Carbon cluster-containing composition and method for producing same
A manufacturing method and composition technology, applied in the field of compositions containing carbon clusters, capable of solving problems such as insufficient dispersion
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no. 1 approach
[0081] In the first embodiment of the carbon cluster-containing composition of the present invention (hereinafter, sometimes referred to as "the composition of this embodiment"), the carbon cluster (A), the first solvent (B1), the second solvent (B2), an ethylenically unsaturated group-containing monomer (C), and a resin (D). Among them, the ethylenically unsaturated group-containing monomer (C) is a carboxyl group-containing ethylenically unsaturated compound (m-2). The resin (D) is an epoxy group-containing copolymer (P1) or an epoxy resin (P3).
[0082] As the carbon cluster (A), any one of the above specific examples or a mixture thereof can be used. As the first solvent (B1) used in the present embodiment, any one of the specific examples of the above-mentioned first solvent (B1) or a mixed solvent thereof can be used. Among them, preferably toluene, benzene, xylene, ethylbenzene, trimethylbenzene, chlorobenzene, dichlorobenzene, or their mixed solvents, more preferably...
no. 2 approach
[0141] In the second embodiment of the carbon cluster-containing composition of the present invention (hereinafter, sometimes referred to as "the composition of this embodiment"), the carbon cluster (A), the first solvent (B1), the second solvent (B2), an ethylenically unsaturated group-containing monomer (C), and a resin (D). Among them, the ethylenically unsaturated group-containing monomer (C) is an epoxy group-containing ethylenically unsaturated compound (m-1). The resin (D) is a carboxyl group-containing copolymer (P2) or a carboxyl group-containing resin (P4).
[0142] For the carbon cluster (A), the first solvent (B1), and the second solvent (B2), the same ones as those in the first embodiment can be used.
[0143] The carboxyl group-containing copolymer (P2) or the carboxyl group-containing resin (P4) is ring-openingly added to the epoxy group of the epoxy group-containing ethylenically unsaturated compound (m-1) to generate a hydroxyl group. It is preferable to fur...
no. 3 approach
[0169] In the third embodiment of the carbon cluster-containing composition of the present invention (hereinafter, sometimes referred to as "the composition of this embodiment"), the carbon cluster (A), the first solvent (B1), the second solvent (B2), and resin (D). Among them, the resin (D) is an ethylenically unsaturated resin (A1) or an ethylenically unsaturated resin (A3).
[0170] As the carbon cluster (A), the first solvent (B1), and the second solvent (B2), those used in the first embodiment can be used in the same manner.
[0171] The ethylenically unsaturated resin (A1) contains a monomer composed of a carboxyl group-containing ethylenically unsaturated compound (m-2) and, if necessary, a polybasic acid anhydride (d), and an epoxy group-containing copolymer (P1) The resin (D) precursor is obtained. In addition, as the ethylenically unsaturated resin (A3), a monomer composed of a carboxyl group-containing ethylenically unsaturated compound (m-2) and, if necessary, a ...
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