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Heat-resistant filter felt, preparation method thereof and composite filter felt prepared from heat-resistant filter felt

A technology of composite filtration and filter felt, which is applied in the direction of filtration separation, membrane filter, separation method, etc., can solve the problem of difficulty in further improving the service life of composite felt, poor heat resistance of polyphenylene sulfide fibers, and heat resistance of high-temperature filter materials Poor performance and other problems, to achieve the effect of good surface self-cleaning performance, good mechanical properties, and increase the glass transition temperature

Active Publication Date: 2020-06-30
上海钱丰纺织品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, in practical applications, the flue gas temperature often exceeds 150°C, and the high temperature environment will aggravate the aging problem of PPS fibers, which results in a short service life of PPS fiber mats and increases the cost of waste gas treatment
In order to overcome this problem, the patent 201220079645.5 adds polytetrafluoroethylene fiber to polyphenylene sulfide fiber to make polyphenylene sulfide fiber / polytetrafluoroethylene fiber composite felt, which prolongs the service life, but the polytetrafluoroethylene fiber The processing difficulties brought about by surface self-lubrication, creep and low strength characteristics limit the amount of polytetrafluoroethylene added, which makes it difficult to further improve the service life of the composite felt. At the same time, the polyphenylene sulfide fiber in the composite felt The aging problem will still affect the overall life of the composite felt, and this method does not fundamentally solve the problem of poor heat resistance of high-temperature filter materials
[0004] Therefore, it is of great practical significance to fundamentally solve the poor heat resistance of polyphenylene sulfide fiber and develop a filter felt with excellent heat resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A preparation method of a heat-resistant filter felt, the steps are as follows:

[0034] (1) prepare modified polyphenylene sulfide;

[0035] (1.1) 500 kg of polyphenylene sulfide fibers having a fineness of 1.5 denier and a length of 51 mm were immersed in 1000 kg of an aqueous solution of 0.5 wt % potassium permanganate.

[0036] (1.2) continuously feed ozone in the system of step (1.1), and fully mix, adopt the system of the high-energy electron beam irradiation step (1.1) that energy is 10Mev to carry out grafting reaction to its weight gain 25wt% simultaneously, the flow rate of ozone 800 kg / min;

[0037] (1.3) Wash and dry after taking out the reaction product to obtain modified polyphenylene sulfide;

[0038] The prepared modified polyphenylene sulfide has a glass transition temperature of 425°C, an LOI of 37%, and no molten droplets are produced during combustion. In the modified polyphenylene sulfide molecule, each sulfur atom is randomly associated with N ox...

Embodiment 2

[0045] A preparation method of a heat-resistant filter felt, the steps are as follows:

[0046] The modified polyphenylene sulfide fiber obtained in Example 1 and the polytetrafluoroethylene fiber with a denier of 2.0 denier and a length of 51 mm are blended in a mass ratio of 60:40 and then hydroentangled to obtain a heat-resistant filter. felt.

[0047] The area gram weight of the heat-resistant filter felt made is 500 grams / m 2 ; After thermo-oxidative aging for 100 hours under air conditions at a temperature of 280°C, the tensile strength retention rate is 92%.

[0048] Heat-resistant filter felt with an area weight of 80 g / m 2 The base cloth is compounded to make a composite filter felt, the base cloth is woven from yarn, and the yarn is spun from polytetrafluoroethylene fiber.

[0049] The final composite filter felt has a warp strength of 800N and a weft strength of 800N.

Embodiment 3

[0051] A preparation method of a heat-resistant filter felt, the steps are as follows:

[0052] The modified polyphenylene sulfide fiber obtained in Example 1 and the polytetrafluoroethylene fiber with a denier of 3.0 denier and a length of 51 mm were blended at a mass ratio of 70:30 and then needle punched to obtain a heat-resistant filter felt .

[0053] The area gram weight of the heat-resistant filter felt made is 600 grams / m 2 ; After thermo-oxidative aging for 100 hours under air conditions at a temperature of 280°C, the tensile strength retention rate is 94%.

[0054] Heat-resistant filter felt with an area weight of 100 g / m 2 The base cloth is compounded to make a composite filter felt, the base cloth is woven from yarn, and the yarn is spun from the modified polyphenylene sulfide fiber prepared in Example 1.

[0055] The final composite filter felt has a warp strength of 980N and a weft strength of 980N.

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Abstract

The invention relates to a heat-resistant filter felt, a preparation method thereof and a composite filter felt prepared from the heat-resistant filter felt. The preparation method comprises the stepsthat modified polyphenylene sulfide fibers and polytetrafluoroethylene fibers are blended and then subjected to needling or spunlace processing, the heat-resistant filter felt is prepared, wherein the modified polyphenylene sulfide is polyphenylene sulfide with each sulfur atom randomly connected with N oxygen atoms, and the molar ratio of the oxygen atoms to the sulfur atoms in the modified polyphenylene sulfide is 1.50-1.77: 1. After the prepared heat-resistant filter felt is subjected to thermo-oxidative aging for 100 hours under the air condition that the temperature is 280 DEG C, the tensile strength retention rate is 90% or above. The composite filter felt prepared from the heat-resistant filter felt is mainly composed of base cloth and the heat-resistant filter felt compounded withthe base cloth. The preparation method disclosed by the invention is simple in process and low in cost; the prepared heat-resistant filter felt is excellent in heat resistance; the composite filter felt prepared from the heat-resistant filter felt is excellent in heat resistance and mechanical property and has a great application prospect.

Description

technical field [0001] The invention belongs to the technical field of high-performance industrial textile materials, and relates to a heat-resistant filter felt, a preparation method thereof and a composite filter felt made therefrom, in particular to a modified polyphenylene sulfide with a high glass transition temperature A filter felt obtained by blending fibers and polytetrafluoroethylene fibers, a preparation method thereof and a composite filter felt made therefrom. Background technique [0002] With the development of society, environmental issues have attracted more and more public attention. The main source of air pollutants today is the combustion of fossil fuels, of which emissions from coal-fired thermal power plants account for a large proportion. At present, thermal power stations generally need to treat exhaust gas before discharging exhaust gas, and dust removal is a key step in exhaust gas treatment. At present, thermal power stations mostly use high-temp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/16B01D46/00
CPCB01D39/1623B01D46/0001B01D2239/0216B01D2273/20
Inventor 范同波钱辉春陈利
Owner 上海钱丰纺织品有限公司
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