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Bi-component high-temperature-resistant and low-temperature-resistant novel acrylate structural adhesive and preparation method thereof

An acrylate and acrylate-based technology, applied in the direction of adhesives, polymer adhesive additives, non-polymer adhesive additives, etc., to achieve the effects of short heating and curing time, good stability, and excellent process performance

Inactive Publication Date: 2021-01-22
南京博新新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the increasing application requirements of products, acrylic structural adhesive products need better high and low temperature resistance, while maintaining the original high strength and toughness requirements, and existing products cannot fully meet the requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0028] Specific embodiment 1: This embodiment provides a two-component high-temperature-resistant novel acrylic structural adhesive, including component A and component B; the volume ratio of component A and component B is (5- 15): 1; wherein, component A is prepared from the following raw materials in weight ratio: 30-60 parts of acrylic monomer a, 5-30 parts of polyimide oligomer, 5-20 parts 1-5 parts of toughening agent, 1-5 parts of stabilizer, 0.5-5 parts of coupling agent, 0.5-5 parts of accelerator, 0.5-5 parts of other auxiliary agents; the B component is formulated by the following weight It is prepared from the following raw materials: 10-40 parts of acrylate monomer b, 10-50 parts of plasticizer, 3-10 parts of oxidizing agent and 0.1-0.5 parts of polymerization inhibitor.

[0029] In this embodiment, methyl methacrylate can be selected as the acrylate monomer; methyl methacrylate is the main active monomer of acrylic structural adhesives, and at the same time, highe...

specific Embodiment approach 2

[0039] Embodiment 2: The difference between this embodiment and Embodiment 1 is that: the volume ratio of the A component and the B component is (9-11):1, and the others are the same as the Embodiment 1.

specific Embodiment approach 3

[0040] Specific embodiment 3: The difference between this embodiment and specific embodiments 1 and 2 is that the volume ratio of the A component and B component is 10:1, and the others are the same as the specific embodiments 1 and 2.

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PUM

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Abstract

The invention relates to a bi-component high-temperature-resistant and low-temperature-resistant novel acrylate structural adhesive and a preparation method thereof. The structural adhesive comprisesa component A and a component B, wherein the component A comprises an acrylate monomer a, a polyimide oligomer, a flexibilizer, a stabilizer, a coupling agent, an accelerator and other assistants; andthe component B comprises an acrylate monomer b, a plasticizer, an oxidant and a polymerization inhibitor. The preparation method comprises the following steps: mixing the acrylate monomer a, the polyimide oligomer and the flexibilizer in proportion until the components are completely dissolved, adding the stabilizer, the accelerant and other assistants, uniformly mixing, adding the coupling agent, stirring, and defoaming to obtain the component A; uniformly mixing the acrylate monomer b, the plasticizer, the oxidant and the polymerization inhibitor, and defoaming to obtain the component B; when the structural adhesive is used, the component A and the component B are mixed to obtain the structural adhesive. The structural adhesive provided by the invention has excellent high and low temperature resistance, good stability, long storage time and simple preparation method; the sizing is easy to control and convenient to operate.

Description

technical field [0001] The invention relates to the field of adhesives, in particular to a novel two-component high- and low-temperature-resistant acrylate structural adhesive and a preparation method thereof. Background technique [0002] Acrylic structural adhesive is a reactive two-component adhesive, which has been widely used in structural bonding due to its simple process, fast curing at room temperature, good toughness, high strength, and oil surface bonding. [0003] With the development of the times and the continuous improvement of product requirements, the existing acrylic structural adhesives have high bonding strength, extensive bonding performance, fast curing at room temperature, excellent weather resistance and stability, and good comprehensive performance; Some products have high toughness and high strength; some products have low odor and so on. However, with the increasing application requirements of products, acrylic structural adhesive products need bet...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J4/02C09J4/06C09J11/06C09J11/08
CPCC09J4/06C09J11/06C09J11/08
Inventor 许林利
Owner 南京博新新材料有限公司
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