Porous copper foil and preparation method thereof
A technology of porous copper and electroplating copper, applied in the direction of electrolysis, electroforming, etc., can solve the problems of poor performance, high cost, complicated preparation process, etc., and achieve the effect of wide application space, low cost and simple process
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Embodiment 1
[0022] The invention discloses a method for preparing ultra-thin porous copper foil with conductive cloth. The process route is as follows: the conductive cloth is subjected to copper electroplating, sintering and reduction, and roller rolling to prepare ultra-thin porous copper foil.
[0023] In this embodiment, the conductive fabric refers to a nickel-plated non-woven fabric with a thickness of 80 um and a weaving density of 300T.
[0024] In this embodiment, the copper electroplating refers to electroplating copper with conductive arrangement in the electroplating copper solution, and the copper surface density is 150g / m 2 . The copper electroplating solution is specifically a copper pyrophosphate solution, and its process parameters are: the concentration of copper pyrophosphate is 60g / L, the concentration of potassium pyrophosphate is 300g / L, the concentration of ammonium citrate is 30g / L, the concentration of ammonia water is 2ml / L, pH is 8.5, the temperature is 50°C, a...
Embodiment 2
[0029] The invention discloses a method for preparing ultra-thin porous copper foil with conductive cloth. The process route is as follows: the conductive cloth is subjected to copper electroplating, sintering and reduction, and roller rolling to prepare ultra-thin porous copper foil.
[0030] In this embodiment, the conductive cloth is a woven cloth plated with copper, its thickness is 50 um, and its weaving density is 250T.
[0031] In this embodiment, the copper electroplating refers to further electroplating copper on the conductive cloth, and the copper surface density is 80g / m 2 , The copper sulfate solution system is used in the copper electroplating process: the concentration of copper sulfate is 180g / L, the concentration of sulfuric acid is 30ml / L, the temperature is 25°C, and the current is 300A.
[0032] In this embodiment, the sintering reduction refers to placing the copper-plated material in an environment of 550° C. to incinerate the cloth, and then placing it i...
Embodiment 3
[0036] The invention discloses a method for preparing ultra-thin porous copper foil with conductive gauze. The process route is as follows: the conductive gauze is subjected to copper electroplating, sintering and reduction, and roller rolling to prepare ultra-thin porous copper foil.
[0037] In this embodiment, the conductive gauze refers to the gauze that has been plated with nickel, its thickness is 80um, and its aperture density is 300 mesh.
[0038] In this embodiment, the copper electroplating refers to electroplating copper by placing the conductive gauze in the copper electroplating solution, and the copper surface density is 200g / m 2 . The copper electroplating solution is specifically a copper pyrophosphate solution, and its process parameters are: the concentration of copper pyrophosphate is 60g / L, the concentration of potassium pyrophosphate is 300g / L, the concentration of ammonium citrate is 30g / L, the concentration of ammonia water is 2ml / L, pH is 8.8, the temp...
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Abstract
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