Preparation method of iron-carbon micro-electrolysis filler for retarding formation of isolating layer through rare earth carbonization

A technology of iron-carbon micro-electrolysis and rare earth carbonization, which is applied in chemical instruments and methods, water/sewage treatment, water/sludge/sewage treatment, etc. Inconvenient to deal with, fast formation of the isolation layer, etc., to achieve the effect of enhancing electrolytic conductivity, improving porous firmness, and improving electrolytic efficiency

Pending Publication Date: 2022-02-25
山东北方三潍环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the iron-carbon micro-electrolysis treatment of wastewater with iron-carbon micro-electrolysis fillers, the electrolysis between iron and carbon forms electrolytic coating grains with large grains, resulting in a relatively fast formation of the isolation layer, and then the iron-carbon micro-electrolysis fillers cannot be reused. At the same time, the iron-carbon micro-electrolytic fillers are easily bonded together during the electrolysis process, causing hardening, and the iron-carbon micro-electrolytic fillers that have been cleaned out and piled up also bring inconvenience to subsequent processing.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] like figure 1 Shown, a kind of rare earth carbonization slows down the preparation method of the iron-carbon micro-electrolytic filler that isolation layer forms, comprises the steps:

[0024] Step 1. Get 50-90g of Fe, 5-20g of C, 1-2g of yttrium, 1-2g of cerium and 1.5-3g of tungsten from each storage container and mix them evenly into a refractory container. Put it into a sintering furnace and sinter for 16 hours according to three temperature stages of 1200-1250°C, 1300-1350°C and 1400-1450°C, so that the above materials are integrated and solid-phase combined;

[0025] Step 2. Grinding the mixed metal lumps: the cooled mixed metal lumps are crushed by a crusher, and then ground to nano-level mixed metal powders with a total mass of 100-200 g, and stored for later use.

[0026] Further, in the step 1, 5-10g of Ti, 10-20g of Ag, 2g of cerium and 3g of tungsten are mixed together to form a cerium-tungsten electrode.

[0027] The preparation method of the iron-carbon ...

Embodiment 2

[0029] like figure 1 Shown, a kind of rare earth carbonization slows down the preparation method of the iron-carbon micro-electrolytic filler that isolation layer forms, comprises the steps:

[0030] Step 3. Paste preparation: Weigh graphene powder, ytterbium powder, scandium chloride powder, and viscous agent according to the ratio of 8:1:2:12 or 10:1:1:6 and put them into the mixer The silo is fully mixed by the mixer to form a paste mixture, which is ready for use;

[0031] Step 4, Slurry carbonization: Take 100g of mixed metal powder from step 2 and put it into the silo of the mixer equipped with paste-like mixed liquid in step 3 and mix well until the surface of each fine mixed metal powder particle is fully slurryed. After entering the dryer, it is dried at a gradual high temperature of 150-300°C. After cooling and taking it out, it is put into a refractory container and placed in a high-temperature sintering furnace, so that the surface of the mixed metal powder is car...

Embodiment 3

[0036] like figure 1 Shown, a kind of rare earth carbonization slows down the preparation method of the iron-carbon micro-electrolytic filler that isolation layer forms, comprises the steps:

[0037]Step 5. Pill making: Take any one of the 20-90 parts of mixed metal powder in step 4 and add an appropriate amount of coupling agent, and the mass of each carbonized mixed metal powder is 2-3 grams, and send it into a mixer for full stirring Mix for 15-25 minutes, add 0.2-0.5g of natural rubber juice evenly, stir and react for 30-45 minutes, it is in a paste state, then pour it into a pelletizing mold and send it to a microwave oven at 260-960°C for drying and sintering for 10- After 12 hours, it was cooled to below 30°C and released from the furnace to obtain an iron-carbon micro-electrolytic filler formed by a rare earth carbonization slowing isolation layer.

[0038] The preparation method of the iron-carbon micro-electrolytic filler formed by the above-mentioned rare earth car...

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PUM

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Abstract

The invention discloses a preparation method of an iron-carbon micro-electrolysis filler for retarding formation of an isolating layer through rare earth carbonization. The preparation method comprises the following steps: mixing and sintering metal powder; grinding a mixed metal block; preparing paste; coating and carbonizing; and pelleting. The iron-carbon micro-electrolysis filler is reasonable in design, grains of an electrolytic coating are refined, uniform and compact, formation of large grains of the electrolytic coating is reduced, formation of an isolating layer is slowed down, the service life of the iron-carbon micro-electrolysis filler is prolonged, meanwhile, the used iron-carbon micro-electrolysis filler can be decomposed under the action of deliquescent scandium chloride powder in air, hardening after cleaning and stacking is avoided, the porous firmness performance of the surface of the iron-carbon micro-electrolysis filler can be improved by adopting a mold pelleting mode, the outermost surface of the iron-carbon micro-electrolysis filler does not contain metal elements, and the condition of bonding hardening between the iron-carbon micro-electrolysis filler caused by metal passivation can be avoided.

Description

technical field [0001] The present application relates to the field of iron-carbon micro-electrolytic fillers, in particular to a method for preparing iron-carbon micro-electrolytic fillers for the formation of rare earth carbonization slowing barrier layers. Background technique [0002] Iron-carbon micro-electrolysis is a good process for treating wastewater by using the principle of metal corrosion to form a primary battery, also known as internal electrolysis, iron filings filtration, etc. Micro-electrolysis technology is currently an ideal process for treating high-concentration organic wastewater. Also known as the internal electrolysis method, it uses the micro-electrolysis material filled in the wastewater to generate a 1.2V potential difference to electrolyze the wastewater to achieve the purpose of degrading organic pollutants without electricity. [0003] In the iron-carbon micro-electrolysis treatment of wastewater with iron-carbon micro-electrolysis fillers, the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/461
CPCC02F1/46104C02F1/46109C02F1/46114C02F2001/46133
Inventor 赵红磊王廷文
Owner 山东北方三潍环保科技有限公司
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