Heat-resistant filter felt, preparation method thereof and composite filter felt prepared from heat-resistant filter felt
A technology of composite filtration and filter felt, which is applied in the direction of filtration separation, membrane filter, separation method, etc., can solve the problem of difficulty in further improving the service life of composite felt, poor heat resistance of polyphenylene sulfide fibers, and heat resistance of high-temperature filter materials Poor performance and other problems, to achieve the effect of good surface self-cleaning performance, good mechanical properties, and increase the glass transition temperature
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Embodiment 1
[0033] A preparation method of a heat-resistant filter felt, the steps are as follows:
[0034] (1) prepare modified polyphenylene sulfide;
[0035] (1.1) 500 kg of polyphenylene sulfide fibers having a fineness of 1.5 denier and a length of 51 mm were immersed in 1000 kg of an aqueous solution of 0.5 wt % potassium permanganate.
[0036] (1.2) continuously feed ozone in the system of step (1.1), and fully mix, adopt the system of the high-energy electron beam irradiation step (1.1) that energy is 10Mev to carry out grafting reaction to its weight gain 25wt% simultaneously, the flow rate of ozone 800 kg / min;
[0037] (1.3) Wash and dry after taking out the reaction product to obtain modified polyphenylene sulfide;
[0038] The prepared modified polyphenylene sulfide has a glass transition temperature of 425°C, an LOI of 37%, and no molten droplets are produced during combustion. In the modified polyphenylene sulfide molecule, each sulfur atom is randomly associated with N ox...
Embodiment 2
[0045] A preparation method of a heat-resistant filter felt, the steps are as follows:
[0046] The modified polyphenylene sulfide fiber obtained in Example 1 and the polytetrafluoroethylene fiber with a denier of 2.0 denier and a length of 51 mm are blended in a mass ratio of 60:40 and then hydroentangled to obtain a heat-resistant filter. felt.
[0047] The area gram weight of the heat-resistant filter felt made is 500 grams / m 2 ; After thermo-oxidative aging for 100 hours under air conditions at a temperature of 280°C, the tensile strength retention rate is 92%.
[0048] Heat-resistant filter felt with an area weight of 80 g / m 2 The base cloth is compounded to make a composite filter felt, the base cloth is woven from yarn, and the yarn is spun from polytetrafluoroethylene fiber.
[0049] The final composite filter felt has a warp strength of 800N and a weft strength of 800N.
Embodiment 3
[0051] A preparation method of a heat-resistant filter felt, the steps are as follows:
[0052] The modified polyphenylene sulfide fiber obtained in Example 1 and the polytetrafluoroethylene fiber with a denier of 3.0 denier and a length of 51 mm were blended at a mass ratio of 70:30 and then needle punched to obtain a heat-resistant filter felt .
[0053] The area gram weight of the heat-resistant filter felt made is 600 grams / m 2 ; After thermo-oxidative aging for 100 hours under air conditions at a temperature of 280°C, the tensile strength retention rate is 94%.
[0054] Heat-resistant filter felt with an area weight of 100 g / m 2 The base cloth is compounded to make a composite filter felt, the base cloth is woven from yarn, and the yarn is spun from the modified polyphenylene sulfide fiber prepared in Example 1.
[0055] The final composite filter felt has a warp strength of 980N and a weft strength of 980N.
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