UV-curing adhesive based polarizing plate and preparation method thereof
An adhesive and polarizing plate technology, applied in the direction of adhesives, non-polymer organic compound adhesives, polarizing elements, etc., can solve the problems of inability to pass light, light leakage from polarizing plates, dark light brightness, etc., to improve durability and prevent viscosity. and reaction speed, the effect of increasing interfacial adhesion
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[0034] According to the parts by weight of Table 1, bifunctional alicyclic epoxy compounds, polyglycidyl ethers of aromatic compounds, bifunctional (meth)acrylic compounds, vinyl ether compounds, carboxylic acid compounds containing unsaturated double bonds, Cationic photoinitiators and free radical initiators are routinely mixed to prepare UV-curable adhesives for polarizers. Wherein, in embodiment 5, the vinyl ether compound is 4-hydroxybutyl vinyl ether; in embodiment 6, the carboxylic acid compound containing unsaturated double bonds is fumaric acid; in embodiment 10, will contain The carboxylic acid compound with saturated double bond is replaced with polycaprolactone trihydric alcohol, a conventional adhesion promoter; the rest of the raw materials are as above A to G.
Embodiment 8
[0054] The peeling force of Example 8 reaches 5.6N / cm (PET film), 5.3N / cm (TAC film), 5.5N / cm (COP film); the white edge of the existing commercially available adhesive polarizing plate is very small after heat and humidity resistance, 0.1 mm, but the peel force is low and selective, 3.1N / cm (PET film), 3.3N / cm (TAC film), 1.9N / cm (COP film).
[0055] Table 2 embodiment, comparative example test result
[0056]
[0057]
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