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Pr < 3 + >/Ho < 3 + > doped ZAlFB optical fiber glass and preparation method thereof

An optical fiber and glass technology, applied in the field of Pr3+/Ho3+ doped ZAlFB optical fiber glass and its preparation, can solve the problems of low luminous intensity, limited application, increased probability of non-radiative transition of rare earth ions, etc.

Active Publication Date: 2021-06-08
宏安集团有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The more mature Ho-doped 3+ Quartz fiber technology, the quality of the fiber is excellent, but the phonon energy of the quartz glass is as high as 1100cm -1 , leading to an increase in the probability of non-radiative transitions of rare earth ions, and a low luminous intensity in the 2-3 μm band, which greatly limits its application in the field of mid-infrared fiber lasers

Method used

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  • Pr &lt; 3 + &gt;/Ho &lt; 3 + &gt; doped ZAlFB optical fiber glass and preparation method thereof
  • Pr &lt; 3 + &gt;/Ho &lt; 3 + &gt; doped ZAlFB optical fiber glass and preparation method thereof

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Effect test

Embodiment 1

[0032] The invention provides a Pr 3+ / Ho 3+ Doped ZAlFB glass, its preparation method includes the following steps:.

[0033] (1) According to the molar percentage, take each raw material respectively: ZnF of 10mol% 2 , 4mol% Al 2 o 3 , 30mol% LiF, 55mol% B 2 o 3 , 0.5 mol% Pr 6 o 11 , 0.5mol% HoF 3 , for standby; wherein, the mass percent purity of each raw material is required to be 99.99%.

[0034] (2) Fully grind and mix the raw materials weighed in step (1) in an agate mortar, and the grinding time is 6 hours; then put them in an oven and keep them warm for 300 minutes at a temperature of 300°C; then pour them into a porcelain crucible , heated and melted in a high-temperature vacuum electric furnace, the melting temperature is 1200° C., the holding time is 180 minutes, and the vacuum degree is 0.5 MPa to obtain a glass melt.

[0035] (3) Use the vacuum suction casting method to quickly transfer the glass melt obtained in step (2) into a pre-heated stainless st...

Embodiment 2

[0039] The invention provides a Pr 3+ / Ho 3+ Doped ZAlFB glass, its preparation method includes the following steps:.

[0040] (1) According to the molar percentage, take each raw material respectively: ZnF of 10mol% 2 , 4.4mol% Al 2 o 3 , 30mol% LiF, 55mol% B 2 o 3 , 0.1mol% Pr 6 o 11 , 0.5mol% HoF 3 , for standby; wherein, the mass percent purity of each raw material is required to be 99.99%.

[0041] (2) Fully grind and mix the raw materials weighed in step (1) in an agate mortar, and the grinding time is 6 hours; then put them in an oven and keep them warm for 300 minutes at a temperature of 300°C; then pour them into a porcelain crucible , heated and melted in a high-temperature vacuum electric furnace, the melting temperature is 1200° C., the holding time is 180 minutes, and the vacuum degree is 0.5 MPa to obtain a glass melt.

[0042] (3) Use the vacuum suction casting method to quickly transfer the glass melt obtained in step (2) into a pre-heated stainless s...

Embodiment 3

[0046] The invention provides a Pr 3+ / Ho 3+ Doped ZAlFB glass, its preparation method includes the following steps:.

[0047] (1) According to the molar percentage, take each raw material respectively: ZnF of 9mol% 2 , 5mol% Al 2 o 3 , 29mol% LiF, 56mol% B 2 o 3 , 0.4mol% Pr 6 o 11 , 0.6 mol% HoF 3 , for standby; wherein, the mass percent purity of each raw material is required to be 99.99%.

[0048] (2) Fully grind and mix the raw materials weighed in step (1) in an agate mortar, and the grinding time is 5 hours; then put them in an oven and keep them warm for 600 minutes at a temperature of 100°C; then pour them into a porcelain crucible , heated and melted in a high-temperature vacuum electric furnace with a melting temperature of 1300° C., a holding time of 120 minutes, and a vacuum degree of 0.1 MPa to obtain a glass melt.

[0049] (3) Use the vacuum suction casting method to quickly transfer the glass melt obtained in step (2) into a pre-heated stainless steel...

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Abstract

The invention provides Pr < 3 + > / Ho < 3 + > doped ZAlFB optical fiber glass and a preparation method thereof, and solves the technical problems that in the prior art, due to the fact that the phonon energy of quartz glass is high, the probability of non-radiative transition of rare earth ions is increased, and the luminous intensity in the wave band of 2-3 microns is low. The Pr < 3 + > / Ho < 3 + > doped ZAlFB optical fiber glass is prepared from the following raw materials in mole percent: 9-10 mol% of ZnF2, 4-5 mol% of Al2O3, 29-30 mol% of LiF, 55-56 mol% of B2O3, 0.1-0.5 mol% of Pr6O11 and 0.5-1.0 mol% of HoF3. The preparation method of the Pr < 3 + > / Ho < 3 + > doped ZAlFB optical fiber glass can be widely applied to the field of fiber communication materials.

Description

technical field [0001] The invention belongs to the field of optical fiber communication materials, in particular to a Pr 3+ / Ho 3+ Doped ZAlFB optical fiber glass and its preparation method. Background technique [0002] The mid-infrared laser in the 2-3μm band is close to the absorption peak of water, which is extremely safe for human eyes. It can make human cells instantly heat up and gasify after irradiation, and cover the absorption bands of various toxic gases such as nitric oxide and methane. Therefore, mid-infrared lasers in the 2-3 μm band have important applications in the fields of national defense, medical treatment, sensing and material processing. Fiber lasers have become the focus of research in the field of mid-infrared lasers due to their advantages of good beam quality, high conversion efficiency and small size. As the gain medium of fiber laser, rare earth ion doped glass fiber plays a decisive role in the performance of fiber laser. In terms of rare e...

Claims

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Application Information

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IPC IPC(8): C03C13/04C03B37/012
CPCC03B37/01268C03C13/048
Inventor 陈卫东王传杰张鹏魏敏张桂林张明立
Owner 宏安集团有限公司
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