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Antistatic bacteriostatic ultra-high molecular weight polyethylene fiber and preparation method thereof

An ultra-high molecular weight, polyethylene fiber technology for conductive/antistatic filament manufacturing, single-component polyolefin rayon, fiber chemical characteristics, etc., which can solve the breaking strength and initial modulus negative, inorganic particle migration The problems of high speed and non-ideal antibacterial rate can achieve the effect of reducing migration speed, excellent antistatic effect and excellent mechanical properties.

Pending Publication Date: 2021-04-16
九江中科鑫星新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the low-molecular antistatic agent used in this method gradually precipitates from the surface of the product over time, and the antistatic performance of the material is gradually reduced until lost. The instability of the antistatic performance of the product in the practical process is safe. Hidden dangers of production
[0005] CN106589582A discloses a kind of reinforced and toughened antibacterial polypropylene material and its production method, which adopts nano zinc oxide or titanium dioxide as inorganic antibacterial agent, and then polypropylene, ultra-high molecular weight polyethylene masterbatch, inorganic antibacterial agent, grafted polypropylene and other additives are melted and extruded through a twin-screw extruder to obtain reinforced and toughened antibacterial polypropylene materials. However, when the method is applied to the production of ultra-high molecular weight polyethylene (UHMWPE) fibers, the antibacterial rate is greatly reduced, and the impact on fracture Both the strength and the initial modulus have a negative effect, and the TiO 2 It has antibacterial effect only when it is excited by ultraviolet light, and has no antibacterial ability under other conditions
First of all, the antibacterial rate of the above-mentioned obtained materials is not an ideal effect, which limits its application in the field of medicine, and because its inorganic antibacterial agent molecules are small, the migration speed of inorganic particles is large, and it is easy to be lost from the material to further reduce Its antibacterial rate; secondly, without describing the mechanical properties and antistatic effect of the product, it is difficult to comment on its practicability as a material

Method used

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  • Antistatic bacteriostatic ultra-high molecular weight polyethylene fiber and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0031] An antistatic antibacterial type ultra-high molecular weight polyethylene fiber, consisting of 150 parts by weight of UHMWPE powder, 2 parts by weight of antioxidant, 4 parts by weight of antistatic agent, 35 parts by weight of antibacterial agent, 6 parts by weight of macromolecular compatibilizer, 0.8 parts by weight coupling agent, 6 parts by weight surfactant, 0.5 parts by weight synergist and 750 parts by weight solvent;

[0032] Wherein, the macromolecule compatibilizer is selected from polyethylene grafted with maleic anhydride PE-g-MAH, and the viscosity-average molecular weight of the UHMWPE powder is 6.5 million.

[0033] Described antioxidant is made up of AT168 antioxidant and 412S antioxidant by weight ratio 3: 1.5; Described antistatic agent is made up of conductive carbon black and single-walled carbon nanotube by weight ratio 2.5: 1.5; The coupling The agent selects silane coupling agent KH560; the surfactant is composed of sodium lauryl sulfate, lauryl ...

Embodiment 2

[0045] An antistatic antibacterial type ultra-high molecular weight polyethylene fiber, consisting of 200 parts by weight of UHMWPE powder, 1 part by weight of antioxidant, 5 parts by weight of antistatic agent, 20 parts by weight of antibacterial agent, 10 parts by weight of macromolecular compatibilizer, 0.2 parts by weight coupling agent, 8 parts by weight surfactant, 0.1 parts by weight synergist and 1000 parts by weight solvent;

[0046] Wherein, the macromolecule compatibilizer is selected from polyethylene grafted maleic anhydride / styrene copolymer, and the viscosity-average molecular weight of the UHMWPE powder is 8.5 million.

[0047] Described antioxidant is made up of AT168 antioxidant and 412S antioxidant by weight ratio 5: 1; Described antistatic agent is made up of conductive carbon black and single-walled carbon nanotube by weight ratio 3: 1; The coupling The agent selects silane coupling agent KH570; the surfactant is composed of sodium lauryl sulfate, lauryl a...

Embodiment 3

[0059] An antistatic antibacterial type ultra-high molecular weight polyethylene fiber, consisting of 100 parts by weight of UHMWPE powder, 3 parts by weight of antioxidant, 3 parts of antistatic agent, 50 parts by weight of antibacterial agent, 1 part by weight of macromolecule compatibilizer, 1.4 parts by weight coupling agent, 4 parts by weight surfactant, 1 part by weight synergist and 450 parts by weight solvent;

[0060] Wherein, the macromolecule compatibilizer is selected from polyethylene grafted with maleic anhydride PE-g-MAH, and the viscosity-average molecular weight of the UHMWPE powder is 4.5 million.

[0061] Described antioxidant is made up of AT168 antioxidant and 412S antioxidant by weight ratio 1: 2; Described antistatic agent is made up of conductive carbon black and single-wall carbon nanotube by weight ratio 2: 2; The coupling The agent selects silane coupling agent DL602; the surfactant is composed of sodium lauryl sulfate, lauryl amidopropyl betaine and...

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Abstract

The invention belongs to the technical field of ultra-high molecular weight polyethylene fibers, and particularly relates to an antistatic antibacterial ultra-high molecular weight polyethylene fiber. The antistatic antibacterial ultra-high molecular weight polyethylene fiber is composed of the following components of, in parts by weight, 100-200 parts of ultra-high molecular weight polyethylene, 1-3 parts of an antioxidant, 3-5 parts of an antistatic agent, 20-50 parts of an antibacterial agent, 1-10 parts of a macromolecular compatilizer, 0.2-1.4 parts of a coupling agent, 4-8 parts of a surfactant, 0.1-1 part of a synergist and 450-1,000 parts of a solvent. According to the antistatic bacteriostatic ultra-high molecular weight polyethylene fiber and the preparation method thereof, a reasonable formula is selected, and all the components have a synergistic effect, so that the overall performance of the UHMWPE fiber is effectively improved, particularly, the UHMWPE fiber has stronger antistatic and antibacterial properties, excellent mechanical properties of the material can be maintained, the stability is high, the service life of the UHMWPE fiber is prolonged, and the use cost is reduced.

Description

technical field [0001] The invention belongs to the technical field of ultra-high molecular weight polyethylene fibers, and in particular relates to an antistatic and antibacterial ultra-high molecular weight polyethylene fiber and a preparation method thereof. Background technique [0002] Ultra-high molecular weight polyethylene (UHMWPE) fibers have the characteristics of high strength, high modulus, and high thermal conductivity, and are irreplaceable in many fields. It is pioneering to produce a UHMWPE fiber with antibacterial function, which can enrich the performance and function of UHMWPE fiber and expand the application of UHMWPE fiber in civil fabrics, medical equipment and other fields. [0003] UHMWPE fiber has low surface energy and surface tension, high crystallinity, and extremely smooth surface. It is difficult to effectively combine with commonly used inorganic and organic antibacterial agents, which makes post-treatment methods such as padding and coating an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/46D01F1/09D01F1/07D01F1/10
Inventor 时艳李祈利万小江
Owner 九江中科鑫星新材料有限公司
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