical alignment carbon nanotube thermal interface material which comprises vertical alignment carbon nanotube arrays and a packaging material dispersed among the carbon nanotube arrays. The preparation method comprises the following steps: arranging temporary glue at the free end of the carbon nanotube array, separating the carbon nanotube array, and removing the temporary glue after filling the packaging material. The invention provides the method for transferring the carbon nanotube array growing on the substrate, the thermal interface material is prepared by using the transferred carbon nanotube array, the preparation method is simple, and the obtained thermal interface material is novel in structure, high in thermal conductivity, flexible and suitable for high-heat-yield electronic products and flexible electronic products.

Description

technical field [0001] The invention relates to the field of electronic packaging materials, in particular to a surface-designable carbon nanotube thermal interface material and a preparation method and application thereof. Background technique [0002] In the field of electronic packaging, thermal interface materials are often used to thermally manage components. The contact interface between the heat sink and the component often becomes an obstacle to heat dissipation. The commonly used thermal interface materials at this stage are thermally conductive silica gel / silicon grease / gel, whose thermal conductivity is only 3W / (m·K), which has gradually failed to meet the heat dissipation requirements of high-power devices. Carbon nanotubes are one-dimensional nanomaterials with anisotropic electrical and thermal conductivity due to their unique tubular structure. Among them, the thermal conductivity of carbon nanotubes in the tube axial direction is as high as 2000-6000 W / (m·K...

Claims

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Application Information

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IPC IPC(8): H01L23/29H01L23/373C01B32/168
CPCH01L23/29H01L23/373C01B32/168
Inventor 林志强胡友根田锭坤许亚东辛培培邓飞孙蓉
Owner SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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