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Method for preparing two-dimensional layered transition metal nanosheet gel

A transition metal, two-dimensional layered technology, applied in gel preparation, chemical instruments and methods, colloidal chemistry, etc., can solve the problems of high cost, complicated preparation process, long preparation time, etc. The effect of craftsmanship

Active Publication Date: 2020-02-21
SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Two-dimensional layered transition metal nanosheet hydrogels are usually prepared by self-assembly method, solution mixing method, in-situ polymerization method or chemical reduction method. Long time and high cost are not conducive to retaining the excellent physical and chemical properties of two-dimensional layered transition metal nanosheets
[0004] The highly isotropic hydrogel skeleton network has strong conductivity in all directions, and its structure is stable, which facilitates the transport of substances between networks. However, its preparation is difficult, and it is difficult to ensure the conductivity of hydrogels by traditional methods. While building a stable three-dimensional network, to achieve its isotropy

Method used

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  • Method for preparing two-dimensional layered transition metal nanosheet gel
  • Method for preparing two-dimensional layered transition metal nanosheet gel
  • Method for preparing two-dimensional layered transition metal nanosheet gel

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preparation example Construction

[0030] The invention provides a method for preparing a two-dimensional layered transition metal nanosheet gel, such as figure 1 As shown, including the following steps:

[0031] Step S1: Provide two-dimensional layered transition metal nanosheets (MXene nanosheets) with specific functional groups as a solute, and dissolve the two-dimensional layered transition metal nanosheets in a solvent to form a nano dispersion.

[0032] Specifically, the specific functional groups in the two-dimensional layered transition metal nanosheets with specific functional groups may be carboxyl groups, hydroxyl groups, ether groups, ester groups, ketone groups, carbonyl groups, acid anhydrides, epoxy functional groups, fluorine groups, and sulfonic acid groups. One or more of, amino, secondary amine, tertiary amine and aromatic functional group. The above-mentioned specific functional groups in the two-dimensional layered transition metal nanosheets with specific functional groups can improve the dispe...

Embodiment 1

[0050] Disperse the two-dimensional layered transition metal nanosheets in water, configure a 2mg / mL two-dimensional layered transition metal nanosheet aqueous solution, measure 2mL of the two-dimensional layered transition metal nanosheet aqueous solution and place it in a 5mL centrifuge tube To FeCl 2 Is a metal ion crosslinking agent, add 0.2mL of 5mg / mL FeCl to the two-dimensional layered transition metal nanosheet aqueous solution 2 Solution, the reaction temperature is room temperature, and then stand still. The obtained product is subjected to conductivity tests and electrochemical tests in different directions.

Embodiment 2

[0052] Disperse the two-dimensional layered transition metal nanosheets in water, configure a 3mg / mL two-dimensional layered transition metal nanosheet aqueous solution, measure 2mL of the two-dimensional layered transition metal nanosheet aqueous solution and place it in a 5mL centrifuge tube To FeCl 2 Is a metal ion crosslinking agent, add 0.2mL of 5mg / mL FeCl to the two-dimensional layered transition metal nanosheet aqueous solution 2 Solution, the reaction temperature is room temperature, and then stand still. The obtained product is subjected to conductivity tests and electrochemical tests in different directions.

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Abstract

The invention provides a method for preparing a two-dimensional layered transition metal nanosheet gel. The method comprises the following steps: providing two-dimensional layered transition metal nanosheets with specific functional groups as a solute, and dissolving the two-dimensional layered transition metal nanosheets in a solvent to form a nano dispersion; and providing a cross-linking agentsolution containing a metal ion crosslinking agent containing positive divalent or positive trivalent metal ions, mixing the cross-linking agent solution with the nano dispersion, so as to form the two-dimensional layered transition metal nanosheet gel after mixing.

Description

Technical field [0001] The invention relates to the field of chemical engineering, in particular to a method for preparing a two-dimensional layered transition metal nanosheet gel. Background technique [0002] Two-dimensional layered transition metal nanosheets are a kind of layered two-dimensional nanosheets with excellent electrical conductivity, catalytic activity and adsorption. The gelation of the two-dimensional nanosheets effectively improves the utilization rate of the nanosheets and gives them The advantages of hydrogels can expand the application prospects of two-dimensional layered transition metal nanosheets in the fields of energy storage, catalysis, high-strength materials, electronics, chemistry, and biological detection. [0003] However, compared to other zero-dimensional or one-dimensional materials, one of the most significant problems of two-dimensional materials is that they tend to "face-to-face" stacking. That is, the macroscopic appearance is gel-like, and...

Claims

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Application Information

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IPC IPC(8): B01J13/00
CPCB01J13/0052
Inventor 吕伟邓亚茜罗冲游从辉杨全红康飞宇
Owner SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV
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