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High-pressure-bearing plugging agent for oil extraction casing pipe and processing technology thereof

The invention relates to a processing technology and a technology for a leakage plugging agent, which is applied in the field of a high pressure-bearing leakage plugging agent for oil production casings and its processing technology. Strength, weak pressure bearing capacity and other problems, to achieve the effect of strong pressure bearing capacity, enhanced sealing and less corrosion

Active Publication Date: 2020-11-27
DONGYING DONGFANG CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Conventional gel plugging technology has achieved relatively good results in field application, but there are still some disadvantages, such as the crosslinking domain line in the polymer system, it is difficult to form a continuous space network structure, which leads to the failure of the gel plugging agent. The strength is not high, and the pressure bearing capacity is weak; the gel polymer is easily affected by the external temperature, which makes it difficult to control the gelation time and gelation strength of the plugging agent during on-site construction

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A high-pressure plugging agent for oil production casing, the raw material components are as follows; by weight fraction, 48 parts of MOFs-modified epoxy resin, 23 parts of solid particles, 17 parts of curing agent, 13 parts of coupling agent, curing Regulator 0.7 parts.

[0022] The solid particles are a mixture of bentonite and attapulgite, and the mass ratio of bentonite to attapulgite is 3:1.

[0023] A kind of processing technology of high pressure bearing plugging agent for oil production casing, comprises the following steps (1) MOFs-modified epoxy resin: take acrylate monomer, methacrylic acid, acrylonitrile, and its mass ratio is 75:5: 10. Dissolve in acetone solution at 8°C, add dimethyl azobisisobutyrate, raise the temperature to 48°C, react for 2.5 hours, cool, and dry in vacuum to obtain substance A; take nano-silicon nitride Dissolve in acetone solution, add substance A, stir, react at 105°C for 2 hours, and dry in vacuum to obtain substance B;

[0024] ...

Embodiment 2

[0028] A high-pressure plugging agent for oil production casing, the raw material components are as follows; by weight fraction, 51 parts of MOFs-modified epoxy resin, 25 parts of solid particles, 20 parts of curing agent, 14 parts of coupling agent, curing Regulator 1.0 parts.

[0029] The solid particles are a mixture of bentonite and attapulgite, and the mass ratio of bentonite to attapulgite is 3:1.

[0030] A kind of processing technology of high pressure bearing plugging agent for oil production casing, comprises the following steps (1) MOFs-modified epoxy resin: take acrylate monomer, methacrylic acid, acrylonitrile, and its mass ratio is 75:5: 10. Dissolve in acetone solution at a temperature of 9°C, add dimethyl azobisisobutyrate, raise the temperature to 51°C, react for 2.7 hours, cool, and dry in vacuum to obtain substance A; take nano-silicon nitride Dissolve in acetone solution, add substance A, stir, react at 112°C for 2.2 hours, and dry in vacuum to obtain substa...

Embodiment 3

[0035] A high pressure-bearing plugging agent for oil production casing, the raw material components are as follows; by weight fraction, 60 parts of MOFs-modified epoxy resin, 27 parts of solid particles, 21 parts of curing agent, 17 parts of coupling agent, curing Regulator 1.2 parts.

[0036] The solid particles are a mixture of bentonite and attapulgite, and the mass ratio of bentonite to attapulgite is 3:1.

[0037] A kind of processing technology of high pressure bearing plugging agent for oil production casing, comprises the following steps (1) MOFs-modified epoxy resin: take acrylate monomer, methacrylic acid, acrylonitrile, and its mass ratio is 75:5: 10. Dissolve in acetone solution at a temperature of 10°C, add dimethyl azobisisobutyrate, raise the temperature to 52°C, react for 3 hours, cool, and dry in vacuum to obtain substance A; take nano-silicon nitride to dissolve Add substance A to acetone solution, stir, react at 115°C for 2.5 hours, and dry in vacuum to ob...

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PUM

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Abstract

The invention discloses a high-pressure-bearing plugging agent for an oil extraction casing pipe and a processing technology thereof. The high-pressure-bearing plugging agent for an oil extraction casing pipe comprises 48-60 parts of MOFs-modified epoxy resin, 23-27 parts of solid particles, 17-21 parts of a curing agent, 13-17 parts of a coupling agent and 0.7-1.2 parts of a curing regulator. TheMOFs-modified epoxy resin is prepared from bisphenol A epoxy resin, nano silicon nitride, an acrylate monomer, methacrylic acid, acrylonitrile, hydroxyl-terminated nitrile rubber powder and an MOFs material through multistage reaction, the modified epoxy resin is crosslinked with the curing agent and the solid particles to form the plugging agent, and the plugging agent has the advantages of highmechanical strength, strong pressure bearing capacity, high thermal stability, salt and alkali resistance and capability of slowly expanding when meeting water to enhance the sealing property. The plugging agent acts on an oil extraction casing pipe, can effectively plug leakage layers such as pores and cracks, and can extrude to prevent leakage.

Description

technical field [0001] The invention relates to the technical field of oil field chemical plugging, in particular to a high-pressure plugging agent for oil production casings and a processing technology thereof. Background technique [0002] With the long-term exploitation of oil, gas and water wells, in some old wells, the service life of the oil layer casing is too long, and the cementing cement has not completely sealed the oil layer casing. The free section, the sealing section, and the production section are perforated due to corrosion, coupled with special and complex geological conditions, the development of the salt-gypsum layer, and the movement of the earth's crust, resulting in deformation of the casing, damage to the formation, mud, water, and long-term water injection In development, especially pressurized water injection, oil and water well casing damage is very common, and the problem of well condition deterioration has become increasingly prominent, seriously...

Claims

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Application Information

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IPC IPC(8): C09K8/467C09K8/42C08F279/02C08F220/06C08F220/46C08F220/18C08G59/14C04B24/42
CPCC09K8/426C09K8/422C09K8/467C08F279/02C08G59/14C04B40/0039C08F220/06C08F220/46C08F220/18C04B24/281C04B22/08C04B24/121C04B24/287C04B24/42Y02P20/141
Inventor 毕海涛杜森昌孟庆东周志全宋健张安东
Owner DONGYING DONGFANG CHEM IND
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