Schiff base-based polyurethane/chitosan self-healing hydrogel and preparation method thereof
A technology of polyurethane and chitosan, applied in medical science, bandages, etc., can solve problems such as poor mechanical properties, achieve good mechanical properties, superior antibacterial properties, and convenient use
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Embodiment 1
[0030] A kind of polyurethane / chitosan self-healing hydrogel based on Schiff's base, which is prepared by cross-linking imine bonds with aldylated polyurethane and chitosan as raw materials; amino groups and aldehydes in the chitosan The molar ratio of aldehyde groups in the alkylated polyurethane is 1:1; the solid content of the self-healing hydrogel is 10.5%.
[0031] The above-mentioned preparation method of polyurethane / chitosan self-healing hydrogel based on Schiff base specifically comprises the following steps:
[0032] (1) Weigh 40g of polyethylene glycol and 5.34g of isophorone diisocyanate and dissolve them in 20g of acetone at 60°C. After fully dissolving, add 0.009g of organotin catalyst dropwise and keep at 60°C for 30 minutes to obtain a colorless Transparent polyurethane prepolymer solution.
[0033] (2) Take 1.1g 2,4-dihydroxybenzaldehyde and disperse it in 20g acetone, add the dispersion liquid to the polyurethane prepolymer solution prepared in step (1), aft...
Embodiment 2
[0039]A kind of polyurethane / chitosan self-healing hydrogel based on Schiff's base, which is prepared by cross-linking imine bonds with aldylated polyurethane and chitosan as raw materials; amino groups and aldehydes in the chitosan The molar ratio of aldehyde groups in the alkylated polyurethane is 3:1; the solid content of the self-healing hydrogel is 8.7%.
[0040] The above-mentioned preparation method of polyurethane / chitosan self-healing hydrogel based on Schiff base specifically comprises the following steps:
[0041] (1) Weigh 40g of polyethylene glycol and 5.56g of isophorone diisocyanate and dissolve them in 20g of acetone at 60°C. After fully dissolving, add 0.009g of organotin catalyst dropwise and keep at 60°C for 25 minutes to obtain a colorless Transparent polyurethane prepolymer solution.
[0042] (2) Take 1.38g 2,4-dihydroxybenzaldehyde and disperse it in 10g acetone, add the dispersion liquid to the polyurethane prepolymer solution prepared in step (1), afte...
Embodiment 3
[0048] A kind of polyurethane / chitosan self-healing hydrogel based on Schiff's base, which is prepared by cross-linking imine bonds with aldylated polyurethane and chitosan as raw materials; amino groups and aldehydes in the chitosan The molar ratio of aldehyde groups in the alkylated polyurethane is 1:1; the solid content of the self-healing hydrogel is 10.6%.
[0049] The above-mentioned preparation method of polyurethane / chitosan self-healing hydrogel based on Schiff base specifically comprises the following steps:
[0050] (1) Weigh 40g of polyethylene glycol and 5.56g of isophorone diisocyanate and dissolve them in 20g of acetone at 60°C. After fully dissolving, add 0.009g of organotin catalyst dropwise and keep at 60°C for 25 minutes to obtain a colorless Transparent polyurethane prepolymer solution.
[0051] (2) Weigh 1.38g 2,4-dihydroxybenzaldehyde and disperse it in 10g of acetone, add the dispersion to the polyurethane prepolymer solution prepared in step (1), and r...
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