Water-based amino baking varnish for galvanized sheets and preparation method thereof

A technology of amino baking varnish and water-based amino resin, applied in coatings, anti-corrosion coatings, polyester coatings, etc., can solve the problems of affecting the anti-corrosion performance of the zinc layer on steel plates, immature water-based coatings, and poor adhesion of primers, etc., to achieve Excellent salt spray performance, improved binding force, and good chemical resistance

Inactive Publication Date: 2020-05-29
山东七维新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The fatty acid substances contained in the coatings of the prior art are easy to undergo saponification reaction with zinc to form zinc soap, which destroys the zinc layer on the surface of the steel plate. On the one hand, it affects the anti-corrosion performance of the zinc layer on the steel plate. Smooth, which is not conducive to the adhesion of the existing paint film, and the raw materials in the existing paint are easy to react with zinc, and the resulting basic double salt is easily soluble in water, which will lead to poor adhesion of the primer and easy peeling off of the paint layer
Generally speaking, the existing water-based coatings for galvanized sheets are still immature, and it is difficult to meet some occasions with relatively high performance requirements. Therefore, it is particularly important to develop corresponding water-based coating products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A water-based amino baking varnish for galvanized sheets, consisting of raw materials of the following qualities:

[0027] 200g of water-based polyester resin, 50g of water-based amino resin, 50g of titanium dioxide, 10g of carbon black, 100g of barium sulfate, 50g of epoxy modified wollastonite, 0.5g of bentonite, 5g of gas silicon, 50g of ethylene glycol butyl ether, and butyl dipropylene glycol Ether 100g, dispersant 10g, defoamer I 1g, defoamer II 5g, wetting agent 3g, leveling agent 3g, amine neutralizer (DMEA) 12g, anti-sag additive 3g, matting powder 50g, adhesion promoter Agent 10g, deionized water 300g.

[0028] The preparation method of above-mentioned galvanized sheet water-based amino baking varnish, the process is as follows:

[0029] (1) After the above-mentioned weighed raw materials are prepared, put deionized water, neutralizer, water-based dispersant, defoamer I, bentonite, and alcohol ether additives into the stirring tank in sequence at a speed of 8...

Embodiment 2

[0031] A water-based amino baking varnish for galvanized sheets, consisting of raw materials of the following qualities:

[0032] Water-based polyester resin 200g, water-based amino resin 50g, titanium dioxide 50g, carbon black 10g, barium sulfate 100g, epoxy modified wollastonite 50g, anti-rust pigment 50g, bentonite 0.5g, gas silicon 5g, butyl glycol ether 50g, 100g of dipropylene glycol butyl ether, 10g of dispersant, 1g of defoamer I, 5g of defoamer II, 3g of wetting agent, 3g of leveling agent, 12g of amine neutralizer (DMEA), 3g of anti-sag additive, adhesion Accelerator 10g, deionized water 300g.

[0033] The difference between the specific preparation method and Example 1 is that antirust pigments are added in step (2), and matting powder is not added in step (3).

Embodiment 3

[0035] A water-based amino baking varnish for galvanized sheets, consisting of raw materials of the following qualities:

[0036] Water-based polyester resin 200g, water-based amino resin 50g, titanium dioxide 50g, carbon black 10g, barium sulfate 100g, epoxy modified wollastonite 50g, anti-rust pigment 50g, bentonite 0.5g, gas silicon 5g, butyl glycol ether 50g, 100g of dipropylene glycol butyl ether, 10g of dispersant, 1g of defoamer I, 5g of defoamer II, 3g of wetting agent, 3g of leveling agent, 12g of amine neutralizer (DMEA), 3g of anti-sag additive, matting powder 50g, adhesion promoter 10g, deionized water 300g.

[0037] The difference between the specific preparation method and Example 1 is that antirust pigments are added in step (2).

[0038] The stoving varnish of embodiment 1-3 in the present application is used as primer.

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PUM

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Abstract

The invention provides water-based amino baking varnish for galvanized sheets and a preparation method thereof. The water-based amino baking varnish is prepared from the following raw materials in parts by weight: 20-35 parts of an aqueous polyester resin, 4 to 8 parts of a water-based amino resin; 5-10 parts of titanium dioxide, 1-3 parts of carbon black, 10-15 parts of barium sulfate, 3 to 5 parts of epoxy modified wollastonite; 0.1 to 0.3 part of bentonite, 0.5 to 1 part of fumed silica, 8 to 15 parts of an alcohol ether auxiliary agent, 1 to 2 parts of a dispersant, 0.5 to 0.8 part of an antifoaming agent, 0.3 to 0.5 part of a wetting agent, 0.3 to 0.5 part of a leveling agent, 1 to 1.5 parts of an amine neutralizer, 0.3 to 0.8 part of an anti-sagging auxiliary agent, 0.5 to 1 part ofan adhesion promoter and 30 to 50 parts of deionized water. The baking varnish has the advantage of high adhesive force on galvanized plates, and can effectively improve the corrosion resistance of the galvanized plates.

Description

technical field [0001] The invention relates to the field of water-based coatings, in particular to a water-based amino baking varnish for galvanized sheets and a preparation method thereof. Background technique [0002] Water-based coatings are non-toxic, non-combustible, use water as a solvent, save a lot of energy, eliminate the risk of fire during construction; reduce air pollution; only use a small amount of low-toxicity alcohol ether organic solvents, improve the working environment conditions, The VOC content is much lower than that of solvent-based coatings, and the physical and chemical properties of the paint film are as good as or better than those of solvent-based coatings, so it is favored by people. [0003] The existing coatings, whether they are primers or topcoats, are based on non-toxic and non-polluting basic requirements for research and development. On the basis of achieving environmental protection, economy and high performance, it is important to impro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D167/00C09D161/32C09D5/08C09D7/45C09D7/40
CPCC09D5/082C09D167/00C09D7/40C09D7/45C08L61/32C08K13/06C08K9/04C08K3/34C08K3/346C08K7/26
Inventor 王进科庞博
Owner 山东七维新材料有限公司
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