Sinking expansion polyurethane with strong tearing property and preparation method thereof

A polyurethane and modified polyester technology, applied in the field of polyurethane, can solve the problems of poor mechanical properties, inconvenient practical application, and short service life of filter sponges

Pending Publication Date: 2021-01-22
盐城市恒丰海绵有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Filter sponge, also known as mesh sponge, blasting sponge, conventional filter sponge is generally polyurethane sponge, which is processed by ordinary open-cell soft foam through net treatment, and net treatment removes the original mask between the foam network Or the wall membrane, obtained the main frame network structure, but the mechanical properties of the existing filter sponge are poor, the tearing property is poor, and the service life is short, which brings inconvenience to practical application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:

[0043] (1) Preparation of modified isocyanate:

[0044] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1.5h, keep stirring while ultrasonically dispersing, condense and reflux in an oil bath at 62°C, continue stirring for 2.5h, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry , to obtain pretreated carbon nanotubes; wherein the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.

[0045] Take the pretreated carbon nanotubes and anhydrous toluene, stir and react for 0.9h under a nitrogen environment, continue to carry out ultrasonic dispersion during stirring, and then place it in an oil bath at 63°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 9 hours, filter with suction, wash an...

Embodiment 2

[0052] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:

[0053] (1) Preparation of modified isocyanate:

[0054] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1 hour, continue to stir during ultrasonic dispersion, condense and reflux in an oil bath at 60°C, continue to stir and react for 3 hours, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry to obtain Pretreatment of carbon nanotubes; the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.

[0055] Take pretreated carbon nanotubes and anhydrous toluene, stir and react under nitrogen atmosphere for 0.8h, continue to carry out ultrasonic dispersion during stirring, and then place them in an oil bath at 60°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 10 hours, filter with suction, wa...

Embodiment 3

[0062] A preparation method of a bottom-sinking expanded polyurethane with strong tearability, comprising the following steps:

[0063] (1) Preparation of modified isocyanate:

[0064] Mix carbon nanotubes and mixed acid, ultrasonically disperse for 1.5h, keep stirring while ultrasonically dispersing, condense and reflux in an oil bath at 62°C, continue stirring for 2.5h, cool to room temperature, filter with suction, wash with deionized water until neutral, and dry , to obtain pretreated carbon nanotubes; wherein the mixed acid is a mixture of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1.

[0065] Take the pretreated carbon nanotubes and anhydrous toluene, stir and react for 0.9h under a nitrogen environment, continue to carry out ultrasonic dispersion during stirring, and then place it in an oil bath at 63°C, add toluene diisocyanate and dibutyltin dilaurate catalyst, and continue stirring React for 9 hours, filter with suction, wash an...

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PUM

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Abstract

The invention discloses sinking expansion polyurethane with strong tearing property and a preparation method thereof. The polyurethane is prepared from the following raw materials in parts by weight:80-90 parts of modified polyester polyol, 50-60 parts of modified isocyanate, 10-20 parts of polyether polyol, 0.01-0.02 part of a catalyst, 1-1.5 parts of an antioxidant, 1-1.5 parts of ethylene glycol, 1-1.5 parts of a surfactant and 6-8 parts of a hydrophilic agent. The invention discloses sinking expansion polyurethane with strong tearing property and a preparation method thereof, and the prepared polyurethane not only can sink to adsorb pollutants at the bottom of water, but also has excellent tearing strength and tensile strength and excellent mechanical properties, can be applied to filtering processes such as sewage treatment and the like, and has higher practicability.

Description

technical field [0001] The invention relates to the technical field of polyurethane, in particular to a bottom-sinking expanded polyurethane with strong tear resistance and a preparation method thereof. Background technique [0002] With the rapid development of the economy, the increasing discharge of oily sewage in the industry has caused great environmental problems. The large discharge of industrial sewage will not only damage the ecosystem, but also damage people's health. Therefore, researchers have been committed to finding and researching Simpler and more efficient sewage treatment materials and treatment methods, and in the existing treatment process, filter sponge is one of our commonly used materials. [0003] Filter sponge, also known as mesh sponge, blasting sponge, conventional filter sponge is generally polyurethane sponge, which is processed by ordinary open-cell soft foam through net treatment, and net treatment removes the original mask between the foam net...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/63C08G18/48C08G18/38C08G18/32C08K9/02C08K3/04C02F1/28
CPCC08G18/6666C08G18/631C08G18/3206C08G18/4825C08G18/4072C08G18/3895C08K9/02C08K3/041C02F1/285C08K2201/011
Inventor 顾紫敬
Owner 盐城市恒丰海绵有限公司
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