Preparation method of high-performance nano rare earth doped barium ferrite permanent magnet material

Abstract

The invention discloses a preparation method of a high-performance nano rare earth doped barium ferrite permanent magnet material, wherein the chemical composition formula of the rare earth doped barium ferrite is Ba1-xLnxFe12-xAxO19, the element Ln in the compound is rare earth elements such as La, Yb and the like, the element A is a divalent transition group metal element such as Co and the like, and x is greater than or equal to 0 and less than or equal to 0.5. According to the invention, a Ba1-xLnxFe12-xAxO19 precursor is prepared through a coprecipitation method of a Taylor reactor, thenmagnetic field orientation and sintering are carried out to obtain the rare earth doped barium ferrite, the preparation method can obtain the precursor with good crystallinity and the size of 100-200nm, and the barium ferrite obtained after co-doping and sintering of rare earth elements and metal elements is higher in magnetic performance; and the preparation method can effectively reduce high-temperature sintering temperature and time and save energy consumption.

Description

technical field [0001] The invention relates to a preparation method of a high-performance nano rare earth doped barium ferrite permanent magnet material, belonging to the field of magnetic materials. Background technique [0002] In recent years, ferrite materials have been developed rapidly, and rare earth barium ferrite materials are favored by virtue of their advantages such as uniaxial magnetic dissimilarity, high coercive force, high Curie temperature, strong chemical stability, and superior cost performance. received widespread attention. [0003] However, ferrite materials prepared by traditional high-temperature solid-state sintering have complicated process flow, long sintering time, and high temperature requirements, resulting in very high energy consumption, and the prepared ferrite materials have low uniformity. [0004] In order to improve the magnetic properties of ferrite materials and reduce energy consumption, researchers used sol-gel method and co-precipi...

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Problems solved by technology

[0003] However, the ferrite material prepared by traditional high-temperature solid-state sintering has complex process flow, long sintering time, and high temperature requirements, resulting in very high energy consumption and low uniformity of the prepared ferrite material

[0004] In order to improve the magnetic properties of ferrite materials and reduce energy consumption, researchers used sol-gel method and co-precipitation method to prepare nano-scale to micro-scale ferrite materials, which improved the magnetic properties of materials, such as patent CN201210418388.8, CN201110102232.4, CN106082349A, CN201310601472.8, CN108554414A and CN108046791A and other nano-ferrite preparation methods, but the amount of ferrite prepared by this co-precipitation method is generally small, the repeatability is poor, and it cannot be produced continuously. The pollution caused by the glue method is relatively large, and the shape is uncontrollable, so neither of these two methods can be used in actual industrial production on a large scale.