Sinking expansion polyurethane with strong tearing property and preparation method thereof
A polyurethane and modified polyester technology, applied in the field of polyurethane, can solve the problems of poor mechanical properties, inconvenient practical application, and short service life of filter sponges
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Embodiment 1
[0042] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:
[0043] (1) Preparation of modified isocyanate:
[0044] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1.5h, keep stirring while ultrasonically dispersing, condense and reflux in an oil bath at 62°C, continue stirring for 2.5h, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry , to obtain pretreated carbon nanotubes; wherein the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.
[0045] Take the pretreated carbon nanotubes and anhydrous toluene, stir and react for 0.9h under a nitrogen environment, continue to carry out ultrasonic dispersion during stirring, and then place it in an oil bath at 63°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 9 hours, filter with suction, wash an...
Embodiment 2
[0052] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:
[0053] (1) Preparation of modified isocyanate:
[0054] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1 hour, continue to stir during ultrasonic dispersion, condense and reflux in an oil bath at 60°C, continue to stir and react for 3 hours, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry to obtain Pretreatment of carbon nanotubes; the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.
[0055] Take pretreated carbon nanotubes and anhydrous toluene, stir and react under nitrogen atmosphere for 0.8h, continue to carry out ultrasonic dispersion during stirring, and then place them in an oil bath at 60°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 10 hours, filter with suction, wa...
Embodiment 3
[0062] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:
[0063] (1) Preparation of modified isocyanate:
[0064] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1.5h, keep stirring while ultrasonically dispersing, condense and reflux in an oil bath at 62°C, continue stirring for 2.5h, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry , to obtain pretreated carbon nanotubes; wherein the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.
[0065] Take the pretreated carbon nanotubes and anhydrous toluene, stir and react for 0.9h under a nitrogen environment, continue to carry out ultrasonic dispersion during stirring, and then place it in an oil bath at 63°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 9 hours, filter with suction, wash an...
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